scholarly journals EMISSIONS MONITORING OF HEAVY METALS AND THEIR COMPOUNDS RESULTED FROM COMBUSTION PROCESSES IN CLINKER KILNS IN ROMANIA

2017 ◽  
Vol 23 (1) ◽  
pp. 20-26
Author(s):  
CRISTIAN CIOBANU ◽  
GHEORGHE VOICU ◽  
MAGDALENA – LAURA TOMA ◽  
PAULA TUDOR
Keyword(s):  
Heavy Metals ◽  
Wastewater Treatment ◽  
Contaminated Soil ◽  
Wastewater Treatment Plants ◽  
Raw Materials ◽  
Cement Plant ◽  
Combustion Gases ◽  
Waste Oils ◽  
Industrial Sources ◽  
Combustion Processes

With the dust arising from the clinker kilns and grill coolers (the major pollution sources in a cement plant), also heavy metals and their compounds (in the form of powders and vaporous), originating from fuels and raw materials, are pumped into the air. The paper presents some aspects regarding the monitoring of heavy metals contained in the combustion gases from a Romanian cement factory. The fuels used in the incinerator varied from coal/petroleum coke, refuse oils (from waste oils and their emulsions, up to sludge, paraffin, tars, contaminated soil), rubber (including whole used tires), plastic, paper, leather, textiles, wood (including sawdust), as such or impregnated/contaminated with various substances from industrial sources or sorted household wastes, sludge (previously dried) from wastewater treatment plants. In addition, the list of over 100 types of waste that can be co-processed can be found in integrated authorizations of cement plants. However, the level of heavy metals in the combustion gases was in allowed limits.

scholarly journals EMISSIONS MONITORING OF HEAVY METALS AND THEIR COMPOUNDS RESULTED FROM COMBUSTION PROCESSES IN CLINKER KILNS IN ROMANIA

2018 ◽  
Vol 24 (1) ◽  
Author(s):  
CRISTIAN CIOBANU ◽  
GHEORGHE VOICU ◽  
MAGDALENA – LAURA TOMA ◽  
PAULA TUDOR
Keyword(s):  
Heavy Metals ◽  
Wastewater Treatment ◽  
Contaminated Soil ◽  
Wastewater Treatment Plants ◽  
Raw Materials ◽  
Cement Plant ◽  
Combustion Gases ◽  
Waste Oils ◽  
Industrial Sources ◽  
Combustion Processes

<p>With the dust arising from the clinker kilns and grill coolers (the major pollution sources in a cement plant), also heavy metals and their compounds (in the form of powders and vaporous), originating from fuels and raw materials, are pumped into the air. The paper presents some aspects regarding the monitoring of heavy metals contained in the combustion gases from a Romanian cement factory. The fuels used in the incinerator varied from coal/petroleum coke, refuse oils (from waste oils and their emulsions, up to sludge, paraffin, tars, contaminated soil), rubber (including whole used tires), plastic, paper, leather, textiles, wood (including sawdust), as such or impregnated/contaminated with various substances from industrial sources or sorted household wastes, sludge (previously dried) from wastewater treatment plants. In addition, the list of over 100 types of waste that can be co-processed can be found in integrated authorizations of cement plants. However, the level of heavy metals in the combustion gases was in allowed limits.</p>

scholarly journals EMISSIONS MONITORING OF HEAVY METALS AND THEIR COMPOUNDS RESULTED FROM COMBUSTION PROCESSES IN CLINKER KILNS IN ROMANIA

2018 ◽  
Vol 24 (1) ◽  
pp. 17-23
Author(s):  
CRISTIAN CIOBANU ◽  
GHEORGHE VOICU ◽  
MAGDALENA – LAURA TOMA ◽  
PAULA TUDOR
Keyword(s):  
Heavy Metals ◽  
Wastewater Treatment ◽  
Contaminated Soil ◽  
Wastewater Treatment Plants ◽  
Raw Materials ◽  
Cement Plant ◽  
Combustion Gases ◽  
Waste Oils ◽  
Industrial Sources ◽  
Combustion Processes

