One-pot Synthesis of Novel Thiophene Containing Aminonaphthols using Fe3O4 Nanoparticles as a Recyclable Heterogeneous Catalyst

2021 ◽  
Vol 10 ◽  
Author(s):  
Ganesh Pavale ◽  
M. M. V. Ramana ◽  
Poornima Acharya ◽  
Sarfaraz Shaikh
Keyword(s):  
Catalytic Activity ◽  
Metal Oxide ◽  
Fe3o4 Nanoparticles ◽  
Metal Oxide Nanoparticles ◽  
Solvent Free ◽  
Precipitation Method ◽  
Synthetic Approach ◽  
One Pot ◽  
Solvent Free Conditions ◽  
Wide Range

Background: Metal oxide and metal oxide nanoparticles are gaining significant importance due to their reusability and wide range of catalytic applications in many organic transformations. Objective: To report simple and efficient Fe3O4 catalyzed one-pot five-component reaction protocol to synthesize novel thiophene containing aminonaphthols under solvent-free conditions. Method: To prepare the Fe3O4 nanoparticles by facile and simple co-precipitation method and surface characterization was done using FT-IR, XRD, BET, SEM, and TEM analysis technique. Aminonaphthol derivatives bearing thiophene moiety were synthesized using Fe3O4 nanoparticles under solvent-free conditions. Results: The prepared nanoparticles are smaller in size (15nm) and can be easily detachable. It can be recycled and reused five times without any significant loss of catalytic activity with excellent yields in a short time. The existing protocol for synthesizing amino naphthol becomes feasible and attractive due to the reusability of the catalyst, excellent catalytic performance, and eco-friendly procedure. Conclusion: In conclusion, Fe3O4 nanoparticles provide a simple, efficient, and greener one-pot five-component synthetic approach to synthesize thiophene containing aminonaphthols. Excellent catalytic activity was perceived in a short reaction time without any co-catalyst or any other activator. Moreover, reusability of catalyst, high yields, and environmentally benign solvent-free condition are vital factors of this protocol.

ZnO@SnO2 Mixed Metal Oxide as an Efficient and Recoverable Nanocatalyst for the Solvent Free Synthesis of Hantzsch 1,4-Dihydropyridines

2019 ◽  
Vol 16 (2) ◽  
pp. 139-144 ◽  
Author(s):  
Bharatkumar M. Sapkal ◽  
Prakash K. Labhane ◽  
Shamrao T. Disale ◽  
Dhananjay H. More
Keyword(s):  
Metal Oxide ◽  
Metal Oxide Nanoparticles ◽  
Reaction Times ◽  
Solvent Free ◽  
Catalyst Loading ◽  
Mixed Metal Oxide ◽  
One Pot ◽  
Mixed Metal ◽  
Solvent Free Conditions ◽  
Three Component Reaction

An efficient synthesis of Hantzsch 1,4-dihydropyridines via a one-pot three-component reaction of ethyl acetoacetate, substituted aldehydes and ammonium acetate in the presence of ZnO@SnO2 mixed metal oxide nanoparticles under solvent-free conditions has been reported. Compare to the reported reactions, this method shows attractive aspects such as cleaner reaction profile, shorter reaction times, minimum catalyst loading and high yields. Isolated catalysts were reused for new reactions without considerable loss of their catalytic activity.

Facile Synthesis of 1,8-dioxooctahydro Xanthenes by Reusable Zinc Sulfide based Ternary Nanocomposite via Hydrothermal Route

2020 ◽  
Vol 9 (1) ◽  
pp. 72-79
Author(s):  
Jhansi R. Sunkara ◽  
Sathish M. Botsa
Keyword(s):  
Catalytic Activity ◽  
Reaction Time ◽  
Metal Oxide ◽  
Solvent Free ◽  
Hydrothermal Route ◽  
One Pot ◽  
Co Catalyst ◽  
Short Reaction Time ◽  
Solvent Free Conditions ◽  
Xanthene Derivatives

Background: Metal oxide or metal oxide composite nanoparticles are attaining tremendous importance due to their catalytic activities for various organic transformations. Objective: To report the one-pot synthesis of xanthene derivatives prepared by ZnS-Fe2O3-Ag composite under solvent-free conditions. Method: To prepare nanocomposite by a facile and simple hydrothermal approach. Results: The prepared composite is smaller (17.56 nm) in size and can be easily separable, recycled and reused six times without any significant loss of catalytic activity with excellent yields. In short reaction time, great catalytic activity was perceived with no co-catalyst and any other activator. Conclusion: In conclusion, ZnS-Fe2O3-Ag composite provides a simple, economical, efficient and greener method for the synthesis of one-pot multicomponent reaction of aldehyde with 1,3-diketones under solvent free conditions for the synthesis of 1,8-dioxooctahydro xanthenes. In short reaction time, great catalytic activity was perceived with no co-catalyst and any other activator.

