scholarly journals Heavy Metal Pollution and Ecological Risk Assessment in Soils Adjacent to Electrical Generators in Ramadi City, Iraq

2021 ◽  
pp. 1077-1087
Author(s):  
Lina F.D. AL-Heety ◽  
Omer M. Hasan ◽  
Emad A. Mohammed Salih Al-Heety

     This study aims to evaluate the concentration of the heavy metals (Co, Cd, Cr, Cu, Ni, Pb, and Zn) and their ecological risk in soils adjacent to the power generators of Ramadi city, Iraq. The soil samples were collected from a depth of 20cm. The obtained results showed that the mean concentrations of heavy metals (HMs) are ranked as in the following order: Cr (360.90mg/kg) > Ni (283.65mg/kg) > Zn (190.96mg/kg) > Pb (130.75 mg/kg) > Cu (36.54 mg/kg) > Co (16.62 mg/kg) > Cd (2.55 mg/kg). The mean values of HMs concentration exceed the international guidelines. The result of correlation matrix analysis at P £ 0.05 showed significant correlations between the concentrations of HMs. These correlations are interpreted in the context of a common source of pollution and/or common origin. Results of the potential ecological risk factor assessment of metal i (Eir) in soil adjacent to the power generators  of Ramadi city showed that the Eir values take the following descending order: Ni (354.56, very severe) > Cd (255.31, severe) , Co (207.77, severe) > Zn (88.69, heavy) > Cu (25.73, light) > Cr (17.43, light) > Pb (12.0, light). The potential ecological risk index (RI) values are classified as severe ecological risk for all studied heavy metals. This study provides the environmental protection managers and decision-makers with important information about the risk of using electrical generators in residential neighborhoods.

The study assessed the ecological risk and polluting load of heavy metals (Cd, Cr, Cu, Ni, Pb and Zn) in surface soils within Bori Urban. The composite soil samples collected from different locations were prepared and atomic absorption spectrophotometer (AAS) was used for the analysis of the heavy metals. From the results of the analysis, the mean concentrations (mg/kg) of the heavy metals decreased in the order Cu (37.42) > Ni (34.06) > Cr (28.66) > Zn (7.75) >Pb (2.03) > Cd (0.89). The mean concentrations of Cd, Cu, and Ni were above USEPA soil guidelines and world unpolluted soil average, while those of Pb and Zn were below. The mean concentrations of the heavy metals from the study locations were all above that of the control location. The findings indicated that the urban soils of the study were loaded with heavy metals due to anthropogenic activities. The anthropogenic percentage input was in the range of 63.92 - 89.13 above 50% indicating anthropogenic origin of the heavy metals in soils of the study area. The results of ecological risk index (Er) indicated that Cd with Er (467.40) contributed up to 94.51% to the potential ecological risk index (RI) while Zn (0.78) contributed 0.16%. The heavy metals under study posed highly strongly potential ecological risk with RI value of 494.56 to the Bori urban soil due to anthropogenic activities. The ANOVA result of FCal 6.42 > [F(5.30) = 2.53, P< 0.05)] revealed significant differences between the soil sample mean values due to different anthropogenic pollution sources with different loads of heavy metals as pollutants. The Omega Squared (w2) value of 0.52 > 0.14 showed very strong interactive relationship among the heavy metals to bring about high level of ecological potential risk of the urban soils in the study area. Based on the findings, the surface soils have elevated load of heavy metals thereby posing ecological potential risk to Bori urban soils. Therefore, there should be periodic monitoring and environmental audit by relevant authorities to ensure good soil quality of Bori urban soil. Keywords: Potential ecological risk, pollution load, Bori Urban, Anthropogenic Percentage input, contamination Factor.