With the dust arising from the clinker kilns and grill coolers (the major pollution sources in a cement plant), also heavy metals and their compounds (in the form of powders and vaporous), originating from fuels and raw materials, are pumped into the air. The paper presents some aspects regarding the monitoring of heavy metals contained in the combustion gases from a Romanian cement factory. The fuels used in the incinerator varied from coal/petroleum coke, refuse oils (from waste oils and their emulsions, up to sludge, paraffin, tars, contaminated soil), rubber (including whole used tires), plastic, paper, leather, textiles, wood (including sawdust), as such or impregnated/contaminated with various substances from industrial sources or sorted household wastes, sludge (previously dried) from wastewater treatment plants. In addition, the list of over 100 types of waste that can be co-processed can be found in integrated authorizations of cement plants. However, the level of heavy metals in the combustion gases was in allowed limits.

Heavy Metals in Wastewater Treatment Plant Sludges in the Czech Republic

1992 ◽  
Vol 25 (4-5) ◽  
pp. 429-431 ◽  
Author(s):  
M. Sedláček ◽  
T. Just
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wastewater Treatment ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Raw Materials ◽  
Treatment Plant ◽  
Heavy Metal Concentration ◽  
Contamination Level ◽  
Municipal Wastewater Treatment

Since 1987 operators of municipal wastewater treatment plants, having the population equivalent over 5 000, monitor systematically heavy metals in sludges, based on one or two samplings on the average annually. Generally, Cd, Cr, Cu, Ni, Pb and Zn are monitored: since 1989 Hg is becoming the centre of systematic attention. Occasional data are available on concentrated Ag, Co, As and Mo. These data were collected and ordered by the authors of the paper. On their basis lines of exceedance were plotted and sets were prepared, characterizing both localities with the common level of the sludge contamination, and with the extremely low contamination level reflecting the condition that could be achieved if measures limiting the heavy metal input into public sewerage systems were adopted. The results achieved were compared with heavy metal concentration limits, as determined in the Industrial composts standard, both for raw materials used for the compost production, and for composts of Ist and IInd grades. With a view to the general environmental contamination, and considering the present economic and agricultural use, the input raw materials should meet the demands that are required under the standard for the prepared composts.

PCDD/F, PAH and heavy metals in the sewage sludge from six wastewater treatment plants in Beijing, China

Chemosphere ◽  
2007 ◽  
Vol 66 (2) ◽  
pp. 353-361 ◽  
Author(s):  
Jiayin Dai ◽  
Muqi Xu ◽  
Jiping Chen ◽  
Xiangping Yang ◽  
Zhenshan Ke
Keyword(s):  
Heavy Metals ◽  
Wastewater Treatment ◽  
Sewage Sludge ◽  
Wastewater Treatment Plants ◽  
Beijing China

scholarly journals Use of Sewage Sludge in Agriculture

2011 ◽  
Vol 68 (2) ◽  
Author(s):  
Daniela CIUPEANU CĂLUGĂRU
Keyword(s):  
Waste Water ◽  
Heavy Metals ◽  
Wastewater Treatment ◽  
Sewage Sludge ◽  
Environmental Protection ◽  
Environmental Quality ◽  
Wastewater Treatment Plants ◽  
Biological Sludge ◽  
The Law ◽  
High Degree

For turning to a high degree of favorability of sludge from wastewater treatment plants, currently the reintroduction in the natural circuit of this waste is an urgent priority. Knowing precisely the composition of chemical and biological sludge from waste water in accordance with the law and the rules of their application, along with modern wastewater treatment appropriate technologies play a key role on environmental protection. Involvement by precise rules, the content of heavy metals in relation to the maximum permitted by law, translate in to particularly advantageous results in terms of environmental quality.

