scholarly journals MAGNETIC CHARACTERISTICS OF METAMORPHIZED ULTRABASITES OF THE OCEANIC LITHOSPHERE

2019 ◽  
Vol 47 (4) ◽  
pp. 106-127
Author(s):  
K. V. Popov ◽  
A. M. Gorodnitskiy ◽  
N. A. Shishkina
Keyword(s):  
World Ocean ◽  
Oceanic Lithosphere ◽  
Structural Features ◽  
Residual Magnetization ◽  
Magnetic Characteristics ◽  
Transform Faults ◽  
Ocean Ridges ◽  
Submarine Ridge ◽  
Deep Layers ◽  
The Stability

As part of the study of the nature of magnetic anomalies associated with the deep layers of the oceanic crust, a comparative analysis was made of the petromagnetic characteristics of serpentinized mantle ultrabasic samples taken from oceanographic expeditions of the Institute of Oceanology and the Institute of Geochemistry and Analytical Chemistry of the Russian Academy of Sciences in various morphotectonic regions of the World Ocean. The purpose of the work is to obtain information on the composition, concentration, crystallization temperature and structural features of ferromagnetic minerals, which are formed in different conditions of the post-magmatic metamorphism of ultrabasites. Sample collections are divided into three groups. 1. Oceanic peridotites from the rift zones of the mid-ocean ridges and transform faults. 2. Peridotites of the submarine ridge Gorringe, located within the Azoro-Gibraltar zone of faults. 3. Dunites of the Pekulney complex (Chukotka) formed in the island arc system. It has been established that in all selected regions, samples of serpentinized hyperbasites have high values of natural residual magnetization, magnetic susceptibility and saturation magnetization. The highest values of magnetic parameters are the dunites of the Pekulney complex. Estimation of the dependence of the concentration of ferrimagnetic materials C% of the degree of serpentinization of the SS%. showed that it is practically of little significance. The main factors contributing to the increase in the concentration of magnetite are the increased iron content of olivine in ultrabasites and the temperature of metamorphism. The question of the period of formation of magnetites and the stability of their primary residual magnetization requires further study.

FABRICATION OF NANOPOROUS CHITOSAN MEMBRANES

NANO ◽  
2010 ◽  
Vol 05 (01) ◽  
pp. 53-60 ◽  
Author(s):  
XIAOLIANG WANG ◽  
XIANG LI ◽  
ELEANOR STRIDE ◽  
MOHAN EDIRISINGHE
Keyword(s):  
Low Frequency ◽  
Drug Carriers ◽  
Structural Features ◽  
Wound Dressings ◽  
Ftir Analysis ◽  
Tissue Engineering Scaffolds ◽  
Nanoscale Structures ◽  
Low Frequency Ultrasound ◽  
Chitosan Membranes ◽  
The Stability

Naturally derived biopolymers have been widely used for biomedical applications such as drug carriers, wound dressings, and tissue engineering scaffolds. Chitosan is a typical polysaccharide of great interest due to its biocompatibility and film-formability. Chitosan membranes with controllable porous structures also have significant potential in membrane chromatography. Thus, the processing of membranes with porous nanoscale structures is of great importance, but it is also challenging and this has limited the application of these membranes to date. In this study, with the aid of a carefully selected surfactant, polyethyleneglycol stearate-40, chitosan membranes with a well controlled nanoscale structure were successfully prepared. Additional control over the membrane structure was obtained by exposing the suspension to high intensity, low frequency ultrasound. It was found that the concentration of chitosan/surfactant ratio and the ultrasound exposure conditions affect the structural features of the membranes. The stability of nanopores in the membrane was improved by intensive ultrasonication. Furthermore, the stability of the blended suspensions and the intermolecular interactions between chitosan and the surfactant were investigated using scanning electron microscope and Fourier transform infrared spectroscopy (FTIR) analysis, respectively. Hydrogen bonds and possible reaction sites for molecular interactions in the two polymers were also confirmed by FTIR analysis.

