Low-cost preparation of silica aerogel for optimized adsorptive removal of naphthalene from aqueous solution with central composite design (CCD)

2016 ◽  
Vol 447 ◽  
pp. 307-314 ◽  
Author(s):  
A.R. Yaqubzadeh ◽  
A. Ahmadpour ◽  
T. Rohani Bastami ◽  
M.R. Hataminia
Molecules ◽  
2021 ◽  
Vol 26 (21) ◽  
pp. 6477
Author(s):  
Yohanis Birhanu ◽  
Seyoum Leta

Lead pollution is a severe health concern for humankind. Utilizing water contaminated with lead can cause musculoskeletal, renal, neurological, and fertility impairments. Therefore, to remove lead ions, proficient, and cost-effective methods are imperative. In this study, the Odaracha soil which is traditionally used by the local community of the Saketa District was used as a novel low-cost technology to adsorb lead ions. Odaracha adsorbent was characterized by scanning electron microscopy and Fourier transform infrared spectroscopy. The adsorption process followed the batch adsorption experiment. The response surface method was implemented to derive the operating variables’ binary interaction effect and optimize the process. According to the study’s experimental result, at optimum experimental conditions Odaracha adsorbent removes 98.17% of lead ions. Based on the result of the central composite design model, the Pb2+ ion removal efficiency of Odaracha was 97.193%, indicating an insignificant dissimilarity of the actual and predicted results. The coefficient of determination (R2) for Pb2+ was 0.9454. According to the factors’ influence indicated in the results of the central composite design model, all individual factors and the interaction effect between contact time and pH has a significant positive effect on lead adsorption. However, other interaction effects (contact time with dose and pH with dose) did not significantly influence the removal efficiency of lead ions. The adsorption kinetics were perfectly fitted with a pseudo-second-order model, and the adsorption isotherm was well fitted with the Freundlich isotherm model. In general, this study suggested that Odaracha adsorbent can be considered a potential adsorbent to remove Pb2+ ions and it is conceivable to raise its effectiveness by extracting its constituents at the industrial level.


2018 ◽  
Vol 17 (2) ◽  
pp. 245-255 ◽  
Author(s):  
S. A. R. Shahamirifard ◽  
M. Ghaedi ◽  
M. Montazerozohori ◽  
A. Masoudiasl

In this work, the use of carbon dots (CDs) as a complexing agent and sensitizer in a polymeric matrix for determination of copper(ii) by UV-vis spectroscopy is reported for the first time.


RSC Advances ◽  
2016 ◽  
Vol 6 (33) ◽  
pp. 27416-27425 ◽  
Author(s):  
Mahnaz Saghanejhad Tehrani ◽  
Rouholah Zare-Dorabei

In this work, metal organic framework (MIL-68(Al)), was synthesized by a simple, fast and low-cost process for simultaneous removal of methylene blue and Rhodamine B, regarded to be toxic and even carcinogenic, from aqueous solution.


2020 ◽  
Vol 1 (1) ◽  
pp. 37-44
Author(s):  
Krishna Bahadur Dawadi ◽  
Mahesh Bhattarai ◽  
Puspa Lal Homagai

Adsorptive removal of methyl red (MR) from aqueous solution onto chemically modified Charred Sal (Shorea robusta) Saw-Dust (CSSD) and Xanthated Sal Saw-Dust (XSSD) has been investigated. The surface modification is characterized by Fourier transformed infra-red (FTIR) spectroscopy, scanning electron microscopy (SEM) and elemental Analysis. Different parameters are studied such as contact time, optimum pH, and initial ion concentration. Maximum dye removal is observed at pH 4 for charred and xanthated Sal saw dust. The dye can be quantitatively removed onto the surface of these adsorbent. At a contact time of 3-4 hours maximum adsorption capacity (qmax) for CSSD and XSSD are found to be 70 mg/g and 130 mg/g respectively. Adsorption kinetic data are best fitted onto pseudo second order. The obtained result indicated an excellent alternative for the treatment of dye contaminated waste water using such chemically modified Sal saw dust at low cost with better efficiency.


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