2014 ◽  
Vol 955-959 ◽  
pp. 2280-2284
Author(s):  
Kai Yue Gong ◽  
Pei Shi Qi ◽  
Yun Zhi Liu

In this study, the distribution and enrichment characters of heavy metals were explored. And the potential ecological risk levels of heavy metals were evaluated by geo-accumulation index method and potential ecological risk index method. The concentrations of heavy metals in sediments of Harbin section of Songhua River are: Zn>Pb>Cr>Cu>Ni>Cd. The enrichment degree of Zn is the highest, while Cd is the lowest. The potential ecological risk indexes of heavy metals in the sediments of section of Songhua River in Harbin are: Cd>Pb>Cu>Zn>Ni>Cr. The main heavy metals pollution is Cd, which has low content but considerable potential ecological risk and contributes most to RI. The ecological risk level of heavy metals in the sediments of the section of Songhua River in Harbin is moderate.


2012 ◽  
Vol 610-613 ◽  
pp. 928-931 ◽  
Author(s):  
Hui Min Zhang ◽  
Hui Zhang ◽  
Ai Min Song ◽  
Jian Qiao Qin ◽  
Ming Wei Song

This paper was seleced Qingyuan as a case study, in order to analyze Hg, As, Cu, Zn, Pb, Cd, Ni, Cr concentrations of the soil samples. And used the Hakanson potential ecological risk index method to assess the potential ecological risks of concentrations of heavy metals in soil. The results shows that the average concentration of Hg, As, Cu, Zn, Pb, Cd, Ni, Cr in soil is 6.45, 0.26, 20.25, 119.11, 181.67, 189.22, 0.27, 32.92, 201.35 mg•kg-1 respectively. The rank by severity of ecological risk as Hg > Cu > Pb > As > Cr > Cd > Ni > Zn, based on their single-element indexes. Heavy metals in several samples of the soil have posed a serious threat on the ecosystem.


Author(s):  
L. Salami ◽  
J. G. Akinbomi ◽  
R. J. Patinvoh

Soil contaminated with heavy metals poses an ecological risk especially to public health. The aim of this work is to assess the ecological risk of heavy metals in soil of Lagos State University (LASU), Epe, Lagos State, Nigeria. Soil samples were collected from 8 different points in LASU which were stored in various polythene bags labeled SS1 – SS8. A control sample was taken 1 km away from LASU and was labeled SC9. All the sampling locations were identified using handheld Global Positioning System (GPS) for the purpose of universal identification. The soil samples were analysed for nickel (Ni), lead (Pb), copper (Cu), Zinc (Zn), chromium (Cr), cadmium (Cd) and Iron (Fe) using Atomic Absorption Spectrophotometer. Enrichment factor (EF), potential ecological risk (Ei) and ecological risk index (RI) were carried out using the data from the analysis. The results revealed that all the EF values were less than 2 except that of lead in SS1. The Ei values were less than 40 except that of lead in SS1. Moreover RI values of all the soil samples investigated were less than 150. It was obvious from this work that the soil of LASU, Epe, Lagos State, were not enriched with heavy metals and have a low potential ecological risk.


Water ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1855 ◽  
Author(s):  
Zike Zhou ◽  
Yongping Wang ◽  
Haowei Teng ◽  
Hao Yang ◽  
Aiju Liu ◽  
...  

In this study, the concentrations of seven heavy metals (Cr, Ni, Cu, Zn, As, Hg, and Pb) and Pb isotope in a sediment core from the Shuanglong reservoir, Southwestern China, were investigated. Based on the constant rate of supply (CRS) model, the age span of a 60 cm sediment sample was determined to range from the years 1944 to 2015. Combined with chronology and heavy metal content, the evolution of the sources and pollution levels of heavy metals showed a changing trend composed of various stages. The sources of heavy metals transitioned from natural origins in 1944–1964 to industrial origins in 1965–2004. The subsequent reduction in heavy metal content was mainly due to the vigorous implementation of environmental protection policies from 2005 to 2012. In recent years (2013–2015), the heavy metal content has increased due to frequent human activity. Principal component analysis (PCA), correlation analysis, and the coefficient of variation (CV) analysis indicated that Cr, Ni, Cu, Zn, and As were derived from natural processes, Pb mainly came from automobile manufacturing, and Hg was mainly from industrial sources. The values of the geo-accumulation index (Ig), single pollution index (Pi), and single potential ecological risk index (Er) showed that the contamination of Hg and Pb was slight to moderate. Moreover, the values of the potential ecological risk index (RI), pollution load index (PLI), and Nemerow index (PN) indicated that the Shuanglong reservoir is under low ecological risk.