Radial Anisotropy and it's Relation to Fast and Slow Moving Tectonic Plates

2021 ◽  
Author(s):  
Tak Ho ◽  
Keith Priestley ◽  
Eric Debayle
Keyword(s):  
Upper Mantle ◽  
Large Scale ◽  
Oceanic Lithosphere ◽  
Azimuthal Anisotropy ◽  
Plate Motion ◽  
Moho Depth ◽  
Dispersion Characteristics ◽  
Anisotropic Models ◽  
Ocean Ridges ◽  
Average Dispersion

<p>We present a new radially anisotropic (<strong>ξ)</strong> tomographic model for the upper mantle to transition zone depths derived from a large Rayleigh (~4.5 x 10<sup>6 </sup>paths) and Love (~0.7 x 10<sup>6</sup> paths) wave path average dispersion curves with periods of 50-250 s and up to the fifth overtone. We first extract the path average dispersion characteristics from the waveforms. Dispersion characteristics for common paths (~0.3 x 10<sup>6</sup> paths) are taken from the Love and Rayleigh datasets and jointly inverted for isotropic V<sub>s </sub>and <strong>ξ</strong>. CRUST1.0 is used for crustal corrections and a model similar to PREM is used as a starting model. V<sub>s</sub> and <strong>ξ</strong> are regionalised for a 3D model. The effects of azimuthal anisotropy are accounted for during the regionalisation. Our model confirms large-scale upper mantle features seen in previously published models, but a number of these features are better resolved because of the increased data density of the fundamental and higher modes coverage from which our <strong>ξ</strong>(z) was derived. Synthetic tests show structures with radii of 400 km can be distinguished easily. Crustal perturbations of +/-10% to V<sub>p</sub>, V<sub>s</sub> and density, or perturbations to Moho depth of +/-10 km over regions of 400 km do not significantly change the model. The global average decreases from <strong>ξ~</strong>1.06 below the Moho to <strong>ξ</strong>~1 at ~275 km depth. At shallow depths beneath the oceans <strong>ξ</strong>>1 as is seen in previously published global mantle radially anisotropic models. The thickness of this layer increases slightly with the increasing age of the oceanic lithosphere. At ~200 km and deeper depths below the fast-spreading East Pacific Rise and starting at somewhat greater depths beneath the slower spreading ridges, <strong>ξ</strong><1. At depths ≥200 km and deeper depths below most of the backarc basins of the western Pacific <strong>ξ</strong><1. The signature of mid-ocean ridges vanishes at about 150 km depth in V<sub>s</sub> while it extends much deeper in the <strong>ξ</strong> model suggesting that upwelling beneath mid-ocean ridges could be more deeply rooted than previously believed. The pattern of radially anisotropy we observe, when compared with the pattern of azimuthal anisotropy determined from Rayleigh waves, suggests that the shearing at the bottom of the plates is only sufficiently strong to cause large-scale preferential alignment of the crystals when the plate motion exceeds some critical value which Debayle and Ricard (2013) suggest is about 4 cm/yr.</p>

3. Fracture zones and transform faults

2015 ◽  
pp. 36-52
Author(s):  
Peter Molnar
Keyword(s):  
Fracture Zones ◽  
Transform Faults ◽  
Ocean Ridges ◽  
The 1950S

‘Fracture zones and transform faults’ introduces fracture zones, huge, long linear scars in the seafloor first mapped in the 1950s, and their interpretation in terms of a new concept, transform faulting. Fracture zones are made at mid-ocean ridges, where the seafloor spreads apart. Segments of zones of spreading intersect fracture zones at right angles, along which transform faulting transfers the spreading on one spreading zone to another. As the seafloor spreads, and plates move apart at mid-ocean ridges, fracture zones grow longer. Testing this idea relied on the study of earthquakes that occurred on the transform faults, using seismographs on distant continents. This chapter introduces readers to the pertinent seismological methods by which this was achieved.

scholarly journals Plasma-Assisted Chemical Vapor Deposition of F-Doped MnO2 Nanostructures on Single Crystal Substrates

