scholarly journals Synthesis And Excited State Processes of Arrays Containing Amine-Rich Carbon Dots and Unsymmetrical Rylene Diimides

Author(s):  
Luka Dordevic ◽  
Michele Cacioppo ◽  
Francesca Arcudi ◽  
Tobias Scharl ◽  
Philipp Haines ◽  
...  

<p>Combining carbon dots (CDs) with π-extended chromophores is an attractive way to study the electronic and energy processes of the former as a key step to many applications, including photosensing, photocatalysis, or photosensitization. CDs, in conjugation with chromophores, can have value in preparing donor-acceptor hybrids, and can also be used as scaffolds to support electronic communication between dyes. In this work, we conjugate two different rylene diimides, naphthalene and perylene diimides (NDI and PDI, respectively), with amorphous nitrogen-doped carbon dots. We take advantage of the imidization reaction between the amine rich surface of the carbon dots and the monimide monoanhydride precursors of NDIs and PDIs, under microwave assisted conditions. The resulting (nano)hybrids were characterized also by spectroscopic methods. In particular, time-resolved spectroscopy for the multichromophoric array, consisting of CDs and both rylene diimides, allowed us to elucidate the complex inter-chromophoric interactions taking place in the excited state.</p>

2020 ◽  
Author(s):  
Luka Dordevic ◽  
Michele Cacioppo ◽  
Francesca Arcudi ◽  
Tobias Scharl ◽  
Philipp Haines ◽  
...  

<p>Combining carbon dots (CDs) with π-extended chromophores is an attractive way to study the electronic and energy processes of the former as a key step to many applications, including photosensing, photocatalysis, or photosensitization. CDs, in conjugation with chromophores, can have value in preparing donor-acceptor hybrids, and can also be used as scaffolds to support electronic communication between dyes. In this work, we conjugate two different rylene diimides, naphthalene and perylene diimides (NDI and PDI, respectively), with amorphous nitrogen-doped carbon dots. We take advantage of the imidization reaction between the amine rich surface of the carbon dots and the monimide monoanhydride precursors of NDIs and PDIs, under microwave assisted conditions. The resulting (nano)hybrids were characterized also by spectroscopic methods. In particular, time-resolved spectroscopy for the multichromophoric array, consisting of CDs and both rylene diimides, allowed us to elucidate the complex inter-chromophoric interactions taking place in the excited state.</p>


2020 ◽  
Author(s):  
Luka Dordevic ◽  
Michele Cacioppo ◽  
Francesca Arcudi ◽  
Tobias Scharl ◽  
Philipp Haines ◽  
...  

<p>Combining carbon dots (CDs) with π-extended chromophores is an attractive way to study the electronic and energy processes of the former as a key step to many applications, including photosensing, photocatalysis, or photosensitization. CDs, in conjugation with chromophores, can have value in preparing donor-acceptor hybrids, and can also be used as scaffolds to support electronic communication between dyes. In this work, we conjugate two different rylene diimides, naphthalene and perylene diimides (NDI and PDI, respectively), with amorphous nitrogen-doped carbon dots. We take advantage of the imidization reaction between the amine rich surface of the carbon dots and the monimide monoanhydride precursors of NDIs and PDIs, under microwave assisted conditions. The resulting (nano)hybrids were characterized also by spectroscopic methods. In particular, time-resolved spectroscopy for the multichromophoric array, consisting of CDs and both rylene diimides, allowed us to elucidate the complex inter-chromophoric interactions taking place in the excited state.</p>


2021 ◽  
Author(s):  
Shreya Bhatt ◽  
Gaurav Vyas ◽  
Parimal Paul

Preparation of water dispersible carbon dots from inexpensive natural carbon precursors and its application for purposes such as sensing, bio-imaging, patterning agent etc. is showing growing interest in recent years....


2018 ◽  
Vol 20 (17) ◽  
pp. 11673-11681 ◽  
Author(s):  
Sunghu Kim ◽  
Byung-Kuk Yoo ◽  
Yuri Choi ◽  
Byeong-Su Kim ◽  
Oh-Hoon Kwon

The non-exponential decay of the photoluminescence of carbon dots are analyzed using stretched exponential fit functions to reflect the heterogeneity in their luminescent surface states.


2021 ◽  
Vol 5 (1) ◽  
pp. 84-92
Author(s):  
Shuting Chen ◽  
Chaoqun Chen ◽  
Jian Wang ◽  
Fang Luo ◽  
Longhua Guo ◽  
...  

2021 ◽  
Author(s):  
Alagan Muthurasu ◽  
V GANESH

Carbon dots (CDs) exhibiting fluorescence property are generally derived from carbonaceous materials and possessing ultra small size with various exciting physical, chemical and photo-properties that have been used in many...


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