scholarly journals CFD modelling of biomass catalytic fast pyrolysis in bubbling fluidized reactor: effects of catalyst parameters

2021 ◽  
Author(s):  
Yajun Qiu ◽  
Qixiang Xu ◽  
Shusheng Pang ◽  
Xiaoyuechuan Ma
Keyword(s):  
Mass Transfer ◽  
Active Sites ◽  
Fast Pyrolysis ◽  
Mass Transfer Process ◽  
Reaction Rates ◽  
Cfd Modelling ◽  
Catalytic Fast Pyrolysis ◽  
Engineering Designs ◽  
Average Size ◽  
Multi Phase

In this study, a CFD mathematical model has been developed for catalytic fast pyrolysis (CFP) of biomass. The multi-phase fluid flow, and the inter-phase momentum and energy transfer processes were modelled with Eulerian multi-phase formulas. The biomass catalyst fast pyrolysis reactions were described by using a two-stage, semi-global model. Specified secondary tar catalytic cracking process, which considers both intrinsic reaction rates and mass transfer process are embedded to the developed model by user-defined function (UDF). The developed model has then been employed to investigate the effects of structural properties of catalyst, such as specific internal area, average size of active sites, pore diameter, and tortuosity, on products yields and composition. The influences of adsorption capability of tar molecule on catalyst surface and external film mass transfer were also analyzed. The developed model can be employed for further research and engineering designs of the catalyst pyrolysis of carbonaceous materials.

Catalytic fast pyrolysis of biomass: superior selectivity of hierarchical zeolites to aromatics

2017 ◽  
Vol 19 (22) ◽  
pp. 5442-5459 ◽  
Author(s):  
L. Y. Jia ◽  
M. Raad ◽  
S. Hamieh ◽  
J. Toufaily ◽  
T. Hamieh ◽  
...  
Keyword(s):  
Mass Transfer ◽  
Aromatic Hydrocarbons ◽  
Fast Pyrolysis ◽  
Biomass Pyrolysis ◽  
Hierarchical Zeolites ◽  
Catalytic Fast Pyrolysis ◽  
Pyrolysis Of Biomass ◽  
Zeolite Crystals

Mesopores are “highways” for mass transfer inside zeolite crystals and enhance the formation of mono-aromatic hydrocarbons from biomass pyrolysis.

Simulation of volumetric heating of a moist medium with allowance for fluid mobility

2012 ◽  
Vol 9 (1) ◽  
pp. 91-93
Author(s):  
U.R. Ilyasov ◽  
A.V. Dolgushev
Keyword(s):  
Mass Transfer ◽  
Porous Medium ◽  
Numerical Solution ◽  
Heat And Mass Transfer ◽  
Transfer Process ◽  
Thermal Action ◽  
Mass Transfer Process ◽  
Low Permeability ◽  
Volumetric Heating ◽  
Drying Regime

The problem of volumetric thermal action on a moist porous medium is considered. Numerical solution, the influence of fluid mobility on the dynamics of the heat and mass transfer process is analyzed. It is established that fluid mobility leads to a softer drying regime. It is shown that in low-permeability media, the fluid can be assumed to be stationary.

Free Convective Mass Transfer at Isosceles Triangular Surfaces of Varying Inclination

2003 ◽  
Vol 68 (11) ◽  
pp. 2080-2092 ◽  
Author(s):  
Martin Keppert ◽  
Josef Krýsa ◽  
Anthony A. Wragg
Keyword(s):  
Mass Transfer ◽  
Transfer Rate ◽  
Mass Transfer Rate ◽  
Mass Transfer Process ◽  
Sulfate Solution ◽  
Convective Mass Transfer ◽  
Varying Length ◽  
Inclined Surface ◽  
Vertical Case ◽  
Limiting Diffusion Current

The limiting diffusion current technique was used for investigation of free convective mass transfer at down-pointing up-facing isosceles triangular surfaces of varying length and inclination. As the mass transfer process, copper deposition from acidified copper(II) sulfate solution was used. It was found that the mass transfer rate increases with inclination from the vertical to the horizontal position and decreases with length of inclined surface. Correlation equations for 7 angles from 0 to 90° were found. The exponent in the ShL-RaL correlation ranged from 0.247 for the vertical case, indicating laminar flow, to 0.32 for inclinations of 60 to 90°, indicating mixed or turbulent flow. The general correlation ShL = 0.358(RaL sin θ)0.30 for the RaL sin θ range from 7 × 106 to 2 × 1011 and inclination range from 15 to 90° was obtained.

