scholarly journals The optical properties of (PVA+PVP) + PANI blends

2019 ◽  
Vol 13 (28) ◽  
pp. 162-169
Author(s):  
Jinan M. Hassan Jabir

Polyaniline polymer has been prepared by chemical oxidationpolymerization method in laboratory successfully. The PANI and(PVA+PVP) as a polymer blends in different percentage (30%, 50%,70%) from Polyaniline was prepared. The sample was studies asoptical properties by UV-vis spectrophotometer at (400-700) nm.The result of optical energy gap was 2.23 eV for pure (PVA+ PVP)and with additive was increasing with increasing PANI concentrationto become (2.49 for 30% to 2.52 for 70%) PANI. The goal of thisproject is prepare triple blend polymer and study the effect when addconductive polymer (Polyaniline) on the optical properties andcalculate optical constant as energy gap, refractive index, dielectricconstant and dielectric losses for (PVA+PVP) blends.

2006 ◽  
Vol 3 (1) ◽  
pp. 56-61
Author(s):  
Baghdad Science Journal

In this research study the effect of fish on the properties optical films thickness 1200-1800 and calculated energy gap Basra direct transport permitted and forbidden to membranes and urged decreasing values ??of Optical Energy Gap increase fish included accounts optical also calculate the constants visual as factories winding down and the refractive index and reflectivity membranes also by real part and imaginarythe dielectric constant


2013 ◽  
Vol 724-725 ◽  
pp. 176-179
Author(s):  
T. Zhang ◽  
H. Wang ◽  
Z.Y. Zhong ◽  
C.Y. Yang ◽  
Jin Hou

Transparent conducting gallium-titanium codoped zinc oxide thin films were grown onto glass substrates with magnetron sputtering technique in ambient argon gas, and the influence of argon pressure on optical properties of the films were investigated. The refractive indexes of the films were calculated. It is found that the refractive index tends to increase with increasing the photon energy. Meanwhile, the dispersion behavior of the refractive index was analyzed in terms of the single-oscillator model and the oscillator parameters were obtained. Furthermore, the optical energy gaps were evaluated by single-oscillator model and Tauc’s relation, respectively. The values of optical energy gap estimated from single-oscillator model are in agreement with those determined from Tauc’s relation.


2014 ◽  
Vol 11 (2) ◽  
pp. 518-526
Author(s):  
Baghdad Science Journal

Thin films of pure tin mono-sulfide SnS and tin mono-sulfide for (1,2,3,4)% fluorine SnS:F with Thicknesses of (0.85 ±0.05) ?m and (0.45±0.05) ?m respectively were prepared by chemical spray pyrolysis technique. the effect of doping of F on structural and optical properties has been studied. X-Ray diffraction analysis showed that the prepared films were polycrystalline with orthorhombic structure. It was found that doping increased the intensity of diffraction peaks. Optical properties of all samples were studied by recording the absorption and transmission spectrum in range of wave lengths (300-900) nm. The optical energy gap for direct forbidden transition and indirect allowed transition were evaluated It is found that for doping less than 2% the optical energy gap increases as the percentage of doping increases in the samples while for doping more than 2% the values of the optical energy gap decreases as the percentage of doping increases.


2016 ◽  
Vol 23 (02) ◽  
pp. 1650001 ◽  
Author(s):  
ZAKI S. KHALIFA

Crystal structure, microstructure, and optical properties of TiO2 thin films deposited on quartz substrates by metal-organic chemical vapor deposition (MOCVD) in the temperature range from 250[Formula: see text]C to 450[Formula: see text]C have been studied. The crystal structure, thickness, microstructure, and optical properties have been carried out using X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), atomic force microscope (AFM), and UV-visible transmittance spectroscopy, respectively. XRD patterns show that the obtained films are pure anatase. Simultaneously, the crystal size calculated using XRD peaks, and the grain size measured by AFM decrease with the increase in deposition temperature. Moreover, the texture of the films change and roughness decrease with the increase in deposition temperature. The spectrophotometric transmittance spectra have been used to calculate the refractive index, extinction coefficient, dielectric constant, optical energy gap, and porosity of the deposited films. While the refractive index and dielectric constant decrease with the increase of deposition temperature, the porosity shows the opposite.


