Исследование межфазного натяжения на границе воды и раствора асфальтенов в толуоле

The dynamics of the interfacial tension coefficient at the interface between water and model solutions of asphaltenes of different concentrations in toluene has been studied. It has been shown that, over time, the interfacial tension decreases due to the adsorption of asphaltene molecules at the interface. With an increase in the concentration of asphaltenes in the solution, the decrease in interfacial tension occurs more intensively. The results of a study of the elongation of a water drop in a solution under the influence of an electric field are presented. It is shown that after the formation of an adsorption film, a higher stress must be applied to stretch the droplet, and the relative elongation depends nonlinearly on the applied stress. The studies were carried out using the suspended drop method.

Structure and Dynamics of Interfacial Water on Muscovite Surface under Different Temperature Conditions (298 K to 673 K): Molecular Dynamics Investigation

We performed molecular dynamics (MD) simulations to study structure, stability, and dynamics of the water adsorption layer on muscovite mica at several temperatures (from 298 K to 673 K) and pressures (0.1 MPa, 10 MPa, and 50 MPa). We studied the structure of the adsorption layers with three characteristic peaks of density and orientation of H2O molecules in one-dimensional and two-dimensional profiles. The results show that the water adsorption layers become less structured and more mobile as the temperature increases. We also found the first and the second layers are less diffusive than the third one, and the difference of diffusivity gets unclear as the temperature increases. Finally, we discuss implications to hydration forces and wettability, which are significant interfacial properties of the multiphase fluids system such as water/gas/mineral systems, from the viewpoint of water adsorption film with nanometer thickness.

Regulation mechanism of biomolecule interaction behaviors on the superlubricity of hydrophilic polymer coatings

Hydrophilic polymer coatings can improve the surface characteristics of artificial implants. However, because they are used in vivo, they inevitably come into contact with biomolecules that affect their interfacial tribological properties. In this paper, the friction behaviors of poly(vinylphosphonic acid) (PVPA)-modified Ti6Al4V and polytetrafluorethylene balls were analyzed using albumin, globulin, aggrecan, and hyaluronic acid as lubricants. The interaction properties and dynamic adsorption characteristics of the biomolecules and PVPA molecules were explored by a quartz crystal microbalance to identify the cause of the friction difference. It was found that protein molecules disturbed the superlubricity of the PVPA-phosphate-buffered saline system because of the formation of a stable adsorption film, which replaced the interfacial characteristics of the PVPA coating. Polysaccharides, with their excellent hydration properties and polymer structure, had an unstable dynamic interaction or zero adsorption with PVPA molecules, and hardly changed the superlubricity of the PVPA and phosphate-buffered-saline system. The influence mechanism of the specific friction of proteins and polysaccharides was analyzed. Interactions were observed among different biomolecules. Polysaccharides can potentially reduce protein adsorption. The result of the synergistic regulation of the friction coefficient for PVPA-modified Ti6Al4V is approximately 0.017. The results of this study will provide a theoretical basis for the use of polymer coatings in vivo.

Study on Synergistic Corrosion Inhibition Effect between Calcium Lignosulfonate (CLS) and Inorganic Inhibitors on Q235 Carbon Steel in Alkaline Environment with Cl−

The synergistic corrosion inhibition effect between calcium lignosulfonate (CLS) and three kinds of inorganic inhibitors (Na2MoO4, Na2SnO3, and NaWO4) with various molar ratios on Q235 carbon steel in alkaline solution (pH 11.5) with 0.02 mol/L NaCl was investigated by cyclic potentiodynamic polarization, electrochemical impedance spectroscopy, linear polarization, scanning electron microscopy, and X-ray photoelectron spectroscopy. Molybdate and stannate in hybrid inhibitor could promote the passivation of steel and form a complex film, which could suppress the corrosion effectively. Moreover, the insoluble metal oxides in the complex film formed by three kinds of inorganic inhibitor could help the adsorption of CLS onto the steel surface. The CLS molecules could adsorb onto the steel surface and metal oxides to form an adsorption film to protect the steel from corrosion. A three-layer protection film formed by a hybrid inhibitor, including passivation film, deposition film, and adsorption film, would effectively inhibit the corrosion reactions on the steel surface. The CLS compound with molybdate with the ratio of 2:3 shows the best inhibition effect on both general corrosion and localized corrosion.