2021 ◽  
Vol 9 (2) ◽  
pp. 025-035
Author(s):  
Edori ES ◽  
Iyama WA ◽  
Edori OS

Soil samples were collected at a depth of 0-30cm within two steel markets and a control site in Port Harcourt, Rivers State Nigeria to assess the level of heavy metals (Fe, Pb, Cu, Cd, Cr, Ni and As) in the environment. Atomic Adsorption Spectrophotometer was used to analyze the samples for heavy metals. The concentrations of all the heavy metals in the steel rods markets exceeded that of the control. The results indicated that heavy metals concentrations in the sites were in the order; Mile III > Kala > RSU. The average levels of contamination of heavy metals recorded followed the order Fe > Cr > Cu > Pb > Ni > As > Cd in Mile III, Fe > Pb > Cu > Cr > Ni > As > Cd in Kala and Fe > Cu > Pb > Cr > Ni > As > Cd in RSU (control). Mean concentrations obtained for heavy metals within the months of investigation were; 1420.931±9.155, 7.753±0.184, 8.730±0.050, 2.843±0.124, 9.428±0.122, 7.433±0.047 and 3.732±0.047 mg/Kg for Fe, Pb, Cu, Cd, Cr, Ni and As respectively at the mile III station, while the mean concentrations of heavy metals observed at the Kala station were; 1161.173±1.823, 9.425±0.054, 7.596±0.027, 1.425±0.020, 6.507±0.006, 5.455±0.033 and 1.901±0.010 mg/Kg for Fe, Pb, Cu, Cd, Cr, Ni and As respectively. The mean values of heavy metals concentrations observed at the RSU station within the period were; 892.064±1.025,5.603±0.007, 5.841±0.051, 0.173±0.005, 3.389±0.009, 2.309±0.010 and 0.706±0.006 mg/Kg for Fe, Pb, Cu, Cd, Cr, Ni and As respectively. Pollution assessment models used for assessing the anthropogenic input on the quality of the soil in the area using the control site as the basis of judgment were: contamination factor (CF), pollution load index (PLI), contamination degree (CD), modified contamination degree (mCD), potential ecological risk coefficient (Eir), potential ecological risk index (RI), Geo-accumulation index (Igeo) and anthropogenicity. These indices revealed that the steel markets were contaminated and polluted and poses ecological risks by heavy metals, even though the values obtained were still below the WHO acceptable limits. The steel rods markets need to be adequately monitored and regulated to avoid further soil contamination by heavy metals to a degree that will be dangerous to human health.


2021 ◽  
Vol 2021 ◽  
pp. 1-7
Author(s):  
Xiaojuan Zhang ◽  
Yutao Zhang

With the aim of revealing the potential ecological risk and distribution characteristics of heavy metals on the surface sediment at the Shawan River section of Yelang Lake, the following three analyses were first performed: (1) analysis of grain-size composition on sediment samples collected at seven different sites in the water-level-fluctuation zone (WLFZ); (2) analysis of bulk sediment content of six heavy metals, namely, Cd, Cr, Pb, Mn, Zn, and Cu; and (3) the correlation analysis of grain-size composition and heavy metal content in the sediment. Afterwards, the approach of Hakanson potential ecological risk index was employed to analyze the risk of heavy metal pollution in sediments of seven WLFZ plots. The outcomes indicate that (1) the mean sediment grain size at each sampling site was generally >0.063 mm, with gravel grains (>1 mm) and sand grains (0.22–1 mm) accounting for the largest proportions; (2) the site-averaged mean sediment content of each of the six heavy metals was significantly higher than their respective geochemical background contents in the sediment of Guizhou Province, and the grain-size dependence of the bulk sediment content of heavy metals was not significant; (3) the distribution of Cr was relatively independent of other metals, which was in contrast to notable positive correlations observed between other metals; and (4) in accordance with the approach of Hakanson potential ecological risk index, for these heavy metals, their potential ecological risk reduced by the order of Zn < Cr < Cu < Pb < Cd, with Cd having a mean potential risk index (Ei) of 566.13, suggestive of a very high level of potential ecological risk, Zn, Cr, and Cu having a mild potential ecological risk, and Pb having moderate potential ecological risk. Cd largely contributes to the comprehensive ecological risk index RI is the largest, thereby having important environmental implications.


