scholarly journals PREPARATION OF HIGHLY POROUS AROMATIC POLYMERS BY THE FRIEDEL-CRAFTS REACTION

2020 ◽  
pp. 114-119
Author(s):  
Наталья Эдуардовна Еремченкова ◽  
Алексей Владимирович Быков ◽  
Линда Жановна Никошвили ◽  
Любовь Львовна Киви-Минскер
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Polymer Synthesis ◽  
High Specific Surface Area ◽  
Hydrogenation Catalysts ◽  
Aromatic Polymer ◽  
Aromatic Polymers ◽  
First Time ◽  
Highly Porous

Работа посвящена получению полимера путем сшивки ароматических фрагментов молекул-мономеров с помощью реакции Фриделя-Крафтса. В ходе работы впервые был синтезирован полимер с высокой удельной площадью поверхности (705 м/г) с применением в качестве мономеров бензола и нафталина. Полученный ароматический полимер в дальнейшем может использоваться в качестве носителя для создания катализаторов гидрирования. This work is devoted to the polymer synthesis by crosslinking of aromatic fragments of monomer molecules using Friedel-Crafts reaction. In the framework of this work, a polymer with a high specific surface area (705 m/g) was synthesized for the first time using benzene and naphthalene as monomers. The resulting aromatic polymer can be used as a support for the development of hydrogenation catalysts.

BCN nanosheets templated by g-C3N4 for high performance capacitive deionization

2018 ◽  
Vol 6 (30) ◽  
pp. 14644-14650 ◽  
Author(s):  
Shiyong Wang ◽  
Gang Wang ◽  
Tingting Wu ◽  
Yunqi Zhang ◽  
Fei Zhan ◽  
...  
Keyword(s):  
Specific Surface ◽  
Pore Structure ◽  
Surface Area ◽  
Specific Surface Area ◽  
High Performance ◽  
Electrode Materials ◽  
High Specific Surface Area ◽  
Capacitive Deionization ◽  
First Time

BCN nanosheets show a pore structure with a high specific surface area and are investigated as CDI electrode materials for the first time.

scholarly journals A large-surface-area TS-1 nanocatalyst: a combination of nanoscale particle sizes and hierarchical micro/mesoporous structures

RSC Advances ◽  
2019 ◽  
Vol 9 (17) ◽  
pp. 9694-9699 ◽  
Author(s):  
Changlin Du ◽  
Nan Cui ◽  
Linghao Li ◽  
Zile Hua ◽  
Jianlin Shi
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Pore Volume ◽  
Total Pore Volume ◽  
High Specific Surface Area ◽  
Particle Sizes ◽  
Top Down ◽  
First Time ◽  
Mesoporous Structures

By dry-gel steam-assisted crystallization and top-down alkali-etching treatment, hierarchically structured TS-1 nanozeolites with abundant micro/mesopores were synthesized for the first time, with high specific surface area of 606 m2 g−1 and total pore volume of 0.86 cm3 g−1.

scholarly journals Nanoporous Quasi-High-Entropy Alloy Microspheres

Metals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 345 ◽  
Author(s):  
Lianzan Yang ◽  
Yongyan Li ◽  
Zhifeng Wang ◽  
Weimin Zhao ◽  
Chunling Qin
Keyword(s):  
Mechanical Properties ◽  
Solid Solution ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
High Specific Surface Area ◽  
High Entropy Alloy ◽  
Face Centered Cubic ◽  
High Entropy ◽  
Hierarchical Porous

High-entropy alloys (HEAs) present excellent mechanical properties. However, the exploitation of chemical properties of HEAs is far less than that of mechanical properties, which is mainly limited by the low specific surface area of HEAs synthesized by traditional methods. Thus, it is vital to develop new routes to fabricate HEAs with novel three-dimensional structures and a high specific surface area. Herein, we develop a facile approach to fabricate nanoporous noble metal quasi-HEA microspheres by melt-spinning and dealloying. The as-obtained nanoporous Cu30Au23Pt22Pd25 quasi-HEA microspheres present a hierarchical porous structure with a high specific surface area of 69.5 m2/g and a multiphase approximatively componential solid solution characteristic with a broad single-group face-centered cubic XRD pattern, which is different from the traditional single-phase or two-phase solid solution HEAs. To differentiate, these are named quasi-HEAs. The synthetic strategy proposed in this paper opens the door for the synthesis of porous quasi-HEAs related materials, and is expected to promote further applications of quasi-HEAs in various chemical fields.

KCl-assisted activation: Moringa oleifera branch-derived porous carbon for high performance supercapacitor

2021 ◽  
Vol 45 (12) ◽  
pp. 5712-5719
Author(s):  
Yongxiang Zhang ◽  
Peifeng Yu ◽  
Mingtao Zheng ◽  
Yong Xiao ◽  
Hang Hu ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Porous Carbon ◽  
High Performance ◽  
Moringa Oleifera ◽  
High Specific Surface Area ◽  
Porous Carbons

Porous carbons with a high specific surface area (2314–3470 m2 g−1) are prepared via a novel KCl-assisted activation strategy for high-performance supercapacitor.

Carbon material with high specific surface area and high pseudocapacitance: Possible application in supercapacitors

2021 ◽  
Vol 319 ◽  
pp. 111063
Author(s):  
Yury M. Volfkovich ◽  
Valentin E. Sosenkin ◽  
Alexei Y. Rychagov ◽  
Alexandr V. Melezhik ◽  
Alexei G. Tkachev ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Carbon Material ◽  
High Specific Surface Area

Efficient conversion of CO2 to methane using thin-layer SiOx matrix anchored nickel catalysts

2019 ◽  
Vol 43 (33) ◽  
pp. 13217-13224 ◽  
Author(s):  
Xieyi Huang ◽  
Peng Wang ◽  
Zhichao Zhang ◽  
Shaoning Zhang ◽  
Xianlong Du ◽  
...  
Keyword(s):  
Thin Layer ◽  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Geometric Structure ◽  
Nickel Catalysts ◽  
High Specific Surface Area ◽  
Efficient Conversion

Thin-layer SiOx matrix anchored nickel catalysts with high specific surface area and a unique electronic/geometric structure were fabricated for efficient CO2 methanation.

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