Weldability of High-Strength Stainless Steel for High Pressure Gaseous Hydrogen Environments

2017 ◽  
Vol 86 (8) ◽  
pp. 555-558
Author(s):  
Kana JOTOKU ◽  
Jun NAKAMURA ◽  
Takahiro OSUKI ◽  
Hiroyuki HIRATA
Materia Japan ◽  
2018 ◽  
Vol 57 (2) ◽  
pp. 69-71
Author(s):  
Jun Nakamura ◽  
Kana Jotoku ◽  
Tomohiko Omura ◽  
Hiroyuki Hirata ◽  
Takahiro Osuki ◽  
...  

Author(s):  
Hideki Nakagawa

Practical application of fuel cell vehicle has started in the world, and high-pressure hydrogen tanks are currently considered to be the mainstream hydrogen storage system for commercially implemented fuel cell vehicle. Application of metallic materials to the components of high-pressure hydrogen storage system: hydrogen tanks, valves, measuring instructions and so on, have been discussed. In this work, tensile properties of four types of stainless steels were evaluated in 45MPa (6527psig) and 75MPa (10878psig) high-pressure gaseous hydrogen at a slow strain rate of 3×10−6 s−1 at ambient temperature. Type 316L (UNS S31603) stainless steel hardly showed ductility loss in gaseous hydrogen, since it had stable austenitic structure. On the other hand, Type 304 (UNS S30400) metastable austenitic stainless steel showed remarkable ductility loss in gaseous hydrogen, which was caused by the hydrogen embrittlement of strain induced martensitic phase. Likewise, Type 205 (UNS S20500) nitrogen-strengthened austenitic stainless steel showed remarkable ductility loss in gaseous hydrogen, though it had stable austenitic structure in the same manner as Type 316L. The ductility loss of Type 205 was due to the hydrogen embrittlement of austenitic phase resulting from the formation of planar dislocation array. Furthermore, Type 329J4L (UNS S31260) duplex stainless steel showed extreme ductility loss in gaseous hydrogen, which was caused by the hydrogen embrittlement of ferritic phase.


Author(s):  
Takashi Iijima ◽  
Hirotoshi Enoki ◽  
Junichiro Yamabe ◽  
Bai An

A high pressure material testing system (max. pressure: 140 MPa, temperature range: −80 ∼ 90 °C) was developed to investigate the testing method of material compatibility for high pressure gaseous hydrogen. In this study, SSRT and fatigue life test of JIS SUS304 and SUS316 austenitic stainless steel were performed in high pressure gaseous hydrogen at room temperature, −45, and −80 °C. These testing results were compared with those in laboratory air atmosphere at the same test temperature range. The SSRT tests were performed at a strain rate of 5 × 10−5 s−1 in 105 MPa hydrogen gas, and nominal stress-strain curves were obtained. The 0.2% offset yield strength (Ys) did not show remarkable difference between in hydrogen gas and in laboratory air atmosphere for SUS304 and SUS316. Total elongation after fracture (El) in hydrogen gas at −45 and −80 °C were approximately 15 % for SUS304 and 20% for SUS316. In the case of fatigue life tests, a smooth surface round bar test specimen with a diameter of 7 mm was used at a frequency of 1, 0.1, and 0.01 Hz under stress rate of R = −1 (tension-compression) in 100 MPa hydrogen gas. It can be seen that the fatigue life test results of SUS304 and SUS316 showed same tendency. The fatigue limit at room temperature in 100 MPa hydrogen gas was comparable with that in laboratory air. The room temperature fatigue life in high pressure hydrogen gas appeared to be the more severe condition compared to the fatigue life at low temperature. The normalized stress amplitude (σa / Ts) at the fatigue limit was 0.37 to 0.39 for SUS304 and SUS316 austenitic stainless steels, respectively.


Author(s):  
Kazuhisa Matsumoto ◽  
Shinichi Ohmiya ◽  
Hideki Fujii ◽  
Masaharu Hatano

To confirm a compatibility of a newly developed high strength stainless steel “NSSC STH®2” for hydrogen related applications, tensile and fatigue crack growth properties were evaluated in high pressure hydrogen gas up to 90MPa. At temperatures between −40 and 85°C, no conspicuous deterioration of tensile properties including ductility was observed even in 90 MPa hydrogen gas at −40°C while strength of STH®2 was higher than SUS316L. Although a slight drop of reduction of area was recognized in one specimen tested in 90 MPa hydrogen gas at −40°C, caused by the segregation of Mn, Ni and Cu in the laboratory manufactured 15mm-thick plate, it was considerably improved in the large mill products having less segregation. Fatigue crack growth rates of STH®2 in high pressure hydrogen gas were almost the same as that of SUS316L in air. Although fatigue crack growth rate in air was considerably decelerated and lower than that in hydrogen gas at lower ΔK region, this was probably caused by crack closure brought by oxide debris formed on the fracture surfaces near the crack tip by the strong contact of the fracture surfaces after the fatigue crack was propagated. By taking the obtained results into account, it is concluded that NSSC STH®2 has excellent properties in high pressure hydrogen gas in addition to high strength compared with standard JIS SUS316L.


