Role of Iron-Rich Phases and Porosity on the Ductility of Rheocast Al-Mg-Si-Alloys

Treatment of the slurry is important during RheoMetalTM casting. In this work, semi-solid slurries were prepared under different stirring intensities, using two types of stirrers: a naked rod (for regular stirring) and a rod with two blades (for intensified stir). Tensile tests were performed, investigating fracture surfaces, as well as metallographic samples. The results show that intensified stir produces castings with finer primary particles and a more homogeneous microstructure. On the other hand, more faceted Fe-rich phases are found along the α-Al grains boundary as well, due to the dissolution of Fe from the stirrers. Moreover, for intensified stir castings, the porosity found on the fracture surfaces are smaller, while more brittle eutectic phases and second (intermetallic) phases, especially Fe-rich phases, are observed. Consequently, the castings with intensified stir show worse ductility. Finally, a quantitative analysis was made regarding ductility, affected both by porosity and the presence of Fe-rich phases.

Peculiarities of stress corrosion fracture of sensitized and neutron irradiated chromium-nickel austenitic steel

The results of SEM studies of fracture surfaces for the 12Cr18Ni9 austenitic steel ruptured under a fixedtensile load in FeCl3 water solutionand in air are presented. The samples of austenized, sensitized at 650° and irradiated with neutrons (to 1020n/cm2) steel were examined. It was shown thatirradiation hardening and sensitizing annealing increased the susceptibility of steel to intergranular cracking in corrosive solution. Structural features of formation of the strain-induced α’-martensite and its reinforcing effect on fracture in various environments are discussed.

Thin films composed of Zr-doped In2O3 grains rich in fracture surfaces and cracks for photoelectrochemical water oxidation

Zr doped In2O3 thin films are prepared on FTO substrates by a two-step method: firstly, Zr-doped In(OH)3 thin films are hydrothermally deposited, and then converted to Zr-doped In2O3 films by...

Strain Rate Effect on Mechanical Properties of Cemented Backfill under Dynamic and Static Combined Loading

In order to study the influence of pillar stopping blasting on the stability of cemented backfill, the dynamic impact test under low strain rate (61.1∼86.8 s−1) was conducted on cemented backfill with two kinds of strength using three-dimensional coupled static-dynamic SHPB equipment. At the same time, the strain rate effect of failure mode, dynamic strength factor, and energy transfer of backfill were analyzed. The results show that when the cemented backfill was loaded under different strain rates in the initial three-dimensional static pressure environment, the pore compaction process was no longer obvious but directly entered the elastic deformation stage. Within the range of strain rates, the extreme value of dynamic intensity factor (DIF) of CTB230 was 6.8, while the extreme value of dynamic intensity factor of CTB310 specimen did not appear within the range of strain rates due to the improvement of the internal cementation force between particles. The fracture surfaces of specimens were perpendicular to the direction of load, and the failure mode was mainly the axial tensile failure, and the fracture surfaces were mostly close to the loading end. According to energy calculation, reflected energy accounts for 80.4%∼86.6% of incident energy; dissipated energy, 5.5%∼14.3%; transmitted energy, 5.3%∼7.9%.

Structural Reservoir Characterization of Akkas Gas Field, Western Iraq: Implications for Hydrocarbon Recovery

Akkas Field is a structural trap with a sandstone reservoir that contains proven gas condensate. The field is a faulted anticline that consists of the Ordovician Khabour Formation. The objective of this research is to use structural reservoir characterization for hydrocarbon recovery. The stratigraphic sequence of the Silurian and older strata was subjected to an uplift that developed a gentle NW-SE trending anticline. The uplifting and folding events developed micro-fractures represented by tension cracks. These microfractures, whether they are outer arc or release fractures, are parallel to the hinge line of the anticline and perpendicular to the bedding planes. The brittle sandstone layers of the reservoir are interbedded with ductile units of shale. The sandstone layers accommodate the formation of micro fractures that play a major role to increase the secondary porosity. The gas and condensate have been stored mainly through the micro fractures. Two types of drilling have been used for experimental gas production, vertical and horizontal. Horizontal drilling was parallel to both hinge line of the anticline and micro fracture surfaces that was conducted and doubled the gas production of the vertical well multiple times. However, if used the third type of drilling, directional, that is perpendicular to the hinge line and parallel to the beddings of both flanks of the anticline gas production will increase more than the horizontal drilling. The directional drilling will become perpendicular to the fracture surfaces and allow the gas and the condensate to flow into the well from all directions. Additionally, it will reduce the effect of both semi – liquid hydrocarbon condensate and vertical sediment barriers.

