Biofuels, such as canola methyl ester (CME) and soy-methyl ester (SME) derived from vegetable oil, are alternative sources of energy that have been developed to reduce the dependence on petroleum-based fuels. In the present study, CME, SME, and commercial Jet-A fuel were tested in a porous-media burner at an equivalence ratio of 0.8 at the burner entrance. The measured combustion characteristics included NOx and CO emission indices, radiative fraction of heat release, and axial temperature profile in the surface stabilized and extended flame. The effects of fuel on the injector and porous-media durability were also documented. The NOx emission index was higher for the SME and CME flames than that of the Jet-A flame. Furthermore, the axial temperature profiles were similar for all the flames. The prolonged use of CME and SME resulted in more solid-particle deposition on the interior walls of the injector and within the structure of the porous medium than for Jet-A fuel, thereby increasing the restriction to the fuel/air flow and pressure drop across the burner.