scholarly journals MOLECULAR INTERACTION STUDIES OF ZWITTER- ION IN AQUEOUS SUCROSE AND ASCORBIC ACID AT CONSTANT TEMPERATURE

2018 ◽  
Vol 6 (9) ◽  
pp. 356-363
Author(s):  
Yasmin Akhtar
Keyword(s):  
Ascorbic Acid ◽  
Hydration Number ◽  
Ternary Systems ◽  
Partial Molal Volume ◽  
Acid Solutions ◽  
Molal Volume ◽  
Solvent Interaction ◽  
Bonding Effect ◽  
Zwitter Ion ◽  
Hydrogen Bonding Effect

Density and viscosity of L-Arginine in aqueous sucrose and ascorbic acid  solutions have been determined experimentally at 298 K. The results obtained from density and viscosity measurement have been used to calculate the Hydration number Hn, apparent molar volume фv, partial molal volume ф0v , at infinite dilution, transfer volume ∆ф0tr   and B- coefficient. It has been observed that there exist strong solute-solvent interaction and complex formation between in these ternary systems. The properties of this amino acid in water and aqueous sucrose and ascorbic acid systems are discussed in terms of the charge, size and hydrogen bonding effect.

scholarly journals SOLUTE-SOLUTE AND SOLUTE-SOLVENT INTERACTIONS STUDIES OF SACCHARIDES IN AQUEOUS SODIUM BUTYRATE SOLUTION AT 308K TEMPERATURES

2020 ◽  
Vol 6 (11) ◽  
pp. 10-17
Author(s):  
Yasmin Akhtar ◽  
S. M. Yasin
Keyword(s):  
Aqueous Solution ◽  
Sodium Butyrate ◽  
Ternary Systems ◽  
Apparent Molal Volume ◽  
Partial Molal Volume ◽  
Molal Volume ◽  
Solvent Interactions ◽  
Bonding Effect ◽  
Solute Interactions ◽  
Hydrogen Bonding Effect

Density and viscosity of D (+) galactose and D (+) lactose mono hydrates in aqueous solution of sodium butyrate solutions have been determined experimentally at 308 K. The results obtained from density and viscosity measurement have been used to calculate the, apparent molal volume фv, partial molal volume ф0v, transfer volume ∆ф0tr at infinite dilution, A and B coefficient and Sv experimental slope. The results are interpreted in terms of solute-co- solute and solute-solvent interactions in these systems. It has been observed that there exist strong solute-solvent and solute-solute interactions and complex formation between in these ternary systems. The properties of the D (+) galactose and D (+) lactose mono hydrates in aqueous solution of sodium butyrate solutions are discussed in terms of the structure making and hydrogen bonding effect.

Ultrasonic and Density Studies of D(+) Mannose with Aqueous Electrolytes at 303K

2014 ◽  
Vol 1051 ◽  
pp. 215-220 ◽  
Author(s):  
Yasmin Akhtar
Keyword(s):  
Adiabatic Compressibility ◽  
Ternary Systems ◽  
Apparent Molal Volume ◽  
Partial Molal Volume ◽  
Molal Volume ◽  
Solvent Interaction ◽  
Solvent Interactions ◽  
Alkali Metal Halides ◽  
Experimental Values ◽  
Apparent Molal Adiabatic Compressibility

The present experimental investigation was carried out in order to explore the possible molecular interactions of D(+) mannose with mixed solvent of aqueous NaCl, KCl , MgCl2and CaCl2at 303 K. Experimental values of densities and ultrasonic velocities were carried out of the ternary mixture solution D(+) mannose with aqueous NaCl ,KCl, MgCl2and CaCl2. Aqueous alkali metal halides (NaCl ,KCl , MgCl2and CaCl2) were added under different molalities with D(+) mannose. The related and relevant parameters correlated to the present study such as adiabatic compressibility Ks, acoustic impedance Z, apparent molal volume фv, apparent molal adiabatic compressibility, фKs, and partial molal volume ф0vand partial molal adiabatic compressibility, фoKsat infinite dilution. The present investigation has exploited the possible molecular associations such as ion-ion, ion-solvent, solute-solute and solute-solvent interactions in these systems. It has been observed that there exist strong solute-solvent interaction and complex formation between in these ternary systems.

