HYDROTHERMAL CONVERSION OF HYDROCARBON FLUID OF THE ASHALCHINSKY DEPOSIT NEAR A SUPER CRITICAL WATER POINT

Author(s):  
A. I. Lakhova ◽  
◽  
S. M. Petrov ◽  
E. G. Moiseeva ◽  
V. S. Balitsky ◽  
...  
2021 ◽  
Author(s):  
Xinpeng Zhao ◽  
Zhimin Zhou ◽  
hu luo ◽  
Yanfei Zhang ◽  
Wang Liu ◽  
...  

Combined experiments and density functional theory (DFT) calculations provided insights into the role of the environment-friendly γ-valerolactone (GVL) as a solvent in the hydrothermal conversion of glucose into lactic acid...


Fuel ◽  
2021 ◽  
Vol 302 ◽  
pp. 121166
Author(s):  
Fatih Güleç ◽  
Luis Miguel Garcia Riesco ◽  
Orla Williams ◽  
Emily T. Kostas ◽  
Abby Samson ◽  
...  

Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4492
Author(s):  
Komeil Kohansal ◽  
Kamaldeep Sharma ◽  
Saqib Sohail Toor ◽  
Eliana Lozano Sanchez ◽  
Joscha Zimmermann ◽  
...  

This study focuses on the valorization of the organic fraction of municipal solid waste (biopulp) by hydrothermal liquefaction. Thereby, homogeneous alkali catalysts (KOH, NaOH, K2CO3, and Na2CO3) and a residual aqueous phase recirculation methodology were mutually employed to enhance the bio-crude yield and energy efficiency of a sub-critical hydrothermal conversion (350 °C, 15–20 Mpa, 15 min). Interestingly, single recirculation of the concentrated aqueous phase positively increased the bio-crude yield in all cases, while the higher heating value (HHV) of the bio-crudes slightly dropped. Compared to the non-catalytic experiment, K2CO3 and Na2CO3 effectively increased the bio-crude yield by 14 and 7.3%, respectively. However, KOH and NaOH showed a negative variation in the bio-crude yield. The highest bio-crude yield (37.5 wt.%) and energy recovery (ER) (59.4%) were achieved when K2CO3 and concentrated aqueous phase recirculation were simultaneously applied to the process. The inorganics distribution results obtained by ICP reveal the tendency of the alkali elements to settle into the aqueous phase, which, if recovered, can potentially boost the circularity of the HTL process. Therefore, wise selection of the alkali catalyst along with aqueous phase recirculation assists hydrothermal liquefaction in green biofuel production and environmentally friendly valorization of biopulp.


2012 ◽  
Vol 34 (3) ◽  
pp. 319 ◽  
Author(s):  
Anke S. K. Frank ◽  
Chris R. Dickman ◽  
Glenda M. Wardle

The activities of livestock in arid environments typically centre on watering points, with grazing impacts often predicted to decrease uniformly, as radial piospheres, with distance from water. In patchy desert environments, however, the spatial distribution of grazing impacts is more difficult to predict. In this study sightings and dung transects are used to identify preferred cattle habitats in the heterogeneous dune system of the Simpson Desert, central Australia. The importance of watering points as foci for cattle activity was confirmed and it was shown that patchily distributed gidgee woodland, which comprises only 16% of the desert environment, is the most heavily used habitat for cattle away from water and provides critical forage and shade resources. By contrast, dune swales and sides, which are dominated by shade- and forage-deficient spinifex grassland and comprise >70% of the available habitat, were less utilised. These results suggest that habitat use by cattle is influenced jointly by water point location and by the dispersion of woodland patches in a resource-poor matrix. The findings were used to build a modified conceptual model of cattle habitat use which was compared with an original piosphere model, and the consequences for wildlife in environments where the model applies are discussed.


Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1413
Author(s):  
Rafał Panek ◽  
Jarosław Madej ◽  
Lidia Bandura ◽  
Grzegorz Słowik

Nowadays, using fly ash for zeolites production has become a well-known strategy aimed on sustainable development. During zeolite synthesis in a hydrothermal conversion large amount of post-reaction solution is generated. In this work, the solution was used as a substrate for Na-A and Na-X zeolites synthesis at laboratory and technical scale. Obtained materials were characterized using particle size analysis, X-ray diffraction (XRD), X-ray fluorescence spectroscopy (XRF), transmission electron microscopy (TEM), Fourier transformed infrared spectroscopy (FTIR), and nitrogen adsorption/desorption isotherm. Produced zeolites revealed high purity (>98%) and monomineral zeolitic phase composition. The SiO2 content was in the range 39–42% and 40–38%, whereas Al2O3 content was 23–22% and 25–26% for Na-X and Na-A, respectively. TEM and BET analyses revealed Na-X zeolite pores were almost identical to commercial 13X with SBET in the range 671–734 m2/g. FTIR indicated slight differences between materials obtained at laboratory and technical scale in Si-O-(Si/Al) bridges of the zeolitic skeleton. The results showed good replicability of the laboratory process in the larger scale. The proposed method allows for waste solution reusability with a view to highly pure zeolites production in line with circular economy assumptions.


2010 ◽  
Author(s):  
Heng Zhong ◽  
Fangming Jin ◽  
Bing Wu ◽  
Hongjuan Chen ◽  
Guodong Yao ◽  
...  

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