scholarly journals Acute toxicity of smoke screen materials to aquatic organisms, white phosphorus-felt, red phosphorus-butyl rubber and SGF No. 2 fog oil. Final report

1986 ◽  
Author(s):  
T.M. Poston ◽  
K.M. McFadden ◽  
R.M. Bean ◽  
M.L. Clark ◽  
B.L. Thomas ◽  
...  
2013 ◽  
Vol 36 (5) ◽  
pp. 965-970 ◽  
Author(s):  
Hao WU ◽  
Min JIANG ◽  
Zhang-Xiao PENG ◽  
Lin HE

2005 ◽  
Vol 40 (4) ◽  
pp. 431-447 ◽  
Author(s):  
R. James Maguire ◽  
Suzanne P. Batchelor

Abstract A survey of water and sediment from 152 harbours, marinas and shipping channels across Canada was conducted in 1999 to determine the extent of contamination by tributyltin (TBT) prior to the total ban on its antifouling uses being phased in over the period 2003 to 2008, and to assess the effectiveness of the 1989 regulation of antifouling uses of TBT under the Canadian Pest Control Products Act. TBT was found in sediments in this survey much more frequently than in water. The main conclusion was that by 1999 the regulation had been generally effective in reducing TBT contamination in water, but not sediment, in small-craft marinas and harbours. TBT continued to be found in some freshwater and seawater locations frequented by larger vessels, that could have been legally painted at the time with TBT antifouling paints, at concentrations that could cause chronic toxicity to aquatic organisms. TBT was also found in many marine sediments, and some freshwater sediments, at concentrations that could cause chronic toxicity to sensitive benthic organisms. In addition, TBT concentrations in many marine sediments could cause acute toxicity to sensitive benthic organisms. Because of the long persistence of TBT in sediments, it may pose a hazard to benthic organisms in some locations in Canada for many years after the total ban on antifouling uses of TBT.


1975 ◽  
Vol 189 (1096) ◽  
pp. 305-332 ◽  

A range of chlorinated hydrocarbons derived from C 1 and C 2 hydrocarbons is manufactured industrially. They are used as intermediates for further chemical manufacture and also outside the chemical industry as solvents or carriers. In the latter category losses in use are eventually dispersed to the environment. The distribution of some of these compounds, including chloroform, carbon tetrachloride, trichloroethylene, perchloroethylene and trichloroethane, in the environment (air, water and marine sediments) has been investigated and the results are presented. The concentrations found have been compared with acute toxicity levels to fish and other aquatic organisms, ascertained by laboratory bioassay. The occurrence of the compounds has been determined in a number of marine organisms, especially those at higher trophic levels, and the accumulation of some of them has been investigated in the laboratory. Chemical and microbial degradation processes have been studied in the laboratory to help determine the course of their removal from the aqueous and aerial environment, and the half lives of some of the compounds have been estimated. It is concluded that these compounds are not persistent in the environment, and that there is no significant bioaccumulation in marine food chains.


2019 ◽  
Vol 60 (12) ◽  
pp. 1-24
Author(s):  
Anton Z. Mindubaev ◽  
◽  
Elena K. Badeeva ◽  
Salima T. Minzanova ◽  
Lubov G. Mironova ◽  
...  

The biological degradation of white phosphorus, which is being studied by our team is without a doubt a phenomenon of scientific novelty and practical significance. In a decade of studying this phenomenon, we have achieved significant results. However, the field of application of white and yellow phosphorus is rather a narrow one, and this imposes a limitation on the applicability of our method for the neutralization of industrial wastes. Accordingly, an interesting and important path of focus is to expand the spectrum of substances neutralized by the microbial cultures studied by our team. It is thus logical to commence such a major study with phosphorus compounds, since fungal cultures were adapted for the biodegradation of substances containing this element. In this regard, it should be pointed out that, white phosphorus cannot be metabolized to phosphate in one stage; metabolites are formed with intermediate oxidation states of phosphorus. Therefore, it can be assumed that microorganisms that neutralize white phosphorus should be capable of biodegradation of a whole spectrum of phosphorus compounds. We tested this hypothesis experimentally. It was uncovered that Aspergillus niger AM1 posseses the ability to use red phosphorus, triamide of phosphoric acid, phosphomolybdic acid, substituted dithiophosphate and organophosphorus matter as sources of phosphorus. In addition, in the present work, we describe attempts made to increase the concentration of white phosphorus in the culture medium to values above 1%. To do this, we added olive oil (a solvent in which white phosphorus is relatively soluble) to the culture medium. It turned out that in the presence of this component, the minimum inhibitory concentration of white phosphorus drops abruptly.


2020 ◽  
Vol 36 (7) ◽  
pp. 467-476
Author(s):  
Halis Boran

Metal-based nanoparticles (NPs) can release metal ions that are toxic to aquatic organisms; however, whether the toxicity is from metal ions rather than unique “nano-scale” effects of the NPs is unresolved. The present study aimed to compare the toxicity of Cu2+ and Cu-NPs in larval zebrafish ( Danio rerio) to clarify whether toxic effects are attributable to release of Cu ions and to determine the effect of the chelating agent ethylenediaminetetraacetic acid (EDTA) and calcium hardness (as CaCO3) on the Cu toxicity. First, the acute toxicity (96-h lethality) of Cu-NPs was determined in comparison to aqueous Cu in larvae exposed to CuSO4, and subsequently, sublethal tests with Cu-NPs and CuSO4 were conducted with additions of EDTA or calcium ions to evaluate alterations in expression of metallothionein-2 ( MT2) gene transcripts (quantitative real-time polymerase chain reaction). Acute toxicity of Cu in larvae exposed to CuSO4 was greater (LC50 = 226 µg Cu/L) than for larvae exposed to Cu-NPs (LC50 = 648 µg Cu/L). The expression of MT2 increased with Cu concentration ( p < 0.05), and the slope of the linear regression was significantly greater in fish exposed to CuSO4 (slope = 0.090) compared to Cu-NPs (slope = 0.011). Cu2+ was 2.9-fold more toxic than Cu-NPs. The presence of 5 mg/L EDTA and 220 mg/L CaCO3 significantly reduced the expression of MT2 (1.8-fold for EDTA, 2.3-fold for CaCO3) in larvae exposed to CuSO4. For larvae exposed to Cu-NPs, the presence of EDTA reduced the expression of MT2 (1.7-fold) relative to Cu-NP concentration. While Cu-NPs induced MT2 expression, the differences in concentration relationships of MT2 expression between Cu-NPs and CuSO4 indicated that factors other than release of Cu ions from Cu-NPs influenced acute toxicity of Cu-NPs. The conclusion drawn from this ecotoxicological risk assessment was that EDTA and calcium significantly decreased Cu toxicity in freshwater fish.


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