2019 ◽  
Vol 6 (3) ◽  
pp. 151-156 ◽  
Author(s):  
Amir Hossein Baghaie ◽  
Forough Aghili

Background: Soil pollution with heavy metals seriously threatens soil quality, food safety, and humanhealth. This study was conducted to determine the soil pollution level and ecological risk assessmentof different heavy metals in agricultural soils around Nakhlak Pb-Zn mine, located in Anarak district,Nain county of Isfahan province.Methods: A total of 50 soil samples were collected from agricultural land around Nakhlak mine andanalyzed to determine the concentrations of Pb, Cd, Zn, Ni, Cu, and Mn. The geo-accumulation index(Igeo), enrichment factor (EF), and potential ecological-risk index (Er) were used to assess the level ofsoil pollution with heavy metals.Results: The mean concentrations of Pb, Cd, Zn, Ni, Cu, and Mn were 355, 2.72, 347, 26, 36, and505 mg/kg, respectively, which were higher than the background values of world soils. Based on theIgeo index, the study area was moderately to heavily contaminated with Pb and Zn, uncontaminated tomoderate contaminated with Cd and Cu, and uncontaminated with Mn and Ni. According to the EFvalues, the study soil was moderately contaminated with Mn, Ni, and Cu, significantly contaminatedwith Cd and Zn, and highly enriched with Pb. The RI values showed a moderate level of heavy metalscontamination in the study soil.Conclusion: According to the results, the ecological risk of heavy metals for ecosystem in agriculturallands around Nakhlak Pb-Zn mine is moderate. However, the contamination status should be consideredperiodically.


2021 ◽  
Author(s):  
Bingyan Jin ◽  
Jinling Wang ◽  
Wei Lou ◽  
Liren Wang ◽  
Jinlong Xu ◽  
...  

Abstract Rivers in urban environments are significant components of their ecosystems but remain under threat of pollution from unchecked discharges of industrial sewage and domestic wastewater. Such river pollution, particularly over the longer term involving heavy metals, is an issue of worldwide concern regarding risks to the ecological environment and human health. In this study, we investigate the long-term pollution characteristics of the Huafei River, an important urban river in Kaifeng, China. River sedimentary samples were analyzed, assessing the degree and ecological risk of heavy metal pollution using the geo-accumulation index and potential ecological risk index methods; whilst Pearson’s correlation, principal component, and cluster analyses were used to identify the sources of pollution. The results show that heavy metal concentrations are significantly higher than their corresponding fluvo-aquic soil background values in China, and the geo-accumulation indexes indicate, that of the 8 heavy metals identified, Hg is most prevalent, followed in sequence by Cd > Zn > Cu > Pb > Ni > As > Cr. The potential ecological risk index of the Huafei river is very high, with the potential ecological risk intensity highest in the midstream and downstream sections where it is recommended that pollution control is carried out, especially concerning Hg and Cd. Long-term sequence analysis indicates that Cu and Pb dropped sharply from 1998 to 2017, but rebounded in 2019, and that Zn shows a continuous decreasing trend. Four main sources for the heavy metal contaminants were identified: Cr, Cu, Ni, Pb, Zn and Hg derived mainly from industrial activities, traffic sources and natural sources; Cd originated mainly from industrial and agricultural activities; whilst As was mainly associated with industrial activities. It is anticipated that the findings of this study will provide theoretical references for the effective control and scientific management of heavy metal pollution in the Huafei River and its surrounding areas.


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