Onset of local ordering in some copper-based alloys: critical solute concentration vis-a-vis various solutionhardening parameters

Open Physics ◽  
2008 ◽  
Vol 6 (4) ◽  
Author(s):  
Muhammad Butt ◽  
Mozina Noshi ◽  
Farooq Bashir

AbstractThe mode of planar distribution of solute atoms in Cu single crystals alloyed with 0.5 to 8.0 at.%Ge has been investigated via the temperature dependence of the critical resolved shear stress of these alloys. It is found that there exists a critical solute concentration c m ≈ 5 at.%Ge below which the distribution of solute atoms in the crystal is random, and above which some local ordering occurs. This together with such data available in the literature for Cu-Zn, Cu-Al and Cu-Mn alloys, i.e. c m ≈7 at. %Zn, 7 at.%Al and 1 at.%Mn, when examined as a function of the size-misfit factor δ = (1/b)(db/dc)of a given binary alloy system, shows that the value of c m strongly depends on δ; the smaller the magnitude of δ, the greater the value of c m and vice versa. Also, the value of c m is found to correlate well with the electron-to-atom ratio (e/a)of the Cu-Zn, Cu-Al, Cu-Ge and Cu-Mn alloys with the solute concentration c = c m. However, no systematic correlation exists between the critical solute concentration c m for the onset of local ordering and the modulus-mismatch parameter η = (1/G)(dG/dc).

2007 ◽  
Vol 561-565 ◽  
pp. 459-462
Author(s):  
Katsushi Tanaka ◽  
Hiromitsu Ide ◽  
Yoshinori Sumi ◽  
Kyosuke Kishida ◽  
Haruyuki Inui

Compressive deformation of L10-ordered single crystals of FePd whose c/a ratio less than unity have been investigated from room temperature to 823 K. The results show that the critical resolved shear stress (CRSS) for octahedral glide of ordinary dislocations is smaller than that of super-lattice dislocations in all the temperature range investigated, that is the opposite sense to the case of Ti-56 mol% Al. The CRSS for ordinary dislocations virtually independent to the temperature. On the other hand, the CRSS for super dislocations exhibits a weak positive temperature dependence from room temperature up to 573 K and decreases in higher temperatures.


2008 ◽  
Vol 1128 ◽  
Author(s):  
Katsushi Tanaka ◽  
Wang Chen ◽  
Kyosuke Kishida ◽  
Norihiko L. Okamoto ◽  
Haruyuki Inui

AbstractCompressive deformations of L10-ordered single crystals of FePd have been investigated from room temperature to 873 K. The critical resolved shear stress for superlattice dislocations is hard to determine resulting from buckling that occurs after a small amount of conventional plastic deformation. The CRSS for superlattice dislocations determined from yield stress is significantly larger than that of ordinary dislocations. The CRSS for octahedral glide of ordinary and superlattice dislocations are virtually independent of the temperature, and the positive temperature dependence of the yield stress is not observed for both, ordinary and superlattice dislocations, by the present experiments.


1990 ◽  
Vol 213 ◽  
Author(s):  
R.D. Field ◽  
D.F. Lahrman ◽  
R. Darolia

ABSTRACTA detailed study of deformation of NiAl single crystals in two soft orientations, <110> and <111>, has been conducted. The Schmid factor favors {100} slip in the former and {110} slip in the latter. Detailed dislocation analysis, critical resolved shear stress measurements, and slip trace analysis have been performed to determine the nature of dislocation motion and interactions in this material. Particular attention is given to prismatic loops formed during deformation, since the shapes of these loops reveal the active slip planes. Similar loop morphologies observed in elevated temperature [001] oriented tensile specimens are also discussed.


The problem of accommodation of constrained deformation by slip and twinning has been analysed. The analysis is based on Taylor’s least work hypothesis. In this analysis, the operative combination of slip and twinning systems is found by minimizing the orientation factor M = (∑ i s i +α∑ i t i )/ ε , where s i and t i are the simple shears resulting from slip and twinning respectively, α is the ratio of the critical resolved shear stress for twinning against slip, and Ɛ is the external strain. Detailed calculations have been made for face-centred cubic crystals deformed by plane strain compression. Experimental observations on deformed single crystals of a Co–8% Fe alloy indicate good agreement with the analysis. Implications of the present study to the twinning observations of Heye & Wassermann on rolled Ag crystals are discussed.


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