Neutrino Catalysis of Nuclear Synthesis Reactions in Cold Hydrogen

This review summarizes the synthesis, reactions, and biological activities of tetrazolo[1,5-a]quinoline derivatives. These derivatives were synthesized by several methods such as i) from the reaction of 2-chloroquinoline with sodium azide ii) from diazotization 2-hydrazinylquinoline derivatives, and iii) from intramolecular cyclocondensation of 2-azidoarylidenes. Also, the chemical reactions and pharmacological activities of some tetrazoloquinolines such as tetrazolo[1,5-a]quinoline-4-carbaldehyde, 5-chlorotetrazolo[ 1,5-a]quinoline, 4-(chloromethyl)tetrazolo[1,5-a]quinoline, tetrazolo[1,5- a]quinoline-4-carboxylic acid, and 5-azidotetrazolo[1,5-a]quinoline were discussed.

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Pyrrole: Chemical Synthesis, Microwave Assisted Synthesis, Reactions and Applications: A Review

Current Organic Chemistry ◽

10.2174/13852728113179990040 ◽

2013 ◽

Vol 17 (20) ◽

pp. 2279-2304 ◽

Cited By ~ 64

Author(s):

Shrinivas Joshi ◽

Uttam More ◽

Venkatrao Kulkarni ◽

Tejraj Aminabhavi

Keyword(s):

Chemical Synthesis ◽

Microwave Assisted Synthesis ◽

Microwave Assisted ◽

Synthesis Reactions

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1,4-Diazepines: A Review on Synthesis, Reactions and Biological Significance

Current Organic Synthesis ◽

10.2174/1570179416666190703113807 ◽

2019 ◽

Vol 16 (5) ◽

pp. 709-729 ◽

Cited By ~ 4

Author(s):

Muhammad A. Rashid ◽

Aisha Ashraf ◽

Sahibzada S. Rehman ◽

Shaukat A. Shahid ◽

Adeel Mahmood ◽

...

Keyword(s):

Biological Activities ◽

Biological Significance ◽

Biological Evaluation ◽

Wide Range ◽

Pharmaceutical Industries ◽

Biological Aspects ◽

Synthetic Routes ◽

Biological Attributes ◽

Synthesis Reactions ◽

Potential Use

Background:1,4-Diazepines are two nitrogen containing seven membered heterocyclic compounds and associated with a wide range of biological activities. Due to its medicinal importance, scientists are actively involved in the synthesis, reactions and biological evaluation of 1,4-diazepines since number of decades.Objective:The primary purpose of this review is to discuss the synthetic schemes and reactivity of 1,4- diazepines. This article also describes biological aspects of 1,4-diazepine derivatives, that can be usefully exploited for the pharmaceutical sector.Conclusion:This review summarizes the abundant literature on synthetic routes, chemical reactions and biological attributes of 1,4-diazepine derivatives. We concluded that 1,4-diazepines have significant importance due to their biological activities like antipsychotic, anxiolytic, anthelmintic, anticonvulsant, antibacterial, antifungal and anticancer. 1,4-diazepine derivatives with significant biological activities could be explored for potential use in the pharmaceutical industries.

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Accelerating the optimization of enzyme-catalyzed synthesis conditions via machine learning and reactivity descriptors

Organic & Biomolecular Chemistry ◽

10.1039/d1ob01066b ◽

2021 ◽

Author(s):

Zhongyu Wan ◽

Quan-De Wang ◽

Dongchang Liu ◽

Jinhu Liang

Keyword(s):

Machine Learning ◽

Optimal Synthesis ◽

Human Knowledge ◽

Crucial Importance ◽

Reactivity Descriptors ◽

Synthesis Conditions ◽

Wide Range ◽

Synthesis Reactions ◽

Selection Of

Enzyme-catalyzed synthesis reactions are of crucial importance for a wide range of applications. An accurate and rapid selection of optimal synthesis conditions is crucial and challenging for both human knowledge...

