scholarly journals Rare earth ion contribution in barium hexaferrite structure to a change of magnetocrystalline anisotropy to improving its magnetic properties

Author(s):  
I Gusti Agung Putra Adnyana

Rare earth ion contribution in barium hexaferrite structure to a change of magneto-crystalline anisotropy to improving its magnetic properties has been investigated. A series of simples of Ba1-xCexFe12O19 with the variation of x (x = 0.0-0.5) were prepared by solid-state reactions using mechanical deformation techniques. The oxide materials used for sample preparation are BaCO3, Fe2O3, and CeO2 with the ratio of material used is adjusted to the stoichiometric calculation for variations of Ce4+ substitution. The phase identification results show that the reaction took place perfectly and successfully formed a single-phase Ba1-xCexFe12O19 namely at the composition x = 0 and x = 0.1. while for the composition x> 0.1, it is formed in three phases. Particle morphology in the composition x = 0 and x = 0.1 has very good and uniform particle homogeneity across the surface of the sample in the form of polygonal particles. So the substitution of Ce atoms into the barium hexaferrite structure is only able at the composition limit x = 0.1. In the composition x = 0.1 has been able to increase the coercivity and magnetization fields. It can be concluded that the permanent magnet with the composition Ba0,9Ce0.1F12O19 gives the best results.

2010 ◽  
Vol 159 ◽  
pp. 57-62 ◽  
Author(s):  
Tatyana Koutzarova ◽  
Svetoslav Kolev ◽  
Kornely Grigorov ◽  
Chavdar Ghelev ◽  
Andrzej Zaleski ◽  
...  

Thin hexagonal barium hexaferrite particles synthesized using the microemulsion technique were studied. A water-in-oil reverse microemulsion system with cetyltrimethylammonium bromide (CTAB) as a cationic surfactant, n-butanol as a co-surfactant, n-hexanol as a continuous oil phase, and an aqueous phase were used. The microstructural and magnetic properties were investigated. The particles obtained were mono-domain with average particle size 280 nm. The magnetic properties of the powder were investigated at 4.2 K and at room temperature. The saturation magnetization was 48.86 emu/g and the coercivity, 2.4 x 105 A/m at room temperature. The anisotropy field Ha and magneto-crystalline anisotropy K1 were 1.4 x 106 A/m and 2.37 x 105 J/m3, respectively.


2006 ◽  
Vol 60 (1) ◽  
pp. 1-6 ◽  
Author(s):  
Lijun Zhao ◽  
Hua Yang ◽  
Xueping Zhao ◽  
Lianxiang Yu ◽  
Yuming Cui ◽  
...  

2016 ◽  
Vol 09 (06) ◽  
pp. 1642010 ◽  
Author(s):  
Biswanath Dutta ◽  
Ingo Opahle ◽  
Tilmann Hickel

The effect of interfaces on the magnetic properties of multilayers is analyzed for Ni2MnGa/Ni2MnSn system using density functional theory. The Ni spin moments at the interface change by about 30% compared to the bulk value, whereas the effect on the Mn spin moments is much less pronounced. A similar strong effect is also observed for the Ni orbital moments at the interface. The magneto-crystalline anisotropy of the multilayer systems can be understood by the additive contribution of the respective values of strained bulk materials.


2019 ◽  
Vol 10 ◽  
pp. 1348-1359 ◽  
Author(s):  
Hajar Jalili ◽  
Bagher Aslibeiki ◽  
Ali Ghotbi Varzaneh ◽  
Volodymyr A Chernenko

Recent advances in the field of magnetic materials emphasize that the development of new and useful magnetic nanoparticles (NPs) requires an accurate and fundamental understanding of their collective magnetic behavior. Studies show that the magnetic properties are strongly affected by the magnetic anisotropy of NPs and by interparticle interactions that are the result of the collective magnetic behavior of NPs. Here we study these effects in more detail. For this purpose, we prepared Co x Fe3− x O4 NPs, with x = 0–1 in steps of 0.2, from soft magnetic (Fe3O4) to hard magnetic (CoFe2O4) ferrite, with a significant variation of the magnetic anisotropy. The phase purity and the formation of crystalline NPs with a spinel structure were confirmed through Rietveld refinement. The effect of Co doping on structure, morphology and magnetic properties of Co x Fe3− x O4 samples was investigated. In particular, we examined the interparticle interactions in the samples by δm graphs and Henkel plots that have not been reported before in literature. Finally, we studied the hyperthermia properties and observed that the heat efficiency of soft Fe3O4 is about 4 times larger than that of hard CoFe2O4 ferrite, which was attributed to the high coercive field of samples compared with the external field amplitude.


2012 ◽  
Vol 13 (1) ◽  
pp. 13
Author(s):  
Erwin Erwin

Co/Sm multilayer films with structure of 20 [Co (x nm)/Sm (1.2 nm)] where x = 1.1, 2.2 and 4.2 nm and 20[Co (4.2nm)/Sm (x nm)] where x=1.2 nm to 7.5 nm were fabricated using dc magnetron sputtering. Each multilayer filmconsisted of 20 bilayers of Co layers with various thicknesses sandwiched with Sm layers. The application of lowangle X-ray diffraction measurements to the characterization of these multilayers is described. The periodiclayered structure with sharp interfaces was observed for all multilayer films. The measured magnetization valuesare lower than the values calculated in terms of the nominal concentration of cobalt in the multilayers. This impliessignificant “mixing” at small film thickness. The formation of a high magneto crystalline anisotropy of CoSm alloyat the interfaces, as a result of interdiffusion between Co and Sm layers was considered to be responsible for theincrease of the coercivity for Co/Sm multilayer.


The theory of the magnetic properties of rare-earth ions in crystals, which has been developed in preceding papers, is here applied to the ethyl sulphates. The magnetic resonance and susceptibility results are discussed at length, and it is shown that the observations can be explained by using fields of C 3۸ symmetry which vary in a systematic way as one rare-earth ion is replaced by another.


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