scholarly journals Comparison on the removal of hydrogen sulfide in biotrickling filters inoculated with Thiobacillus thioparus and Acidithiobacillus thiooxidans

2007 ◽  
Vol 10 (4) ◽  
pp. 0-0 ◽  
Author(s):  
German Aroca ◽  
Homero Urrutia ◽  
Dariela Nunez ◽  
Patricio Oyarzun ◽  
Alejandra Arancibia ◽  
...  
2009 ◽  
Vol 59 (7) ◽  
pp. 1353-1359 ◽  
Author(s):  
M. Ramirez ◽  
J. M. Gómez ◽  
G. Aroca ◽  
D. Cantero

The simultaneous removal of H2S and NH3 was investigated using two biotrickling filters packed with polyurethane foam cubes. One biotrickling filter was inoculated with Thiobacillus thioparus ATCC 23645 for the removal of H2S (BTT) and the other filter with Nitrosomonas europaea ATCC 19718 for the removal of NH3 (BNE). Three different configurations were studied by modification of the gas line and recirculation medium line. The best results were obtained with the BNE biotrickling filter after the co-immobilization of the two bacteria. A removal efficiency of 100% for 230 ppmv of NH3 and 129 ppmv of H2S was reached at an EBRT of 60 seconds. The results obtained show that it is possible to co-immobilize both microorganisms using the same recirculation medium and remove successfully H2S and NH3 from a gas mixture.


2021 ◽  
Author(s):  
Rania Ibrahim ◽  
Abdessamad El Hassni ◽  
Shahram Navaee-Ardeh ◽  
Hubert Cabana

Abstract Hydrogen sulfide (H2S) is one of the main contaminants found in biogas which is one of the end products of the anaerobic biodegradation of proteins and other sulfur-containing compounds in solid waste. The presence of H2S is one of the factors limiting the valorization of biogas. To valorize biogas, H2S and other contaminants must be removed. This study evaluated the performance of a pilot-scale biotrickling filter system on H2S removal from landfill biogas. The biotrickling filter system, which was packed with stainless-steel pall rings and inoculated with an H2S-oxidizing consortium, was designed to process 1 to 10 SCFM of biogas and used to determine the removal efficiency of a high concentration of hydrogen sulfide from landfill biogas. The biofiltration system consisted of two biotrickling filters connected in series. Results indicate that the biofiltration system reduced H2S concentration by 94–97% without reduction of the methane concentration in the outlet biogas. The inlet concentration of hydrogen sulfide, supplied to the two-phase bioreactor, was in the range of 900 to 1500 ppmv. The hydraulic retention times (HRT) of the two biotrickling filters were 3.9 and 0.9 min, respectively. Approximately 50 ppmv of H2S gas was detected in the outlet gas. The maximum elimination capacity of the biotrickling filter system was found to be 272 g H2S.m− 3.h− 1. During the biological process, the performance of biotrickling filter was not affected when the pH of the recirculated liquid decreased to 2–3. The overall performance of the biotrickling filter system was described using a modified Michaelis–Menten equation, and the Ks and Vm values for the biosystem were 34.7 ppmv and 200 mg H2S/L.h− 1, respectively.


Author(s):  
Christian Dannesboe ◽  
John Bøgild Hansen ◽  
Ib Johannsen

AbstractIn the near future, renewable energy sources will replace fossil energy. To allow full carbon utilization of renewable biomass, we have demonstrated a possible integration between a biogas reactor, an electrolysis unit, and a catalytic methanation reactor. Stringent removal of all sulfur contaminants in raw biogas is required to enable this integration. We demonstrate how existing bulk sulfur removal solutions, like a biotrickling filter loaded with Acidithiobacillus thiooxidans and impregnated activated carbon, are unable to meet this requirement. Only the main sulfur contaminant hydrogen sulfide (H2S) can effectively be removed. Contaminants carbon disulfide (CS2), dimethyl sulfide (DMS), and carbonyl sulfide (COS) will leak through the carbon filter, long before hydrogen sulfide can be detected. Utilization of surplus oxygen from the combined system is proven problem free and allows sulfur removal without introducing contaminants. Provided that a recommended sulfur guard is included, the proposed design is ready for full-scale implementation.


2006 ◽  
Vol 101 (6) ◽  
pp. 1269-1281 ◽  
Author(s):  
V.L. Barbosa ◽  
S.D. Atkins ◽  
V.P. Barbosa ◽  
J.E. Burgess ◽  
R.M. Stuetz

2009 ◽  
Vol 100 (21) ◽  
pp. 4989-4995 ◽  
Author(s):  
Martín Ramírez ◽  
José Manuel Gómez ◽  
Germán Aroca ◽  
Domingo Cantero

2006 ◽  
Vol 101 (4) ◽  
pp. 309-314 ◽  
Author(s):  
Eun Young Lee ◽  
Nae Yoon Lee ◽  
Kyung-Suk Cho ◽  
Hee Wook Ryu

2018 ◽  
Vol 77 (11) ◽  
pp. 2657-2667 ◽  
Author(s):  
A. Shammay ◽  
I. Evanson ◽  
R. M. Stuetz

Abstract Three types of odour abatement systems in sewer networks in Australia were studied for 18 months to determine the removals of different compounds. Six volatile sulfurous compounds and seven volatile organic compounds (VOCs) were further investigated. All types of odour abatement systems exhibited good removal of hydrogen sulfide with the biotrickling filters (BTFs) showing the highest consistent removal. Biofilters outperformed BTFs and activated carbon (AC) filters in the removal of dimethyl mono-, di- and tri-sulfide species at the low inlet concentrations typically found. AC filters exhibited little VOC removal with no compound consistently identified as having a removal greater than 0%. Biofilters outperformed BTFs in VOC removal, yet both had high removal variability.


2018 ◽  
Vol 6 (1) ◽  
pp. 42
Author(s):  
Odemar Cardoso Silva ◽  
Andréa Medeiros Salgado ◽  
Francisca Pessoa De França

Due to its corrosive and highly toxic character, the generation of hydrogen sulfide is a serious problem for the environment, human health, and the industry. This paper reported a new and simple methodology for aqueous hydrogen sulfide determination through the development of an optical microbial biosensor. The principle of detection was based on the aerobic and chemolithotrophic metabolism of Acidithiobacillus thiooxidans bacterial cells. Under low oxygen concentration and acidic conditions A. thiooxidans can rapidly oxidize H2S to elemental sulfur. The biochemical formation of elemental sulfur can be spectrophotometrically detected and the increase in absorbance at 620 nm exhibited a linear relationship to an H2S concentration up to 100 mg.L-1. The parameters concerning the analytical performance of the biosensor such as cell harvesting time and pH influence were measured and optimized through the optical absorption value. The biosensor was selective to H2S with no important disturbance by tested species except thiosulfate ion (11.5% error). Biosensor response expressed good repeatability (RSD = 4.46 %) and reproducibility (RSD = 4.66 %). The low cost of cell cultivation and the absence of the immobilization step make feasible the optic biosensor application.


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