Modeling Acid Fracturing Treatments in Heterogeneous Carbonate Reservoirs

The goal of acid fracturing operations is to create enough fracture roughness through non-uniform acid etching on fracture surfaces such that the acid fracture can keep open and sustain a high enough acid fracture conductivity under the formation closure stress. A detailed description of the rough acid-fracture surfaces is required for accurately predicting the acid-fracture conductivity. In this paper, a 3D acid transport model was developed to compute the geometry of acid fracture for acid fracturing treatments. The developed model couples the acid fluid flow, reactive transport and rock dissolution in the fracture. We also included acid viscous fingering in our model since the viscous fingering mechanism is commonly applied in acid fracturing to achieve non-uniform acid etching. Carbonate reservoirs mainly consists of calcite and dolomite minerals but the mineral distribution can be quite heterogeneous. Based on the developed model, we analyzed the effect of mineral heterogeneity on the acid etching process. We compared the acid etching patterns in different carbonate reservoirs with different spatial distributions of calcite and dolomite minerals. We found that thin acid-etched channels can form in carbonate reservoirs with interbedded dolomite layers. When the reservoir heterogeneity does not favor growing thin acid-etched channels, we investigated how to utilize the acid viscous fingering technique to achieve the channeling etching pattern in such reservoirs. Through numerical simulations, we found that thin acid-etched channels can form inside acid viscous fingers. The regions between viscous fingers are left less etched and act as barriers to separate acid-etched channels. In acid fracturing treatments with viscous fingering, the etching pattern is largely dependent on the perforation spacing. With a proper perforation design, we can still achieve the channeling etching pattern even when the reservoir does not have interbedded dolomite layers.

Terrestrial photogrammetry: a method to gather data on fractures for DFN modelling from exposed rock surfaces

The stochastic generation of discrete fracture networks (DFN) is a method for modelling fracture patterns used to assess the in situ fragmentation in a volume of rock. The DFN modelling approach is based on the assumption that the natural fragmentation of rocks is a function of the length and connectivity of the fractures within the considered volume of rock. Thus, in order to generate a site-specific DFN, the primary geometric properties of the fracture surfaces within the rock volume (especially orientation, size and fracture intensity as well as the local spatial variability) must be defined as distribution functions (Elmo et al., 2014). The required base statistics are usually obtained from fracture analysis on boreholes, exposed rock surfaces or (to a limited extent) 3D seismics (e.g. Bisdom et al., 2014; Bemis et al., 2014). We adopted a terrestrial close-range photogrammetry approach to capture several outcrops and analyse fracture traces on the exposed rock surfaces, the chosen workflow is based around the use of free and open-source software. Images were acquired from several quarries in the Weschnitzpluton, a granodioritic to quartz monzodioritic pluton in the Bergstrasse Odenwald (e.g. Altherr et al., 1999) using a consumer-grade Nikon D5300 DSLR with fixed focal length instead of a drone or Lidar-system for legal reasons, partially tree-lined outcrops and cost efficiency. Since point clouds obtained from photogrammetry are inherently dimensionless, we used a spherical target with compass and bubble level for scale and proper spatial orientation (Froideval et al., 2019). The exact geolocation is not particularly important for the task, so the use of GPS, total station or georeferenced ground control points is not necessary. Dense point clouds were computed using the open source SfM photogrammetry suite Meshroom (AliceVision, 2021), which can be used for manual or semi-automatic detection of fracture surfaces and their orientation (Schnabel et al., 2007) and to generate orthorectified images of the rock surface to trace fracture lengths and nodes in a GIS (Nyberg et al., 2018). Our investigations proved terrestrial photogrammetry to be a valuable and easily accessible tool in the documentation of natural fracture patterns and a robust base for the generation of DFN networks.

Strain rate dependent plasticity and fracture of DP1000 steel under proportional and non-proportional loading

To assess the effect of stress state and strain rate on damage and fracture of a commercial DP1000 steel with a very fine microstructure, an extensive series of tests were performed. Using finite element simulations, eight different sample geometries, including a dogbone, a central hole, a shear and several notched samples, were designed to achieve both proportional and non-proportional stress states using conventional test benches. Tested at quasi-static, intermediate and, dynamic deformation rates, in total 175 tests were performed. Local strain fields were obtained by digital image correlation. A correction procedure was worked out to eliminate the influence of thermal softening. After testing, scanning electron microscopy was employed to analyse the fracture surfaces. Tests and fractography allowed to draw systematic conclusions on the response of the DP1000 steel. A two-stage strain rate sensitivity of strength is found with a gradually increasing slope at low strain rates and a much steeper rise at high strain rates, which is further amplified at higher triaxiality stress states. The experimentally derived fracture loci revealed a dominant, detrimental impact of the stress triaxiality that is most pronounced at intermediate strain rates. A remarkable, non-monotonic evolution of the fracture strain with strain rate is observed: the highest values were obtained at intermediate rates. Scanning electron microscopy images of the fracture surfaces indicate a void-assisted ductile fracture, though with the occurrence of brittle features triggered at dynamic strain rates. Fracture morphology and dimple features are heavily dependent on stress state, strain rate and loading path.