Central Composite Design for Optimization of Chromium (VI) Removal from Aqueous Solution Using Low Cost Adsorbent

2015 ◽  
Vol 11 (1) ◽  
pp. 1-6
Author(s):  
D. Krishna ◽  
◽  
D.V. Padma ◽  
Molecules ◽  
2021 ◽  
Vol 26 (21) ◽  
pp. 6477
Author(s):  
Yohanis Birhanu ◽  
Seyoum Leta

Lead pollution is a severe health concern for humankind. Utilizing water contaminated with lead can cause musculoskeletal, renal, neurological, and fertility impairments. Therefore, to remove lead ions, proficient, and cost-effective methods are imperative. In this study, the Odaracha soil which is traditionally used by the local community of the Saketa District was used as a novel low-cost technology to adsorb lead ions. Odaracha adsorbent was characterized by scanning electron microscopy and Fourier transform infrared spectroscopy. The adsorption process followed the batch adsorption experiment. The response surface method was implemented to derive the operating variables’ binary interaction effect and optimize the process. According to the study’s experimental result, at optimum experimental conditions Odaracha adsorbent removes 98.17% of lead ions. Based on the result of the central composite design model, the Pb2+ ion removal efficiency of Odaracha was 97.193%, indicating an insignificant dissimilarity of the actual and predicted results. The coefficient of determination (R2) for Pb2+ was 0.9454. According to the factors’ influence indicated in the results of the central composite design model, all individual factors and the interaction effect between contact time and pH has a significant positive effect on lead adsorption. However, other interaction effects (contact time with dose and pH with dose) did not significantly influence the removal efficiency of lead ions. The adsorption kinetics were perfectly fitted with a pseudo-second-order model, and the adsorption isotherm was well fitted with the Freundlich isotherm model. In general, this study suggested that Odaracha adsorbent can be considered a potential adsorbent to remove Pb2+ ions and it is conceivable to raise its effectiveness by extracting its constituents at the industrial level.


2018 ◽  
Vol 17 (2) ◽  
pp. 245-255 ◽  
Author(s):  
S. A. R. Shahamirifard ◽  
M. Ghaedi ◽  
M. Montazerozohori ◽  
A. Masoudiasl

In this work, the use of carbon dots (CDs) as a complexing agent and sensitizer in a polymeric matrix for determination of copper(ii) by UV-vis spectroscopy is reported for the first time.


RSC Advances ◽  
2016 ◽  
Vol 6 (33) ◽  
pp. 27416-27425 ◽  
Author(s):  
Mahnaz Saghanejhad Tehrani ◽  
Rouholah Zare-Dorabei

In this work, metal organic framework (MIL-68(Al)), was synthesized by a simple, fast and low-cost process for simultaneous removal of methylene blue and Rhodamine B, regarded to be toxic and even carcinogenic, from aqueous solution.


Author(s):  
Muhammad Tahir Butt ◽  
Zara Amjad ◽  
Rauf Ahmad Khan

In the present study yeast biomass has been successfully used as biosorbent for removal of Crfrom aqueous solution. Yeasts of Saccharomyces cerevisiae are effective biosorbents for heavy metal ionsand it can be bought in large quantity at low cost. S. cerevisiae can remove toxic metals from aqueoussolutions to various levels. This low-cost biosorbent will make the process cost-effective and competitiveparticularly for environmental applications in detoxifying effluents. Langmuir’s and Freundlichs isothermswere also plotted to observe the maximum biosorption of heavy metal chromium (VI).


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