scholarly journals Temporal variability of sewage sludge heavy metal content from Greek wastewater treatment plants

2016 ◽  
Vol 23 (2) ◽  
pp. 271-283 ◽  
Author(s):  
Thomas Spanos ◽  
Antoaneta Ene ◽  
Chrysoula Styliani Patronidou ◽  
Christina Xatzixristou
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wastewater Treatment ◽  
Sewage Sludge ◽  
Temporal Variability ◽  
Metal Content ◽  
Wastewater Treatment Plants ◽  
Chromium Species ◽  
Metal Concentrations ◽  
Metal Contents

AbstractThe aim of this study was to evaluate the temporal variations of selected heavy metals level in anaerobic fermented and dewatered sewage sludge. Sewage sludge samples were collected in different seasons and years from three municipal wastewater treatment plants (WWTPs) located in Northern Greece, in Kavala (Kavala and Palio localities) and Drama (Drama locality) Prefectures. An investigation of the potential of sludge utilization in agriculture was performed, based on the comparison of average total heavy metal concentrations and of chromium species (hexavalent, trivalent) concentrations with the allowed values according to the Council Directive 86/278/EEC and Greek national legislation (Joint Cabinet Decision 80568/4225/91) guidelines. In this regard, all the investigated heavy metals (Cd, Cr, Cu, Ni, Pb, Zn, Hg) and chromium species Cr(VI) and Cr(III) have average concentrations (dry matter weight) well below the legislated thresholds for soil application, as following: 2.12 mg kg−1Cd; 103.7 mg kg−1Cr; 136.4 mg kg−1Cu; < 0.2 mg kg−1Hg; 29.1 mg kg−1Ni; 62.0 mg kg−1Pb; 1253.2 mg kg−1Zn; 1.56 mg kg−1Cr(VI) and 115.7 mg kg−1Cr(III). Values of relative standard deviation (RSD) indicate a low or moderate temporal variability for domestic-related metals Zn (10.3-14.7%), Pb (27.9-44.5%) and Cu (33.5-34.2%), and high variability for the metals of mixed origin or predominantly resulted from commercial activities, such as Ni (42.4-50.7%), Cd (44.3-85.5%) and Cr (58.2-102.0%). For some elements the seasonal occurrence pattern is the same for Kavala and Palio sludge, as following: a) Cd and Cr: spring>summer>winter; b) Cu, Ni and Pb: winter>spring>summer. On average, in summer months (dry season) metal concentrations are lower than in spring and winter (wet seasons), with the exception of Zn. For Kavala and Palio the results demonstrate that the increased number of inhabitants (almost doubled) in summer time due to tourism does not influence the metal levels in sludge. Comparing the results obtained for similar spring-summer-winter sequences in 2007 and 2010/11 and for the spring season in 2007, 2008 and 2010, it can be noticed that, in general, the average heavy metal contents show an increasing tendency towards the last year. In all the measurement periods, the Palio sludge had the highest metal contents and Kavala sludge the lowest, leading to the conclusion that the WWTP operating process rather than population has a significant effect upon the heavy metal content of sludge. Cr(VI)/Cr(total) concentration ratios are higher for Kavala sludge in the majority of sampling campaigns, followed by Drama and Palio sludge. The metals which present moderate to strong positive correlation have common origin, which could be a domestic-commercial mixed source.

scholarly journals Determining Discharge Characteristics and Limits of Heavy Metals and Metalloids for Wastewater Treatment Plants (WWTPs) in China Based on Statistical Methods

Water ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 1248 ◽  
Author(s):  
Yuhua Zhou ◽  
Jing Lei ◽  
Yu Zhang ◽  
Jing Zhu ◽  
Yanna Lu ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Wastewater Treatment ◽  
Statistical Methods ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
Monitoring Data ◽  
Discharge Characteristics ◽  
Metals And Metalloids ◽  
Discharge Data ◽  
Heavy Metals And Metalloids