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Low Temperature Large Scale CVD Synthesis of Nano Onion-Like Fullerenes

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.490-495.3211 ◽

2012 ◽

Vol 490-495 ◽

pp. 3211-3214 ◽

Cited By ~ 1

Author(s):

Lei Shan Chen ◽

Cun Jing Wang

Keyword(s):

Electron Microscopy ◽

Low Temperature ◽

Aluminum Hydroxide ◽

Large Scale ◽

Iron Catalyst ◽

Chemical Vapor ◽

X Ray Diffraction ◽

Transmission Electron ◽

Naoh Solution ◽

Synthesis Reactions

Synthesis reactions were carried out by chemical vapor deposition using iron catalyst supported on aluminum hydroxide at 400 °C and 420 °C, in the presence of argon as carrier gas and acetylene as carbon source. The aluminum hydroxide support was separated by refluxing the samples in 40% NaOH solution for 2 h and 36% HCl solution for 24 h, respectively. The samples were characterized by field-emission scanning electron microscopy, energy dispersive spectroscopy, high-resolution transmission electron microscopy and X-ray diffraction. The results show that carbon nanotubes were the main products at 420 °C, while large scale high purity nano onion-like fullerenes encapsulating Fe3C, with almost uniform sizes ranging from 10-50 nm, were obtained at the low temperature of 400 °C.

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Generalizations of reaction rate integrals with applications to nuclear synthesis in astrophysics and some corrections to published literature

Astrophysics and Space Science ◽

10.1007/bf00659413 ◽

1993 ◽

Vol 203 (1) ◽

pp. 43-52 ◽

Cited By ~ 1

Author(s):

W. J. Anderson ◽

A. M. Mathai

Keyword(s):

Reaction Rate ◽

Nuclear Synthesis

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Polymer-supported complexes. Part 2. Polystyrene-anchored pentane- 2,4-dionato-complexes of transition metals: synthesis, reactions, and catalytic properties

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9820000445 ◽

1982 ◽

pp. 445 ◽

Cited By ~ 14

Author(s):

Sumit Bhaduri ◽

Hanif Khwaja ◽

Vinod Khanwalkar

Keyword(s):

Transition Metals ◽

Catalytic Properties ◽

Complexes Of Transition Metals ◽

Polymer Supported ◽

Synthesis Reactions

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ChemInform Abstract: Synthesis, Reactions, and Preliminary Evaluations of Enaminone Esters.

ChemInform ◽

10.1002/chin.199419100 ◽

2010 ◽

Vol 25 (19) ◽

pp. no-no

Author(s):

I. O. EDAFIOGHO ◽

J. A. MOORE ◽

V. A. FARRAR ◽

J. M. NICHOLSON ◽

K. R. SCOTT

Keyword(s):

Synthesis Reactions

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Synthesis of Steroid–Porphyrin Conjugates from Oestradiol, Oestrone, and Lithocholic Acid

Australian Journal of Chemistry ◽

10.1071/ch14080 ◽

2014 ◽

Vol 67 (11) ◽

pp. 1632 ◽

Cited By ~ 2

Author(s):

Fargol Taba ◽

Tze Han Sum ◽

Paul J. Sintic ◽

Ann H. Lundmark ◽

Maxwell J. Crossley

Keyword(s):

Nucleophilic Substitution ◽

Substitution Reaction ◽

Lithocholic Acid ◽

The Other ◽

Nucleophilic Substitution Reaction ◽

Porphyrin Synthesis ◽

Synthesis Reactions ◽

Steroid Conjugates ◽

The Way

The synthesis of porphyrin–steroid conjugates is examined using the natural steroids oestradiol, oestrone, and lithocholic acid as precursors. Two strategies differing in the timing of formation of the steroid–porphyrin linkage leading to four different construction motifs are explored. Two approaches are based on a strategy of introduction of steroidal components in the porphyrin-forming reaction involving condensation of steroidal-alkylaldehydes and pyrrole to give 5,10,15,20-tetrakis(steroidal-alkyl)porphyrins and differ in the way in which the required aldehyde is introduced to the steroidal component. In the other strategy, a steroidal component is introduced by post-porphyrin synthesis reactions and here also two approaches were explored, one involving nucleophilic substitution and the other esterification. Of the four approaches investigated, the most efficient and most versatile one attaches the steroidal components late in the sequence to a 5,10,15,20-tetra(ω-haloalkyl)porphyrin by a nucleophilic substitution reaction. In this way, a 5,10,15,20-tetrakis[oestrone-linked-heptyl)porphyrin was obtained in 47 % yield.

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