Chlorosulfonic Acid Supported Piperidine-4-carboxylic Acid (PPCA) Functionalized Fe3O4 Nanoparticles (Fe3O4-PPCA): The Efficient, Green and Reusable Nanocatalyst for the Synthesis of Pyrazolyl Coumarin Derivatives under Solvent-Free Conditions

2019 ◽  
Vol 22 (2) ◽  
pp. 123-128
Author(s):  
Setareh Habibzadeh ◽  
Hassan Ghasemnejad-Bosra ◽  
Mina Haghdadi ◽  
Soheila Heydari-Parastar
Keyword(s):  
Carboxylic Acid ◽  
Fe3o4 Nanoparticles ◽  
High Efficiency ◽  
Reaction Times ◽  
Chlorosulfonic Acid ◽  
Aromatic Aldehydes ◽  
Solvent Free ◽  
Magnetic Nanocatalyst ◽  
One Pot ◽  
Solvent Free Conditions

Background: In this study, we developed a convenient methodology for the synthesis of coumarin linked to pyrazolines and pyrano [2,3-h] coumarins linked to 3-(1,5-diphenyl-4,5- dihydro-1H-pyrazol-3-yl)-chromen-2-one derivatives using Chlorosulfonic acid supported Piperidine-4-carboxylic acid (PPCA) functionalized Fe3O4 nanoparticles (Fe3O4-PPCA) catalyst. Materials and Methods:: Fe3O4-PPCA was investigated as an efficient and magnetically recoverable Nanocatalyst for the one-pot synthesis of substituted coumarins from the reaction of coumarin with a variety of aromatic aldehydes in high to excellent yield at room temperature under solvent-free conditions. The magnetic nanocatalyst can be easily recovered by applying an external magnet device and reused for at least 10 reaction runs without considerable loss of reactivity. Results and Conclusion: The advantages of this protocol are the use of commercially available materials, simple and an inexpensive procedure, easy separation, and an eco-friendly procedure, and it shows good reaction times, good to high yields, inexpensive and practicability procedure, and high efficiency.

scholarly journals Synthetic versatility of nanoparticles: A new, rapid, one-pot, single-step synthetic approach to spherical mesoporous (metal) oxide nanoparticles using supercritical alcohols

2014 ◽  
Vol 86 (5) ◽  
pp. 785-800 ◽  
Author(s):  
Pengyu Wang ◽  
Kazuya Kobiro
Keyword(s):  
Metal Oxide ◽  
Metal Oxide Nanoparticles ◽  
Single Step ◽  
Oxide Nanoparticles ◽  
Synthetic Approach ◽  
Organic Additives ◽  
Step Method ◽  
One Pot ◽  
Mesoporous Metal ◽  
Mesoporous Metal Oxide

AbstractA simple, rapid (10 min), one-pot, single-step method for the preparation of solid and hollow spherical porous TiO2 nanoparticles with large surface areas (100–211 m2/g) was developed in supercritical alcohols using carboxylic acids as organic additives. The shell thickness of the hollow TiO2 nanoparticles (20–280 nm) was controlled by adjusting the heating rate (2.0–10.0 °C/min). The preparation of different spherical porous metal oxide nanoparticles, including CeO2, SiO2, TiO2, ZrO2, and ZnO, demonstrated the versatility of the synthetic approach. In addition, several rare earth-doped spherical mesoporous metal oxide nanoparticles, including CeO2:Er, CeO2:Er,Yb, ZrO2:Er, and TiO2:Er, which exhibit energy upconversion emission, were successfully prepared using this one-pot, single-step, supercritical methanol method. The obtained spherical mesoporous CeO2:Er and CeO2:Er,Yb nanoparticles emit green light upon excitation, even when irradiated with a low-power IR laser (980 nm, 10 mW) without calcination. Several other (metal) elements were also easily doped into spherical, mesoporous TiO2 nanoparticles, such as Eu, Ce, Yb, Fe, and N, using a similar procedure. Furthermore, the spherical mesoporous TiO2 nanoparticles were successfully applied as a new material for the transport of DNA via biolistic bombardment.