Author(s):  
Yoshinori Sawae ◽  
Kanao Fukuda ◽  
Eiichi Miyakoshi ◽  
Shunichiro Doi ◽  
Hideki Watanabe ◽  
...  

Bearings and seals used in fuel cell vehicles and related hydrogen infrastructures are operating in pressurized gaseous hydrogen. However, there is a paucity of available data about the friction and wear behavior of materials in high pressure hydrogen gas. In this study, authors developed a pin-on-disk type apparatus enclosed in a high pressure vessel and characterized tribological behavior of polymeric sealing materials, such as polytetrafluoroethylene (PTFE) based composites, in gaseous hydrogen pressurized up to 40 MPa. As a result, the friction coefficient between graphite filled PTFE and austenitic stainless steel in 40 MPa hydrogen gas became lower compared with the friction in helium gas at the same pressure. The chemical composition of worn surfaces was analyzed by using X-ray photoelectron spectrometer (XPS) after the wear test. Results of the chemical analysis indicated that there were several differences in chemical compositions of polymer transfer film formed on the stainless disk surface between high pressure hydrogen environment and high pressure helium environment. In addition, the reduction of surface oxide layer of stainless steel was more significant in high pressure hydrogen gas. These particular effects of the pressurized hydrogen gas on the chemical condition of sliding surfaces might be responsible for the tribological characteristics in the high pressure hydrogen environment.


Author(s):  
Shinichi Ohmiya ◽  
Hideki Fujii

Safety of on-board high-pressure hydrogen fuel tanks and piping systems in hydrogen refueling station is one of the most important subjects for upcoming hydrogen society featured by fuel cell vehicles. Type 316L austenitic stainless steel is known as a material in which the effect of hydrogen on mechanical properties is very small, so JIS SUS316L is recognized as the standard material for 35MPa type on-board fuel tank liner in the Japanese standard JARI-S001. However, solution treated 316L does not always have sufficient 0.2% proof stress, and materials having higher proof stress are strongly needed. One of the solutions is work-hardening of the material, which is conventionally used for piping systems for high pressure gas facilities. In this study, the effect of hydrogen on mechanical properties of 40% cold worked 316L in high-pressure gaseous hydrogen at 45MPa was investigated. Results are as follows: Any significant effect of hydrogen was not recognized in tensile tests using round bar type specimens at room temperature and 85°C. In axial fatigue life tests using sand glass type specimens (stress ratio R = −1) at room temperature, not so large difference was observed on S-N curves in air and in high pressure hydrogen. However, a little influence was observed in fatigue crack growth tests using half inch CT specimens at room temperature (R = 0.05). Microstructure observation reveals that any martensitic transformation did not occur. The degradation of fatigue crack growth rate in high pressure gaseous hydrogen is probably caused by the work hardened δ-ferrite which is generally contained in thick materials. However the effect of hydrogen is only limited and 40% cold worked type 316L stainless steel is considered to be used in high pressure hydrogen gas just like solution treated one.


Alloy Digest ◽  
1982 ◽  
Vol 31 (11) ◽  

Abstract JESSOP JS15Cr-5Ni is a martensitic, precipitation-hardening, chromium-nickel-copper stainless steel. It offers high strength and hardness in combination with good resistance to corrosion. Typical applications include aircraft components and a variety of fabricated parts for use in corrosive, high-pressure systems. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness and fatigue. It also includes information on corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: SS-416. Producer or source: Jessop Steel Company.


Author(s):  
Qi He ◽  
Zhengli Hua ◽  
Jinyang Zheng

Austenitic stainless steel of the 300 series and their welds are widely employed in the production, storage and distribution infrastructures of gaseous and liquid hydrogen. However, hydrogen compatibility of their welds has not been completely understood, especially in high-pressure hydrogen environment. In this study, the influence of 98MPa high pressure gaseous hydrogen on the tensile properties and fracture behaviors of three kinds of S31603 weld joints were investigated, including SMAW, SAW and TIG welds. The tensile data indicated that hydrogen caused the ductility loss of the SAW and TIG weld joints, particularly for the TIG welds. For the SMAW weld joints, hydrogen had little impact on its ductility. Fractographic analysis revealed that hydrogen scarcely induced a change in the fracture mode of the SMAW welds. Different from this, the SAW and TIG welds were found to exhibit an obvious susceptibility to hydrogen embrittlement in this study, particularly for the TIG welds, based on the change of fracture features from dimples to facets, striations and secondary cracks. Additionally, both fracture surfaces of the SMAW and SAW welds contained some inclusions where the secondary cracks were promoted.


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