OIL POLLUTION OF THE BLACK SEA COAST IN THE AREAS OF THE TSEMES BAY AND THE KERCH STRAIT: LONG-TERM DYNAMICS AND ASSESSMENT OF SELF-CLEANING CAPACITY
The paper examines the results of twelve-year (2007 to 2019) observations of spatial distribution and temporal changes in the concentrations of petroleum components in the coastal waters and sediment cores, as well as in the quantity and composition of oil slicks and tar balls on the beaches, cliffs and solid constructions of the Black Sea coast in the area of the city of Novorossiysk, which is the most important oil seaport of Russia, and in the Kerch Strait. 165 samples of seawater, 24 sediment cores up to 50 cm long split layer-bylayer into 108 samples, and 102 samples of oil slicks and tar balls were taken and analyzed with the use of thin layer and column chromatography, optical and gravimetric methods. The evidences of high level and chronic character of oil pollution of the studied coastal sectors are presented. Much attention is given to the dynamics of the natural transformation of oil slicks and tar balls found on the shore. It is shown that over time, under the influence of natural factors of attenuation, the oil slicks stranded ashore undergo an exponential decrease of the ratio between relatively labile hydrocarbons and conservative asphaltic components in their composition. The rate of the process may vary considerably depending on the size of oil pollution traces, their location on the coastal zone profile, as well as on the climatic, hydrological, and geomorphological conditions. An empirical statistical model is developed on the base of this data. This model makes it possible to classify and to map seacoasts according to their ability to degrade oil pollution using the information on the principal environmental parameters of attenuation.