scholarly journals Some Physical Properties of Aqueous L-Ascorbic Acid Solutions

1979 ◽  
Vol 32 (10) ◽  
pp. 2293 ◽  
Author(s):  
M Shamim ◽  
SB Khoo
Keyword(s):  
Ascorbic Acid ◽  
Refractive Index ◽  
Physical Properties ◽  
Infinite Dilution ◽  
Relative Viscosity ◽  
Partial Molal Volume ◽  
Acid Solutions ◽  
Molal Volume ◽  
Undissociated Acid

The density, viscosity and refractive index of aqueous L-ascorbic acid solutions, in the concentration range 0.01-1.20 M, have been measured at 25�C. The partial molal volume of the undissociated acid at infinite dilution has been found to be 105.74 cm3 mol-1. Equations which describe the density and relative viscosity of the solutions have also been given.

scholarly journals INTERACTION STUDIES OF AMINO ACIDS IN AQUEOUS SODIUM BROMIDE SOLUTIONS AT DIFFERENT TEMPERATURE

2017 ◽  
Vol 5 (10) ◽  
pp. 160-167
Author(s):  
Yasmin Akhtar
Keyword(s):  
Amino Acids ◽  
Infinite Dilution ◽  
Adiabatic Compressibility ◽  
Sodium Bromide ◽  
Apparent Molal Volume ◽  
Partial Molal Volume ◽  
Molal Volume ◽  
Solvent Interactions ◽  
Aqueous Sodium ◽  
Bonding Effect

Densities, ultrasonic velocities and viscosities of L- Valine and L- Phenylalanine in aqueous sodium bromide (0.00, 0.025 and 0.05) m solutions have been determined experimentally at 308 and 313 K. The results obtained from density ultrasonic velocity and viscosity measurement have been used to calculate the apparent molal volume, фv, apparent molal, adiabatic compressibility ф Ks, partial molal volume ф0v at infinite dilution, partial molal adiabatic compressibility ф0Ks at infinite dilution, transfer volume ∆ф(tr), experimental slopes Sv and SKs,Falkenhagen coefficient A and  Jones-Dole B coefficient. The results are discussed in terms of the dehydration effect of the sodium bromide upon the amino acids and weak solute- solute and strong solute- solvent interactions. The properties of these amino acids in water and water + sodium bromide solution systems are discussed in terms of the charge, size and hydrogen bonding effect.

scholarly journals Acoustic and Volumetric Properties of Digoxin and Thiabendazole in 1, 4 Dioxane at 303 K

2010 ◽  
Vol 7 (3) ◽  
pp. 789-794 ◽  
Author(s):  
A. N. Sonar ◽  
N. S. Pawar
Keyword(s):  
Adiabatic Compressibility ◽  
Viscosity Coefficient ◽  
Volumetric Properties ◽  
Apparent Molal Volume ◽  
Partial Molal Volume ◽  
Molal Volume ◽  
Solvent Interaction ◽  
Acoustical Parameter ◽  
Solute Interaction ◽  
Apparent Molal Compressibility

Acoustical and volumetric properties have been measured for substituted heterocyclic compounds digoxin and thiabendazole in 1, 4 dioxane at 303 K. The ultrasonic velocity measurement have been performed to evaluate acoustical parameter such as adiabatic compressibility (βs), partial molal volume (ɸv), intermolecular free length (Lf), apparent molal compressibility (ɸk), specific acoustic impedance (Z), relative association (RA), salvation number (Sn), limiting apparent molal compressibility (ɸ0k), limiting apparent molal volume(ɸ0v) and their constant (Sk,Sv). The viscosity coefficient (A, B) was evaluated by using john–dole equation. These parameters throw the light on the solute-solvent interaction and solute-solute interaction.

scholarly journals Volumetric and viscometric studies on electrolytes in non-aqueous solvent