Nanomaterials ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 1335
Author(s):  
Lorenzo Bigiani ◽  
Chiara Maccato ◽  
Alberto Gasparotto ◽  
Cinzia Sada ◽  
Elza Bontempi ◽  
...  
Keyword(s):  
Chemical Vapor Deposition ◽  
Data Storage ◽  
Vapor Deposition ◽  
Oxygen Deficiency ◽  
Chemical Vapor ◽  
Magnetic Ordering ◽  
Analytical Techniques ◽  
Structural Features ◽  
Optical Absorption Spectroscopy ◽  
Magnetic Characteristics

MnO2 nanostructures were fabricated by plasma assisted-chemical vapor deposition (PA-CVD) using a fluorinated diketonate diamine manganese complex, acting as single-source precursor for both Mn and F. The syntheses were performed from Ar/O2 plasmas on MgAl2O4(100), YAlO3(010), and Y3Al5O12(100) single crystals at a growth temperature of 300 °C, in order to investigate the substrate influence on material chemico-physical properties. A detailed characterization through complementary analytical techniques highlighted the formation of highly pure and oriented F-doped systems, comprising the sole β-MnO2 polymorph and exhibiting an inherent oxygen deficiency. Optical absorption spectroscopy revealed the presence of an appreciable Vis-light harvesting, of interest in view of possible photocatalytic applications in pollutant degradation and hydrogen production. The used substrates directly affected the system structural features, as well as the resulting magnetic characteristics. In particular, magnetic force microscopy (MFM) measurements, sensitive to the out-of-plane magnetization component, highlighted the formation of spin domains and long-range magnetic ordering in the developed materials, with features dependent on the system morphology. These results open the door to future engineering of the present nanostructures as possible magnetic media for integration in data storage devices.

scholarly journals Surface-Tension-Confined Channel with Biomimetic Microstructures for Unidirectional Liquid Spreading

Micromachines ◽  
2020 ◽  
Vol 11 (11) ◽  
pp. 978
Author(s):  
Yi Zhang ◽  
Yang Gan ◽  
Liwen Zhang ◽  
Deyuan Zhang ◽  
Huawei Chen
Keyword(s):  
Surface Tension ◽  
Underlying Mechanism ◽  
Structural Features ◽  
Liquid Motion ◽  
Water Separation ◽  
Lab On Chip ◽  
Liquid Spreading ◽  
Oil Water Separation ◽  
On Chip ◽  
The Stability

Unidirectional liquid spreading without energy input is of significant interest for the broad applications in diverse fields such as water harvesting, drop transfer, oil–water separation and microfluidic devices. However, the controllability of liquid motion and the simplification of manufacturing process remain challenges. Inspired by the peristome of Nepenthes alata, a surface-tension-confined (STC) channel with biomimetic microcavities was fabricated facilely through UV exposure photolithography and partial plasma treatment. Perfect asymmetric liquid spreading was achieved by combination of microcavities and hydrophobic boundary, and the stability of pinning effect was demonstrated. The influences of structural features of microcavities on both liquid spreading and liquid pinning were investigated and the underlying mechanism was revealed. We also demonstrated the spontaneous unidirectional transport of liquid in 3D space and on tilting slope. In addition, through changing pits arrangement and wettability pattern, complex liquid motion paths and microreactors were realized. This work will open a new way for liquid manipulation and lab-on-chip applications.

Crystallographic analysis and biochemical applications of a novel penicillin-binding protein/β-lactamase homologue from a metagenomic library

2014 ◽  
Vol 70 (9) ◽  
pp. 2455-2466 ◽  
Author(s):  
Tri Duc Ngo ◽  
Bum Han Ryu ◽  
Hansol Ju ◽  
Eun Jin Jang ◽  
Kyeong Kyu Kim ◽  
...  
Keyword(s):  
Metagenomic Library ◽  
Structural Features ◽  
Crystallographic Analysis ◽  
Penicillin Binding Protein ◽  
Hydrophobic Residues ◽  
Penicillin Binding Proteins ◽  
Hydrophobic Compounds ◽  
Nitrophenyl Phosphate ◽  
Biophysical Studies ◽  
The Stability