scholarly journals Fe3o4 nanoparticles: A highly efficient and easily reusable catalyst for the one-pot synthesis of xanthene derivatives under solvent-free conditions

2013 ◽  
Vol 78 (6) ◽  
pp. 769-779 ◽  
Author(s):  
Ali Ghasemzadeh ◽  
Javad Safaei-Ghomi ◽  
Safura Zahedi
Keyword(s):  
Fe3o4 Nanoparticles ◽  
Reaction Times ◽  
Aromatic Aldehydes ◽  
Solvent Free ◽  
Reusable Catalyst ◽  
One Pot ◽  
Solvent Free Conditions ◽  
Xanthene Derivatives ◽  
The One ◽  
High Yields

Magnetically separable Fe3O4 nanoparticles supply environmentally friendly procedure for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthene and 1,8-dioxo-octahydro-xanthene derivatives. These compounds were obtained in high yields and short reaction times by the reaction of dimedone and 2-naphthol with various aromatic aldehydes under solvent-free conditions. The catalyst coluld be easily recovered using an external magnet and reused for six cycles with almost consistent activity.

scholarly journals H4SiW12O40Catalyzed One-Pot Synthesis of 12-Aryl-8,9,10,12-tetrahydrobenzo[a] Xanthen-11-ones Under Solvent-Free Conditions

2012 ◽  
Vol 9 (2) ◽  
pp. 786-790 ◽  
Author(s):  
A. Hassankhani ◽  
E. Mosaddegh ◽  
S. Y. Ebrahimipour
Keyword(s):  
Catalytic Activity ◽  
Solvent Free ◽  
Environmentally Benign ◽  
Reusable Catalyst ◽  
High Catalytic Activity ◽  
One Pot ◽  
Aryl Aldehydes ◽  
One Pot Synthesis ◽  
Solvent Free Conditions ◽  
The One

An efficient and environmentally benign protocol for the one-pot, three-component synthesis of 12-aryl-8,9,10,12-tetrahydro-benzo[a]xanthen-11-one derivatives by condensation of aryl aldehydes, 2-naphthol and dimedone using H4SiW12O40(SiWA) as a reusable catalyst with high catalytic activity was reported. The reaction was carried out at 100 ºC under solvent-free conditions within 15-40 min in 82-91% yield.

Zirconium(IV) 4-sulphophenylethyliminobismethylphosphonate as an efficient and reusable catalyst for one-pot synthesis of 3,4-dihydropyrimidones under solvent-free conditions

2011 ◽  
Vol 65 (6) ◽  
Author(s):  
Xin-Bin Yang ◽  
Xiang-Kai Fu ◽  
Yu Huang ◽  
Ren-Quan Zeng
Keyword(s):  
Catalytic Activity ◽  
Elemental Analysis ◽  
Biginelli Reaction ◽  
Significant Loss ◽  
Solvent Free ◽  
Reusable Catalyst ◽  
One Pot ◽  
Efficient Catalyst ◽  
Solvent Free Conditions ◽  
Simple Filtration

AbstractZirconium(IV) 4-sulphophenylethyliminobismethylphosphonate (ZSBEDP) was prepared and characterised by elemental analysis, IR, TG-DSC, and XRD. ZSBEDP was found to be an efficient catalyst for the Biginelli reaction of aromatic aldehyde, ethyl acetoacetate, and urea or thiourea under solvent-free conditions so as to give 3,4-dihydropyrimidones in good to excellent yields. The catalyst can be separated by simple filtration and reused without significant loss of its catalytic activity.

ZnII doped and immobilized on functionalized magnetic hydrotalcite (Fe3O4/HT-SMTU-ZnII): a novel, green and magnetically recyclable bifunctional nanocatalyst for the one-pot multi-component synthesis of acridinediones under solvent-free conditions

2017 ◽  
Vol 41 (24) ◽  
pp. 15485-15500 ◽  
Author(s):  
Z. Zarei ◽  
B. Akhlaghinia
Keyword(s):  
Catalytic Activity ◽  
Solvent Free ◽  
Efficient Synthesis ◽  
One Pot ◽  
Solvent Free Conditions ◽  
The One

Herein, the catalytic activity of a novel synthesized Fe3O4/HT-SMTU-ZnII nanocatalyst, in the green and efficient synthesis of acridinediones, is described.

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