Materials for Solar Cell Technologies I

2021 ◽  

The book reviews recent research and new trends in the area of solar cell materials. Topics include fabrication methods, solar cell design, energy efficiency and commercialization of next-generation materials. Special focus is placed on graphene and carbon nanomaterials, graphene in dye-sensitized solar cells, perovskite solar cells and organic photovoltaic cells, as well as on transparent conducting electrode (TCE) materials, hollow nanostructured photoelectrodes, monocrystalline silicon solar cells (MSSC) and BHJ organic solar cells. Also discussed is the use of graphene, sulfides, and metal nanoparticle-based absorber materials.

2020 ◽  
Vol 4 (9) ◽  
pp. 4415-4458
Author(s):  
Yongshuai Gong ◽  
Shuai Zhang ◽  
Huaizhi Gao ◽  
Zongwen Ma ◽  
Siqian Hu ◽  
...  

A summary of recent advances and comprehensive insights of NiO in emerging optoelectronic devices, such as dye-sensitized solar cells (DSSCs), perovskite solar cells (PerSCs), organic solar cells (OSCs) and various light-emitting diodes (LEDs).


Polymers ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 143 ◽  
Author(s):  
Wenjing Hou ◽  
Yaoming Xiao ◽  
Gaoyi Han ◽  
Jeng-Yu Lin

The emerging dye-sensitized solar cells, perovskite solar cells, and organic solar cells have been regarded as promising photovoltaic technologies. The device structures and components of these solar cells are imperative to the device’s efficiency and stability. Polymers can be used to adjust the device components and structures of these solar cells purposefully, due to their diversified properties. In dye-sensitized solar cells, polymers can be used as flexible substrates, pore- and film-forming agents of photoanode films, platinum-free counter electrodes, and the frameworks of quasi-solid-state electrolytes. In perovskite solar cells, polymers can be used as the additives to adjust the nucleation and crystallization processes in perovskite films. The polymers can also be used as hole transfer materials, electron transfer materials, and interface layer to enhance the carrier separation efficiency and reduce the recombination. In organic solar cells, polymers are often used as donor layers, buffer layers, and other polymer-based micro/nanostructures in binary or ternary devices to influence device performances. The current achievements about the applications of polymers in solar cells are reviewed and analyzed. In addition, the benefits of polymers for solar cells, the challenges for practical application, and possible solutions are also assessed.


Author(s):  
U. Fegade

Solar energy is an attractive renewable energy source across the globe that can help overcome the energy crises and has the ability to replace conventional resources. Hybrid solar cells have higher conversion efficiency. In the current chapter the research related to the carbon nanotubes, organic and inorganic solar cell, dye-sensitized solar cells and tandem solar cells are reviewed. The organic solar cells are most suitable and economic, but it has low efficiency of up to 15%. The inorganic solar cells are very expensive and have high efficiency of up to 46% and are used in space applications. The hybrid solar cell is the third type and the perovskite tandem has already proven to be quite efficient (17%) and low cost, mostly because of the cheap materials that are being used.


2015 ◽  
Vol 19 (01-03) ◽  
pp. 175-191 ◽  
Author(s):  
Ganesh D. Sharma ◽  
Galateia E. Zervaki ◽  
Kalliopi Ladomenou ◽  
Emmanuel N. Koukaras ◽  
Panagiotis P. Angaridis ◽  
...  

Two porphyrin dyads with the donor-π-acceptor molecular architecture, namely ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which consist of a zinc-metalated porphyrin unit and a free-base porphyrin unit covalently linked at their peripheries to a central triazine group, substituted either by a glycine in the former or a N-piperidine group in the latter, have been synthesized via consecutive amination substitution reactions of cyanuric chloride. The UV-vis absorption spectra and cyclic-voltammetry measurements of the two dyads, as well as theoretical calculations based on Density Functional Theory, suggest that they have suitable frontier orbital energy levels for use as sensitizers in dye-sensitized solar cells. Dye-sensitized solar cells based on ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ) have been fabricated, and they were found to exhibit power conversion efficiency values of 5.44 and 4.15%, respectively. Photovoltaic measurements (J–V curves) and incident photon to current conversion efficiency spectra of the two solar cells suggest that the higher power conversion efficiency value of the former solar cell is a result of its enhanced short circuit current, open circuit voltage, and fill factor values, as well as higher dye loading. This is ascribed to the existence of two carboxylic acid anchoring groups in ( ZnP )-[triazine-gly]-( H 2 PCOOH ), compared to one carboxylic acid group in ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which leads to a more effective binding onto the TiO 2 photoanode. Electrochemical impedance spectra show evidence that the ( ZnP )-[triazine-gly]-( H 2 PCOOH ) based solar cell exhibits a longer electron lifetime and more effective suppression of charge recombination reactions between the injected electrons and electrolyte.


2018 ◽  
Vol 6 (42) ◽  
pp. 11444-11456 ◽  
Author(s):  
Jonnadula Venkata Suman Krishna ◽  
Narra Vamsi Krishna ◽  
Towhid H. Chowdhury ◽  
Suryaprakash Singh ◽  
Idriss Bedja ◽  
...  

We have designed and synthesised four novel porphyrin sensitizers for dye-sensitized solar cell applications and shown power conversion efficiency of 10.5%.


2018 ◽  
Vol 47 (34) ◽  
pp. 11942-11952 ◽  
Author(s):  
Kitty Y. Chen ◽  
Phil A. Schauer ◽  
Brian O. Patrick ◽  
Curtis P. Berlinguette

Two sets of structurally analogous Co(iii/ii)-based redox mediators were incorporated in the dye-sensitized solar cells and a linear correlation was demonstrated between redox potential and photovoltage.


2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Thomas Geiger ◽  
Iuliia Schoger ◽  
Daniel Rentsch ◽  
Anna Christina Véron ◽  
Frédéric Oswald ◽  
...  

Seven unsymmetrical heptamethine dyes with carboxylic acid functionality were synthesized and characterized. These near-infrared dyes exhibit outstanding photophysical properties depending on their heterocyclic moieties and molecular structure. As proof of principle, the dyes were used as photosensitizers in dye-sensitized solar cells. Using the most promising dye, an overall conversion efficiency of 1.22% and an almost colorless solar cell were achieved.


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