The role of WO42− on surface passivation for Q235 carbon steel in tungstate solution

Purpose The purpose of this work is to reveal the mechanism of WO42− on surface passivation for Q235 carbon steel in tungstate solution. Design/methodology/approach In Na2WO4 solutions with the different concentrations of WO42−, the spontaneous passivation occurred on the surface of Q235 carbon steel when the concentration of WO42− was up to 0.13 mmol/L, which was attributed to the formations of the inner deposition film and the outer adsorption film on the Q235 surface under the action of WO42−. Findings The inner deposition film presented a two-layer microstructure: the inside layer was composed of Fe2O3 mainly, and the outside layer comprised Fe(OH)2•nH2O, Fe(OH)3•nH2O, FeWO4 and Fe2(WO4)3. Originality/value Both FeWO4 and Fe2(WO4)3 repaired the defects in the outside layer of the inner deposition film; however, the outer adsorption film played a more important role in the surface passivation than the inner deposition film did.

Soft-nanocomposite lubricants of supramolecular gel with carbon nanotubes

The soft-nanocomposite lubricants have excellent lubricity and anti-wear properties due to the synergistic effect of the effective adsorption film formed by the gelator and the rolling of the carbon nanotubes at the friction interface.

Influence of sodium alginate inhibitor addition on the corrosion protection performance of AZ91D magnesium alloy in NaCl solution

Purpose This paper aims to investigate the inhibition effect of sodium silicate (SS), sodium alginate (SA) and sodium tungstate (ST) on the corrosion behavior of AZ91D magnesium alloy in 3.5 per cent NaCl solution through polarization curve test at room temperature, electrochemical impedance spectroscopy and weight loss measurement. Design/methodology/approach The influence of SA concentration on the inhibition efficiency of the corrosion inhibitor was mainly analyzed. The corrosion morphology and inhibition mechanism of the samples were also analyzed with scanning electron microscopy and energy-dispersive spectroscopy. Findings The results show that with the increase of SA concentration, the corrosion inhibition first increases and then decreases. When SA concentration is 0.03 mol/L, the inhibition efficiency is the highest, reaching 98 per cent. The adsorption film formed by SA and other deposition films produce a synergistic effect on the improvement of corrosion resistance of AZ91D magnesium alloy. Originality/value The adsorption film formed by SA with other deposition films produces a synergistic effect on the improvement of corrosion resistance of AZ91D magnesium alloy. With the increase of SA concentration, the corrosion inhibition first increases and then decreases. When the concentrations of SA, SS and ST are 0.03 mol/L, 0.015 mol/L and 0.02 mol/L, respectively, the inhibition efficiency of the inhibitor is the highest, reaching 98 per cent.

In Situ Observation of Formation Behavior of Adsorption Film in the Narrow Space Using Surface Plasmon Resonance (SPR) Method

In this paper, an application of the surface plasmon resonance (SPR) method to real-time and in-situ measurements of changes in adsorption film thickness, e.g., fatty acid adsorbed films, is presented. As discussed in the previous study, the high sensitivity and overall simplicity of its optical system make the SPR method advantageous for monitoring lubricant film thickness. In order to demonstrate the high sensitivity of the SPR method, in-situ and real-time adsorption film growth processes of stearic acid (additives) in hexadecane (base oil) were monitored using the Otto configuration. Based on a comparison between experimental and model calculation results, changes in the adsorption film thickness during a series of different contact tests were measured.