Industrial wastewater and sewage are both important sources of heavy metals and metalloids in urban wastewater treatment plants (WWTPs). China has made great efforts to control heavy metal and metalloid pollution by setting discharge limits for WWTPs. There is, however, limited discharge data and no systematic methodology for the derivation of discharge limits. In this study, 14 heavy metals and metalloids (Hg, alkyl mercury, As, Cd, Cr, Cr6+, Pb, Ni, Be, Ag, Cu, Zn, Mn, Se) that are listed in the Discharge Standard of Pollutants for Municipal Wastewater Treatment Plant (GB 18918-2002) were selected for the analysis of discharge characteristics while using the supervised monitoring data from more than 800 WWTPs located in nine provinces in China. Of the 14 heavy metals and metalloids, all but alkyl mercury were detected in the discharge water. There was a high rate of detection of As, Cu, Mn, Se, and there were some samples that exceeded the standard concentrations of Cr, Cr6+, Pb, and Ni. Removal rates of Hg, As, Cd, Cr, Cr6+, Pb, Ni, Cu, Zn, Mn, and Se were higher than 40%, comparable to values from other countries. Hg and As were selected to analyze the influencing factors of effluent and derive discharge limits of WWTPs using a statistical method, because these two metals had more detected data than other metals. The study used supervised monitoring data from Zhejiang WWTPs with 99 for Hg and 112 for As. Based on the delta-lognormal distribution, the results showed that geographic location was significantly closely correlated with Hg (P = 0.027 < 0.05) and As (P ≈ 0 < 0.05) discharge concentrations, while size (for Hg P = 0.695 > 0.05, for As P = 0.088 > 0.05) and influent concentration (R2 < 0.5) were not. Derived Hg and As discharge limits suggest that it is necessary to establish stricter discharge limits for WWTPs, which is more consistent with the real-world situation in China. The study here comprehensively researches the discharge characteristics of heavy metals and metalloids in effluent of WWTPs in China, and developed for the first time in China heavy metals and metalloids discharge limits based on statistical methods. The results may inform special discharge limit settings for WWTPs in China.

scholarly journals Radionuclide Transfer in the Zirconium Oxychloride Production Process and the Radiation Effect in a Typical Chinese Enterprise

2019 ◽  
Vol 11 (21) ◽  
pp. 5906
Author(s):  
Shoulong Xu ◽  
Qifan Wu ◽  
Xiaogang Li ◽  
Feng Yuan ◽  
Liangying Tu
Keyword(s):  
Wastewater Treatment ◽  
Production Process ◽  
Effective Dose ◽  
Radiation Effect ◽  
Wastewater Treatment Plants ◽  
Raw Materials ◽  
Zirconium Oxychloride ◽  
Manufacturing Enterprises ◽  
Study Results ◽  
Zircon Sand

The radiation impact on the environment from naturally-occurring radioactive materials in zircon sand is an important issue for zirconium product manufacturing enterprises. In this paper, a typical oxychloride production enterprise has been taken as an example to study the radiation effect and environmental pollution during the whole production process. The transfer and enrichment of radionuclides in zircon sand was studied by analyzing their concentrations in samples, such as products and wastes, which were sampled from every studied workshop, so that the dose rate in the environment and typical facility surfaces of each workshop could be measured. The study results show that the transfer and enrichment of radionuclides occur mainly in workshops of acidification, dissolution, concentration and crystallization. Silicon slag adsorbed some radionuclides, but most of the radionuclides in raw materials are transferred and enriched in waste acid by the concentration and crystallization process. Sludge and wastewater still contain a large quantity of radionuclides after treatment by wastewater treatment plants. This results in a significant increase in U-238 and Th-232 concentrations in river water near the main outlet. The average effective dose of all employees in the studied enterprises was 0.94 mSv, and workers from the wastewater treatment plants had the largest annual effective dose at 11 mSv.

Sign in / Sign up

Export Citation Format

Share Document