scholarly journals The ManureEcoMine pilot installation: advanced integration of technologies for the management of organics and nutrients in livestock waste

2016 ◽  
Vol 75 (6) ◽  
pp. 1281-1293 ◽  
Author(s):  
Cristina Pintucci ◽  
Marta Carballa ◽  
Sam Varga ◽  
Jimena Sarli ◽  
Lai Peng ◽  
...  

Manure represents an exquisite mining opportunity for nutrient recovery (nitrogen and phosphorus), and for their reuse as renewable fertilisers. The ManureEcoMine proposes an integrated approach of technologies, operated in a pilot-scale installation treating swine manure (83.7%) and Ecofrit® (16.3%), a mix of vegetable residues. Thermophilic anaerobic digestion was performed for 150 days, the final organic loading rate was 4.6 kgCOD m−3 d−1, with a biogas production rate of 1.4 Nm3 m−3 d−1. The digester was coupled to an ammonia side-stream stripping column and a scrubbing unit for free ammonia inhibition reduction in the digester, and nitrogen recovery as ammonium sulphate. The stripped digestate was recirculated daily in the digester for 15 days (68% of the digester volume), increasing the gas production rate by 27%. Following a decanter centrifuge, the digestate liquid fraction was treated with an ultrafiltration membrane. The filtrate was fed into a struvite reactor, with a phosphorus recovery efficiency of 83% (as orthophosphate). Acidification of digestate could increment the soluble orthophosphate concentration up to four times, enhancing phosphorus enrichment in the liquid fraction and its recovery via struvite. A synergistic combination of manure processing steps was demonstrated to be technologically feasible to upgrade livestock waste into refined, concentrated fertilisers.

2003 ◽  
Vol 48 (4) ◽  
pp. 229-233 ◽  
Author(s):  
P.A. Scherer ◽  
S. Dobler ◽  
S. Rohardt ◽  
R. Loock ◽  
B. Büttner ◽  
...  

Since April 2000 a two-step anaerobic plant with two subsequent 500 m3 reactors has been producing biogas from fodder beet silage (pH 4.1) as the sole substrate. The plant is located at Kirchlengern near Bielefeld, Germany. Initially the reactors were inoculated with swine manure at 37°C. After a start-up phase the process was sustained at pH 7.5-8.0 by feeding with the silage as sole substrate twice a day. Parallel to the biogas plant at Kirchlengern four one-step laboratory reactors were continuously driven at temperatures of 37°C, 45°C, 60°C and 65°C. They were fed with the same silage, but only once per day (one impulse). The organic loading rate (OLR) was adjusted to 3.9 g volatile solids (VS)/(l*d) with a concomitant hydraulic retention time (HRT) of 27 d. There was no problem with starting the reactors, but after 86 days the volumetric gas production of the 65°C reactor ceased and a high amount of approximately 130 mM propionate could be determined. By decreasing the temperature down to 60°C a stable reactor performance was recovered for a period of at least 250 further days. During impulse feeding it was observed that the quickest recovery of gas production could be observed at 37°C or at 45°C. Recovery of 75% gas volume (related to the value before or after impulse feeding) was obtained after 5.5 and 7.5 h of feeding time point whereas the 60°C reactor needed 16 h. Slight significant differences were seen in the spectrum of volatile fatty acids (VFA) reaching at 37° or 45°C its maximum with 10-30 mM total VFA at 2-3 h after feeding. After this the VFA level declined to nearly zero (except for the 60°C reactor). Therefore the 37°C reactor was favoured. A double experiment with a second 37°C reactor was started by a somewhat different inoculation procedure from the remaining 3 reactors, but revealed similar results. By increasing the temperature no significantly different specific gas production rates and methane yields could be observed, e.g. it gave 600-700 l biogas from 1 kg VS. The corresponding methane content ranged between 62-64%. With a methane content of 63 ± 1% a yield of 40.1 ± 2 m3 methane/ton fresh fodder beet silage was obtained.


