scholarly journals Synthesis and Characterization of Crosslinked Polymers from Cottonseed Oil

2018 ◽  
Author(s):  
Rangana Wijayapala ◽  
Satish Mishra ◽  
Bill Elmore ◽  
Charles Freeman Jr ◽  
Santanu Kundu

In this study, crosslinked polymers were synthesized from cottonseed oil. Unsaturated fatty acids, the major components of cottonseed oils, were initially epoxidized. A network polymer was then formed by crosslinking the epoxidized oil with maleic anhydrate. Mechanical properties of these polymers were altered by varying the amount of maleic anhydrate. These polymers have a tensile modulus of the order 1 MPa and are stable in the acidic and alkaline environment.<br>

2018 ◽  
Author(s):  
Rangana Wijayapala ◽  
Satish Mishra ◽  
Bill Elmore ◽  
Charles Freeman Jr ◽  
Santanu Kundu

In this study, crosslinked polymers were synthesized from cottonseed oil. Unsaturated fatty acids, the major components of cottonseed oils, were initially epoxidized. A network polymer was then formed by crosslinking the epoxidized oil with maleic anhydrate. Mechanical properties of these polymers were altered by varying the amount of maleic anhydrate. These polymers have a tensile modulus of the order 1 MPa and are stable in the acidic and alkaline environment.<br>


1970 ◽  
Vol 1 (1) ◽  
pp. 29-41 ◽  
Author(s):  
Hiew Ming Yu ◽  
Arun Gupta ◽  
Ritu Gupta ◽  
Saad Bala Husain

Soybean oil is one of the major vegetable oils containing more than 99% of triglycerides of saturated and unsaturated fatty acids and has become an interesting source to produce bioplastic. This study investigates the synthesis and characterization of bioplastic developed by the acrylate epoxidized soybean oil through ring opening polymerization process. The mechanical properties of the samples were characterized using Fourier Transform Infrared Spectroscopy, Thermogravimetric analysis and the physio-chemical properties of the bioplastics were studied. In this study, the bioplastic made up from soybean oil with the lowest glycerol concentration showed the best mechanical properties.


2019 ◽  
Vol 136 (24) ◽  
pp. 47655 ◽  
Author(s):  
Rangana Wijayapala ◽  
Satish Mishra ◽  
Bill Elmore ◽  
Charles Freeman ◽  
Santanu Kundu

2021 ◽  
Author(s):  
Shu bin Li ◽  
Xiao Wang ◽  
Jiang Zhu ◽  
Zhenyu Wang ◽  
Lu Wang

In this work, using carboxyl-modified Fe3O4 nanoparticles as a photothermal agent, combining the chemical amide bond and intermolecular hydrogen bond crosslinking force, a photothermal hydrogel with enhanced mechanical properties was...


2016 ◽  
Vol 7 (14) ◽  
pp. 2553-2564 ◽  
Author(s):  
Yating Jia ◽  
Weizhong Wang ◽  
Xiaojun Zhou ◽  
Wei Nie ◽  
Liang Chen ◽  
...  

A poly(glycerol sebacate)-based elastomeric copolyesters with improved mechanical properties and higher water uptake capacity.


ChemInform ◽  
1987 ◽  
Vol 18 (11) ◽  
Author(s):  
S. AHMAD ◽  
M. KHAN ◽  
F. AHMAD ◽  
NASIRULLA NASIRULLA ◽  
S. M. OSMAN

1999 ◽  
Vol 46 (4) ◽  
pp. 1001-1009
Author(s):  
S F Izmailov ◽  
G Y Zhiznevskaya ◽  
L V Kosenko ◽  
G N Troitskaya ◽  
N N Kudryavtseva ◽  
...  

Chemical composition of lipopolysaccharide (LPS) isolated from an effective (97) and ineffective (87) strains of R. l. viciae has been determined. LPS preparations from the two strains contained: glucose, galactose, mannose, fucose, arabinose, heptose, glucosamine, galactosamine, quinovosamine, and 3-N-methyl-3,6-dideoxyhexose, as well as glucuronic, galacturonic and 3-deoxyoctulosonic acid. The following fatty acids were identified: 3-OH 14:0, 3-OH 15:0, 3-OH 16:0, 3-OH 18:0 and 27-OH 28:0. The ratio of 3-OH 14:0 to other major fatty acids in LPS 87 was higher that in LPS 97. SDS/PAGE profiles of LPS indicated that, in lipopolysaccharides, relative content of S form LPS I to that of lower molecular mass (LPS II) was much higher in the effective strain 97 than in 87. All types of polysaccharides exo-, capsular-, lipo, (EPS, CPS, LPS, respectively) examined possessed the ability to bind faba bean lectin. The degree of affinity of the host lectin to LPS 87 was half that to LPS 97. Fatty acids (FA) composition from bacteroids and peribacteroid membrane (PBM) was determined. Palmitic, stearic and hexadecenoic acids were common components found in both strains. There was a high content of unsaturated fatty acids in bacteroids as well as in PBM lipids. The unsaturation index in the PBM formed by strain 87 was lower than in the case of strain 97. Higher ratio of 16:0 to 18:1 fatty acids was characteristic for PMB of the ineffective strain.


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