Interest in penicillin-binding proteins and β-lactamases (the PBP-βL family) is increasing owing to their biological and clinical significance. In this study, the crystal structure of Est-Y29, a metagenomic homologue of the PBP-βL family, was determined at 1.7 Å resolution. In addition, complex structures of Est-Y29 with 4-nitrophenyl phosphate (4NP) and with diethyl phosphonate (DEP) at 2.0 Å resolution were also elucidated. Structural analyses showed that Est-Y29 is composed of two domains: a β-lactamase fold and an insertion domain. A deep hydrophobic patch between these domains defines a wide active site, and a nucleophilic serine (Ser58) residue is located in a groove defined primarily by hydrophobic residues between the two domains. In addition, three hydrophobic motifs, which make up the substrate-binding site, allow this enzyme to hydrolyze a wide variety of hydrophobic compounds, including fish and olive oils. Furthermore, cross-linked Est-Y29 aggregates (CLEA-Est-Y29) significantly increase the stability of the enzyme as well as its potential for extensive reuse in various deactivating conditions. The structural features of Est-Y29, together with biochemical and biophysical studies, could provide a molecular basis for understanding the properties and regulatory mechanisms of the PBP-βL family and their potential for use in industrial biocatalysts.

scholarly journals Joint crystallization of KCuAl[PO4]2 and K(Al,Zn)2[(P,Si)O4]2: crystal chemistry and mechanism of formation of phosphate-silicate epitaxial heterostructure

2020 ◽  
Vol 76 (3) ◽  
pp. 483-491
Author(s):  
Olga Yakubovich ◽  
Galina Kiriukhina ◽  
Larisa Shvanskaya ◽  
Anatoliy Volkov ◽  
Olga Dimitrova
Keyword(s):  
Crystal Structures ◽  
Active Material ◽  
Structure Type ◽  
Structural Features ◽  
X Ray Diffraction ◽  
X Ray ◽  
Electrochemically Active ◽  
Phosphate Silicate ◽  
The Stability ◽  
Small Channels

Two novel phases, potassium copper aluminium bis(phosphate), KCuAl[PO4]2 (I), and potassium zinc aluminium bis(phosphate-silicate), K(Al,Zn)2[(P,Si)O4]2 (II), were obtained in one hydrothermal synthesis experiment at 553 K. Their crystal structures have been studied using single-crystal X-ray diffraction. (I) is a new member of the A + M 2+ M 3+[PO4]2 family. Its open 3D framework built by AlO5 and PO4 polyhedra includes small channels populated by columns of CuO6 octahedra sharing edges, and large channels where K+ ions are deposited. It is assumed that the stability of this structure type is due to the pair substitution of Cu/Al with Ni/Fe, Co/Fe or Mg/Fe in different representatives of the series. From the KCuAl[PO4]2 structural features, one may suppose it is a potentially electrochemically active material and/or possible low-temperature antiferromagnet. In accordance with results obtained from X-ray diffraction data, using scanning electron microscopy, microprobe analysis and detailed crystal chemical observation, (II) is considered as a product of epitaxial intergrowth of phosphate KAlZn[PO4]2 and silicate KAlSi[SiO4]2 components having closely similar crystal structures. The assembly of `coherent intergrowth' is described in the framework of a single diffraction pattern.

Supramolecular complexes formed by dimethoxypillar[5]arenes and imidazolium salts: a joint experimental and computational investigation

2017 ◽  
Vol 41 (21) ◽  
pp. 12490-12505
Author(s):  
Francesca D'Anna ◽  
Carla Rizzo ◽  
Paola Vitale ◽  
Salvatore Marullo ◽  
Francesco Ferrante
Keyword(s):  
Structural Features ◽  
Supramolecular Complexes ◽  
Combined Approach ◽  
Imidazolium Salts ◽  
Computational Investigation ◽  
The Stability

The stability of host–guest complexes formed by dimethoxypillar[5]arenes and imidazolium salts has been analyzed as a function of different structural features of the guest, using a combined approach of different techniques.

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