Catalytic fast pyrolysis of alkali-pretreated bagasse for selective preparation of 4-vinylphenol

2019 ◽  
Vol 143 ◽  
pp. 104669 ◽  
Author(s):  
Qiang Lu ◽  
Zhen-xi Zhang ◽  
Xiao-ning Ye ◽  
Kai Li ◽  
Min-shu Cui ◽  
...  
Keyword(s):  
Fast Pyrolysis ◽  
Catalytic Fast Pyrolysis ◽  
Pretreated Bagasse

scholarly journals A Semi-Theoretical Model for Water Condensation: Dew Used in Conservation of Earthen Heritage Sites

Water ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 52
Author(s):  
Xiang He ◽  
Sijia Wang ◽  
Bingjian Zhang
Keyword(s):  
Mass Transfer ◽  
Theoretical Model ◽  
Field Experiments ◽  
Environmental Control ◽  
Mass Transfer Process ◽  
Formation Processes ◽  
Heritage Sites ◽  
Dew Formation ◽  
The Difference ◽  
Two Parameter

Dew is a common but important phenomenon. Though water is previously considered to be a threat to earthen heritage sites, artificial dew is showing potential in relic preservation. A model of dew prediction on earthen sites will be essential for developing preventive protection methods, but studies of dew formation processes on relics are limited. In this study, a two parameter model is proposed. It makes approximations according to the features of earthen heritage sites, assuming that a thin and steady air layer exists close to the air–solid interface. This semi-theoretical model was based on calculations of the mass transfer process in the air layer, and was validated by simulations of laboratory experiments (R > 0.9) as well as field experiments. Additionally, a numerical simulation, performed by the commercial software COMSOL, confirmed that the difference between fitting parameter δ and the thickness of assumed mass transfer field was not significant. This model will be helpful in developing automatic environmental control systems for stabilizing water and soluble salts, thus enhancing preventive protection of earthen heritage sites.

Multilevel cross flow rotating packed bed to enhance gas film control mass transfer process

2021 ◽  
Vol 161 ◽  
pp. 108321
Author(s):  
Qing-Qing Duan ◽  
Zhi-Guo Yuan ◽  
You-Zhi Liu ◽  
Shan-Shan Duan ◽  
Xi-Fan Duan
Keyword(s):  
Mass Transfer ◽  
Transfer Process ◽  
Cross Flow ◽  
Mass Transfer Process ◽  
Packed Bed ◽  
Rotating Packed Bed

scholarly journals CFD Modelling of a Hydrogen/Air PEM Fuel Cell with a Serpentine Gas Distributor

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 564
Author(s):  
Alessandro d’Adamo ◽  
Matteo Riccardi ◽  
Massimo Borghi ◽  
Stefano Fontanesi
Keyword(s):  
Fuel Cells ◽  
Proton Exchange Membrane ◽  
Catalyst Layer ◽  
Active Surface ◽  
Reaction Rates ◽  
Transport Processes ◽  
Proton Exchange ◽  
Sustainable Mobility ◽  
Cfd Modelling ◽  
Gas Distributor

Hydrogen-fueled fuel cells are considered one of the key strategies to tackle the achievement of fully-sustainable mobility. The transportation sector is paying significant attention to the development and industrialization of proton exchange membrane fuel cells (PEMFC) to be introduced alongside batteries, reaching the goal of complete de-carbonization. In this paper a multi-phase, multi-component, and non-isothermal 3D-CFD model is presented to simulate the fluid, heat, and charge transport processes developing inside a hydrogen/air PEMFC with a serpentine-type gas distributor. Model results are compared against experimental data in terms of polarization and power density curves, including an improved formulation of exchange current density at the cathode catalyst layer, improving the simulation results’ accuracy in the activation-dominated region. Then, 3D-CFD fields of reactants’ delivery to the active electrochemical surface, reaction rates, temperature distributions, and liquid water formation are analyzed, and critical aspects of the current design are commented, i.e., the inhomogeneous use of the active surface for reactions, limiting the produced current and inducing gradients in thermal and reaction rate distribution. The study shows how a complete multi-dimensional framework for physical and chemical processes of PEMFC can be used to understand limiting processes and to guide future development.

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