2018 ◽  
Vol 61 (3) ◽  
pp. 943-953
Author(s):  
Daniel S. Andersen ◽  
Fan Yang ◽  
Steven L. Trabue ◽  
Brian J. Kerr ◽  
Adina Howe

Abstract. High levels of methane production from swine operations have been associated with foam accumulation in deep-pit manure storage systems. This foam poses both a safety concern (i.e., flash fires) and operational challenges in managing stored manure. Mitigating methane production is one approach to controlling foam accumulation. In this study, swine manures obtained from three deep-pit storage barns in central Iowa were dosed with narasin to evaluate its inhibitory effects on methane and biogas production. Dose rates ranged from 0 to 3.0 mg narasin kg-1 manure. Overall, methane rates were reduced by 9% for each mg of narasin added per kg of manure, and this reduction was effective for up to 25 days. However, the inhibitory effect weakened with time such that no statistical difference in cumulative methane production between samples dosed with narasin and undosed controls could be detected after 120 days of incubation. In addition to methane rates, narasin addition reduced the degradation of total and volatile solids in the manure by 1.9% and 2.6%, respectively, for each mg of narasin added per kg of manure. Additional study treatments included sugar (10 g kg-1 manure) with and without narasin (1.5 mg narasin kg-1 manure). Results from this treatment showed that methane production was initially increased by the sugar addition, but the effect lasted less than six days, at which point cumulative methane production was similar to the control. When treated with both narasin and sugar, the inhibitory effect did not impact gas production during the sugar digestion phase but did reduce methane and biogas production thereafter. The addition of sugar and the rate of narasin addition caused changes to the microbial community as compared to the control. Overall, the results indicated that narasin can be an effective additive for reducing methane emission from swine manure, but further study is needed to recommend dosing frequency and to evaluate how continuous addition of manure impacts narasin effectiveness. Keywords: Biogas, Manure management, Manure treatment, Methane, Narasin, Swine manure, Swine production.


2020 ◽  
Vol 14 (4) ◽  
pp. 551-557
Author(s):  
Yongku Li ◽  
Xiaomin Hu ◽  
Lei Feng

The changing parameters, as the biogas production rate, the methane production rate, the cumulative biogas amount, the cumulative methane amount, the biogas composition, pH etc. in high temperature anaerobic fermentation of chicken manure and stalks were analyzed by experiments with different mass ratios of chicken manure or livestock manure and stalks with a high C/N ratio. The methane production mechanism of high temperature anaerobic digestion of chicken manure and stalks was discussed in detail. It showed that not only the biogas production rates but also the methane production rates of R1–R7 demonstrated the trend of initial increase and then decrease after 50 d of high temperature anaerobic digestion. Besides, the gas production of R1 with pure chicken manure stopped on the 30th d of the reaction. The gas production of other groups R2–R7 also stopped on the corresponding 34th, 36th, 36th, 37th, 37th, and 37th day, respectively. At the end of the reaction, the cumulative biogas amounts and the cumulative methane amounts of R1–R7 were 411.58 and 269.54, 459.91 and 314.41, 425.32 and 294.11, 401.85 and 272.54, 382.63 and 257.07, 363.04 and 218.16, and 257.15 and 160.10 N ml/(g VS). The biogas slurry pH of R1–R7 all demonstrated a trend of initial decrease and then increase, e. g., pH of R2 reached the minimum of 5.94 on the 5th day. pH values of other groups were between 6.01 and 6.39. After the addition of 4 g of sodium bicarbonate on the 7th day, biogas slurry pH of R1–R7 all increased. pH was maintained between 7.16 and 7.44 until the end of the reaction.


2006 ◽  
Vol 53 (12) ◽  
pp. 177-186 ◽  
Author(s):  
D. Bolzonella ◽  
P. Pavan ◽  
P. Battistoni ◽  
F. Cecchi

This paper deals with the performances obtained in full scale anaerobic digesters co-digesting waste activated sludge from biological nutrients removal wastewater treatment plants, together with different types of organic wastes (solid and liquid). Results showed that the biogas production can be increased from 4,000 to some 18,000 m3 per month when treating some 3–5 tons per day of organic municipal solid waste together with waste activated sludge. On the other hand, the specific biogas production was improved, passing from 0.3 to 0.5 m3 per kgVS fed the reactor, when treating liquid effluents from cheese factories. The addition of the co-substrates gave minimal increases in the organic loading rate while the hydraulic retention time remained constant. Further, the potentiality of the struvite crystallisation process for treating anaerobic supernatant rich in nitrogen and phosphorus was studied: 80% removal of phosphorus was observed in all the tested conditions. In conclusion, a possible layout is proposed for designing or up-grading wastewater treatment plants for biological nutrients removal process.


