scholarly journals Reinforcement of styrene-butadiene rubber by sol-gel process in the latex.

1996 ◽  
Vol 69 (7) ◽  
pp. 485-490 ◽  
Author(s):  
Kazumasa YOSHIKAI ◽  
Masahiro YAMAGUCHI ◽  
Katsumi NISHIMURA
Keyword(s):  
Sol Gel ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Sol Gel Process ◽  
Styrene Butadiene

In situsilica reinforcement of vinyltriethoxysilane-grafted styrene-butadiene rubber by sol-gel process

2012 ◽  
Vol 128 (4) ◽  
pp. 2262-2268 ◽  
Author(s):  
Changjie Yin ◽  
Qiuyu Zhang ◽  
Junwei Gu ◽  
Jucheng Zheng ◽  
Guangbi Gong ◽  
...  
Keyword(s):  
Sol Gel ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Sol Gel Process ◽  
Styrene Butadiene

The Effect of Bis(3-Triethoxysilylpropyl) Tetrasulfide on Silica Reinforcement of Styrene-Butadiene Rubber

1998 ◽  
Vol 71 (2) ◽  
pp. 289-299 ◽  
Author(s):  
A. S. Hashim ◽  
B. Azahari ◽  
Y. Ikeda ◽  
S. Kohjiya
Keyword(s):  
Fine Particles ◽  
Sol Gel ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Mechanical Mixing ◽  
Transmission Electron ◽  
Curing Characteristics ◽  
Sol Gel Process ◽  
Styrene Butadiene

Abstract Bis(3-triethoxysilylpropyl)tetrasulfide (TESPT) was found to affect the curing characteristics and the physical properties of styrene-butadiene (SBR) gum rubber and xin situ silica-filled SBR vulcanizates. Silica incorporated by the in situ sol-gel reaction of tetraethoxysilane with TESPT showed a much higher reinforcing efficiency than did conventional mechanical mixing and the in situ method without TESPT. The higher reinforcing efficiency is attributed to the formation of a silica-rubber network, which also changed the dynamic mechanical behavior of the SBR vulcanizates. Transmission electron microscopy observations showed in situ silica incorporation of very fine particles in comparison to the sol-gel process without TESPT.

scholarly journals Effects of octamethylcyclotetrasiloxane grafting and in situ silica particle generation on the curing and mechanical properties of a styrene butadiene rubber composite

RSC Advances ◽  
2019 ◽  
Vol 9 (59) ◽  
pp. 34330-34341 ◽  
Author(s):  
Changjie Yin ◽  
Qiuyu Zhang
Keyword(s):  
Mechanical Properties ◽  
Silica Particle ◽  
Sol Gel ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Particle Generation ◽  
In Situ Silica ◽  
Rubber Composite ◽  
Styrene Butadiene

The reinforcement of octamethylcyclotetrasiloxane (D4) grafted styrene butadiene rubber (SBR-g-D4) with in situ generated silica was performed using the sol–gel reaction of tetraethoxysilane (TEOS) in latex.

Improvement of mechanical performance of solution styrene butadiene rubber by controlling the concentration and the size of in situ derived sol–gel silica particles

RSC Advances ◽  
2016 ◽  
Vol 6 (40) ◽  
pp. 33643-33655 ◽  
Author(s):  
V. Sankar Raman ◽  
A. Das ◽  
K. W. Stöckelhuber ◽  
S. B. Eshwaran ◽  
J. Chanda ◽  
...  
Keyword(s):  
Mechanical Performance ◽  
Sol Gel ◽  
Silica Particles ◽  
Polymer Chains ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Styrene Butadiene ◽  
Elastomeric Composites ◽  
Alkoxide Route

The silica particles generated from alkoxide route are grown onto the styrene butadiene polymer chains and offer a direct rubber to filler interaction. As a result, superior mechanical performance of the elastomeric composites can be realised.

DEVELOPMENT OF HIGH PERFORMANCE RUBBER COMPOSITES FROM ALKOXIDE-BASED SILICA AND SOLUTION STYRENE–BUTADIENE RUBBER

2017 ◽  
Vol 90 (3) ◽  
pp. 467-486 ◽  
Author(s):  
Sankar Raman Vaikuntam ◽  
Eshwaran Subramani Bhagavatheswaran ◽  
Klaus Werner Stöckelhuber ◽  
Sven Wießner ◽  
Gert Heinrich ◽  
...  
Keyword(s):  
High Performance ◽  
Sol Gel ◽  
Rolling Resistance ◽  
Silica Particles ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Mechanical Reinforcement ◽  
Precipitated Silica ◽  
Alkoxide Method ◽  
Styrene Butadiene

ABSTRACT The solution SBR and silica-based composites are prepared by hydrolysis of tetraethylorthosilicate in the presence of an organic solution of SBR and n-butylamine as catalyst. Further addition of bis[3-(triethoxysilyl)propyl]tetrasulfide, a silane coupling agent, improves the performance and properties of the composites. All the results are compared with commercial precipitated silica at similar loading conditions. The generated silica particles from this alkoxide route resulted in lower Mooney viscosity of the compound and showed less filler flocculation compared with standard commercial precipitated silica in reference compounds. A detailed dynamic mechanical study also indicated that alkoxide silica in model tire compounds could offer a lower rolling resistance and a higher wet skid resistance compared to the reference. Other properties such as heat build-up, rebound resilience, and hysteresis loss were found to be very promising for alkoxide silica composites, too. The silica particles (aggregated) developed by the alkoxide method were relatively large (∼150–200 nm) compared with the primary particles of precipitated commercial silica. The synthesis of sol–gel silica particles in presence of the polymer allowed for the trapping of some polymer molecules inside the filler aggregates and therefore offers exceptional mechanical reinforcement of the rubber.

Sign in / Sign up

Export Citation Format

Share Document