1970 ◽  
Vol 4 (2) ◽  
pp. 15-18
Author(s):  
MA Yousuf ◽  
KM Salim Reza ◽  
Md Moniruzzaman ◽  
MA Aziz ◽  
MA Salam
Keyword(s):  
Binary Systems ◽  
Viscosity Coefficient ◽  
Shape Effect ◽  
Partial Molal Volume ◽  
Molal Volume ◽  
Solvent Interactions ◽  
Viscosity Coefficients ◽  
Bonding Effect ◽  
Volume Viscosity ◽  
Aqueous Solvent

The densities, ρ and viscosities, η of NH4Cl, NiCl2 and FeCl3 in dimethylsulfoxide were studied as a function of concentration. The partial molal volume, (φ0v) of these electrolytes were evaluated. The viscosity and viscosity-coefficients (A and B) were also determined by Jones-Dole equation. B-coefficient for NiCl2 and FeCl3 are positive that show structure making behavior in all the solutions while those of NH4Cl are negative indicating structure breaking properties. The coefficient A represents the solute-solute interactions coupled with size and shape effect of the solute and to some extent solute-solvent interactions. The behaviors of three solutes in binary systems were discussed in terms of the charge, size and hydrogen bonding effect. Keywords: Density, Apparent and partial molal volume, viscosity coefficient. DOI: 10.3329/diujst.v4i2.4360 Daffodil International University Journal of Science and Technology Vol.4(2) 2009 pp.15-18

scholarly journals A volumetric and viscometric study of 4-aminobutyric acid in aqueous solutions of metformin hydrochloride at 308.15, 313.15 and 318.15k

2011 ◽  
Vol 76 (1) ◽  
pp. 129-142 ◽  
Author(s):  
K. Rajagopal ◽  
S.S. Jayabalakrishnan
Keyword(s):  
Infinite Dilution ◽  
Hydration Number ◽  
Aminobutyric Acid ◽  
Metformin Hydrochloride ◽  
Second Derivative ◽  
Partial Molal Volume ◽  
Molal Volume ◽  
Free Energy Of Activation ◽  
Volume Of Transfer ◽  
Viscometric Study

Density(?) and viscosity (?) measurements were performed for 4-aminobutyric acid in 0.05, 0.10 and 0.15 M aqueous metformin hydrochloride at 308.15, 313.15 and 318.15 K. The measured values of density and viscosity were used to estimate some important parameters, such as the partial molal volume, V?, the standard partial molal volume V0? , the standard partial molal volume of transfer, ?V0?, the hydration number, nH, the second derivative of the infinite dilution of the standard partial molal volume with temperature ?2V0?/?T2, the viscosity Bcoefficients, variation of B with temperature, dB/dT , the free energy of activation per mole of solvent ??01

scholarly journals Ultrasonic Studies of Some Biomolecules in Aqueous Guanidine Hydrochloride Solutions at 298.15 K

2011 ◽  
Vol 8 (3) ◽  
pp. 1146-1151
Author(s):  
R. Palani ◽  
A. Geetha ◽  
S. V. S. L. Poornima
Keyword(s):  
Experimental Data ◽  
Guanidine Hydrochloride ◽  
Hydration Number ◽  
Adiabatic Compressibility ◽  
Apparent Molal Volume ◽  
Acoustical Parameters ◽  
Molal Volume ◽  
Solvent Interaction ◽  
Solute Solvent Interaction ◽  
Apparent Molal Compressibility

Ultrasonic velocity (U), viscocity (η) and density (ρ) ofL- ascorbic acid, dextrose and sucrose in aqueous guanidine hydrochloride (0.3 m) have been measured at 298.15 K. The derived acoustical parameters namely adiabatic compressibility (β), apparent molal compressibility (ΨK) apparent molal volume (ΨV) limiting apparent molal compressibility (Ψ0K) limiting apparent molal volume (Ψ0V) and their constants (SK, Sv) and viscosityB- coefficient and hydration number (nH) have been computed from the experimental data. The variation of these parameters with respect to the molality of solutes have been explained on the basis of solute-solvent interaction and structure making tendency of the solutes in solvents.

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