2017 ◽  
Vol 60 (5) ◽  
pp. 1713-1720 ◽  
Author(s):  
Yi Wang ◽  
Wanqin Zhang ◽  
Hongmin Dong ◽  
Zhiping Zhu ◽  
Baoming Li

Abstract. With the rapid growth of large-scale and intensive swine farms have come many ecological and environmental problems associated with the substantially increased and concentrated animal waste production. In this article, a swine manure and flushed slurry to renewable energy management system is present and discussed. This system was installed in a commercial feeder-to-finish swine farm with 18,000 head of swine in Beijing, China, and included two mesophilic upflow solids reactors (USRI and USRII, 500 m3 and 700 m3) and one psychrophilic plug-flow reactor (PFR, 1000 m3). In this study, USRII was monitored throughout a whole year to evaluate the performance of this swine waste to energy system. The biogas plant used mixed solid swine manure and flushed slurry as substrate with a relatively low organic loading rate (OLR) of 0.7 to 1.8 kg volatile solids (VS) m-3 d-1. The hydraulic retention time (HRT) varied from 15 to 22 days depending on the season. Less added water contributed to the longer HRT and more concentrated influent in winter. In winter, the specific methane production (SMP) of the digester was 0.43 m3 CH4 kg-1 VSadded, which was slightly lower than the value reported in Europe (0.45 m3 CH4 kg-1 VSadded) but about 48.3% higher than that in Asia (0.29 m3 CH4 kg-1 VSadded). This indicated that the performance of this USR in winter was stable, with a higher biogas production, and up to 90% of the VS was removed as well. However, the low OLR limited the volumetric methane production rate to only 0.21 to 0.57 m3 m-3 d-1. Keywords: Flushed slurry, Large-scale biogas plant, Monitoring, Performance, Swine manure.


2008 ◽  
Vol 58 (3) ◽  
pp. 669-676 ◽  
Author(s):  
S. Caffaz ◽  
E. Bettazzi ◽  
D. Scaglione ◽  
C. Lubello

Co-digestion appears to be an interesting solution to increase the biogas production of poorly performing under-loaded digesters of waste activated sludge. In the Florence WWTP anaerobic codigestion could increase nitrogen and phosphorus loading rates and thus lower the nutrient removal efficiency. In order to develop an integrated solution to upgrade the Florence WWTP, the different process units were tested in experimental plants. Anaerobic codigestion with source-collected organic solid waste in a pilot-scale bioreactor showed an increase of GPR from 0.15 to 0.45 Nl biogas/l/d with 23% of organic waste loaded. Autotrophic nitrogen removal was carried out in two lab-scale pilot plants which were fed with a real anaerobic supernatant after phosphate removal via struvite formation. The nitritation MBBR has been working for one year at steady-state conditions with a perfect nitrite/ammonium ratio equal to 1:1. Anammox biomass enrichment was performed in a suspended biomass SBR and the specific nitrogen removal rate increased from 1.7 to 58 gN/kgVSS/d in 375 days.


Processes ◽  
2021 ◽  
Vol 9 (8) ◽  
pp. 1324
Author(s):  
Chiu-Yue Lin ◽  
Wai Siong Chai ◽  
Chyi-How Lay ◽  
Chin-Chao Chen ◽  
Chun-Yi Lee ◽  
...  

The traditional pig manure wastewater treatment in Taiwan has been low in methane production efficiency due to unstable influent concentration, wastewater volume, and quality. Two-stage anaerobic systems, in contrast, have the advantage of buffering the organic loading rate in the first stage (hydrolysis-acidogenesis phase), allowing a more constant feeding rate to the second stage (methanogenesis phase). Response surface methodology was applied to optimize the operational period (0.5–2.0 d) and initial operational pH (4–10) for hydrolysis and acidogenesis of the swine manure (total solid 5.3%) at 35 °C in batch operation mode. A methanogenesis verification experiment with the optimal condition of operational period 1.5 d and pH 6.5 using batch operation resulted in peak volatile acid production 7 g COD/L, methane production rate (MPR) 0.3 L-CH4/L-d, and methane yield (MY) 92 mL-CH4/g-CODre (chemical oxygen demand removed). Moreover, a two-stage system including a hydrolysis-acidogenesis reactor with the optimal operating condition and a methanogenesis reactor provided an average MPR 163 mL/L-d and MY 38 mL/g volatile solids, which values are 60% higher than those of a single-stage system; both systems have similar dominant methane-producing species of Firmicutes and Bacteroidetes with each having around 30%–40%. The advantages of a two-stage anaerobic fermentation system in treating swine manure for biogas production are obvious.