2017 ◽  
Vol 28 (1) ◽  
pp. 158
Author(s):  
Asrar A. Saeed

Effects of methyl green (MG) dye on the optical properties of polystyrene (PS) have been studied. Pure polystyrene and MG doped PS films were prepared by using casting method. These films were characterized using UV/VIS spectrophotometer technique in order to estimate the type of electric transition which was found to be indirect transition. The value of the optical energy gap was decreased with increasing doping ratios of methyl green dye. Absorption coefficient, extinction coefficient, refractive index and energy gap have been also investigated; it was found that all the above parameters affects by doping dye.


2018 ◽  
Vol 16 (36) ◽  
pp. 181-189
Author(s):  
Salma Mohamed H.

The optical energy gap and optical constants such as the reflective index, dielectric constant have been evaluated due to The optical transmission and UV-VIS absorption spectra have been recorded in the wavelength (200 - 1100 nm) for PVA/PANI polymer blends and PVA/PANI/ZnO nanocomposites with different concentrations of ZnO (0.02, 0.05, 0.07, 0.1and 0.2) wt %. The results indicate that the materials have allowed direct transition. The reflection index and dielectric constant are increase with wavelength


2019 ◽  
Vol 15 (32) ◽  
pp. 99-113
Author(s):  
Mahdi Hasan Suhail

Polymer films of PEG and PVA and their blend with differentconcentrations of MnCl2 (0, 2, 4, 6 and 10 %.wt) were study usingcasting technique. The X-ray spectra of pure PEG, PVA andPVA:PEG films and with addition of 2% concentrations from(MnCl2) show amorphous structures. The results for FTIR show theinteraction between the filler and polymer blend results indecreasing crystallinity with rich amorphous phase. Thisamorphous nature confirms the complexation between the filler andthe polymer blend. The optical properties of (PVA:PEG/MnCl2)contain the recording of absorbance (A) and explain that theabsorption coefficient (α), refractive index (n), extinction coefficient(ko) and the dielectric constants (real and imaginary part) increasewith increasing the concentration of Composite (PVA:PEG/MnCl2).The optical energy gap for electrons transitions both are direct andindirect allowed.


2019 ◽  
Vol 30 (1) ◽  
pp. 193
Author(s):  
Karrar Mahdi Saleh

In the present work, undoped CdS and doped with iron CdS:Fe+3 thin films have been prepared by chemical spray pyrolysis method on glass substrate with different temperature from cadmium nitrate solution with constant thickness(450 ± 5 nm), and study the effect of the percentage of doping with iron on optical properties of prepared films. The optical properties have been studied from transmittance and absorbance spectral within wavelengths range (380-900 nm). The results showed that all the prepared films has direct electronic transitions and optical energy gap between (2.31-2.44 eV). They also showed that the transmittance and optical energy gap of films prepared from nitrate solution increase with increasing of substrate temperature, then transmittance start downward with the continued increase in temperature (400, 450 oC), and a decrease in the optical energy gap with increasing doping percentage with iron.


Author(s):  
Nahida B. Hasan ◽  
Mohammed Ahmed Mohammed

In this paper, the design of spray pyrolysis system to prepare thin films of various materials system. The study showed that films prepared with good characteristics. films were prepared from lead oxide PbO this way. The study of the optical properties of these films and through recording the absorbance spectrum and transmittance spectrum of films prepared in the wavelength range (300-1100) nm . Optical constant for thin films prepared such as absorption coefficient, the extinction coefficient , the refractive index and the optical energy gap was calculated as well. films prepared found that it has a direct energy gap value 3.1eV.


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