Water ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 3074
Author(s):  
Apostolos Spyridonidis ◽  
Ioanna A. Vasiliadou ◽  
Christos S. Akratos ◽  
Κaterina Stamatelatou

Biogas plants have been started to expand recently in Greece and their positive contribution to the economy is evident. A typical case study is presented which focuses on the long-term monitoring (lasting for one year) of a 500 kW mesophilic biogas plant consisting of an one-stage digester. The main feedstock used was cow manure, supplemented occasionally with chicken manure, corn silage, wheat/ray silage, glycerine, cheese whey, molasses and olive mill wastewater. The mixture of the feedstocks was adjusted based on their availability, cost and biochemical methane potential. The organic loading rate (OLR) varied at 3.42 ± 0.23 kg COD m−3 day−1 (or 2.74 ± 0.18 kg VS m−3 day−1) and resulted in a stable performance in terms of specific biogas production rate (1.27 ± 0.12 m3 m−3 day−1), biogas yield (0.46 ± 0.05 m3 kg−1 VS, 55 ± 1.3% in methane) and electricity production rate (12687 ± 1140 kWh day−1). There were no problems of foaming, nor was there a need for trace metal addition. The digestate was used by the neighboring farmers who observed an improvement in their crop yield. The profit estimates per feedstock indicate that chicken manure is superior to the other feedstocks, while molasses, silages and glycerin result in less profit due to the long distance of the biogas plant from their production source. Finally, the greenhouse gas emissions due to the digestate storage in the open air seem to be minor (0.81% of the methane consumed).


2013 ◽  
Vol 724-725 ◽  
pp. 383-390
Author(s):  
Yan Bin Li ◽  
Qin Zhang ◽  
Yong Sun

Nutritive salts and complex anaerobic cellulose decomposing bacteria (CACDB) were added for anaerobic digestion process in order to improve biogas production and biodegradability of acid hydrolytic cotton stalk. The results showed that addition of CACDB, nutritive salt I and nutritive salt II could effectively enhance daily biogas production, cumulative biogas and methane yields, in this treatment, the total gas production, daily average gas production, TS gas production rate, VS gas production rate and average yield of methane were all highest and reached 5908.90 mL, 196.96 ± 7.97 mL·d-1, 143.07 ± 5.79 mL·g-1, 156.32 ± 6.33 mL·g-1, 102.58 ± 3.34 mL·d-1, separately. The addition of CACDB and nutritive salts could improve the biodegradability of acid hydrolytic cotton stalk, in all addition treatments, the degradation rates of cellulose and lignin, VS reduction rates were higher and C/N ratios were lower than control treatment. The SEM analysis showed that the microstructure changes of digestion residues were helpful for biogas production.


2013 ◽  
Vol 864-867 ◽  
pp. 225-228
Author(s):  
Zhi Qin ◽  
Qing Qin ◽  
Ying Yang

A continuous stirred-tank reactor (CSTR) was used to produce biohydrogen gas from organic wastewater. The hydrogen producing reactor was operated under high organic loading rate of 21 kgCOD/m3·d, and molasses wastewater was used as substrate. Hydrogen production rate, pH value, sugar utilizing rate and fermentative products in effluent were investigated in continuous fermentation. When Organic Loading Rate was controlled at 21 kgCOD/m3·d, the average concentrations of acetic acid, ethanol, propionic acid, butyric acid and valeric acid in liquid fermentative products were 833, 748, 482, 484 and 256mg/L respectively. There is not any fermentation product playing dominant role absolutely in hydrogen production fermentation. The pH value in effluent was about 4.7~4.9, the average utilizing rate of sugar reached 92.1%, most of the sugar in molasses wastewater was utilized. The biogas production rate in hydrogen producing fermentation was from 21.2 to 27.1L/d, and the average biogas production rate was about 25.1L/d. The hydrogen content was about 37%.


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