scholarly journals Optical Properies of Polystyrene Films Doped by Methyl Green Dye

2017 ◽  
Vol 28 (1) ◽  
pp. 158
Author(s):  
Asrar A. Saeed

Effects of methyl green (MG) dye on the optical properties of polystyrene (PS) have been studied. Pure polystyrene and MG doped PS films were prepared by using casting method. These films were characterized using UV/VIS spectrophotometer technique in order to estimate the type of electric transition which was found to be indirect transition. The value of the optical energy gap was decreased with increasing doping ratios of methyl green dye. Absorption coefficient, extinction coefficient, refractive index and energy gap have been also investigated; it was found that all the above parameters affects by doping dye.

2016 ◽  
Vol 23 (02) ◽  
pp. 1650001 ◽  
Author(s):  
ZAKI S. KHALIFA

Crystal structure, microstructure, and optical properties of TiO2 thin films deposited on quartz substrates by metal-organic chemical vapor deposition (MOCVD) in the temperature range from 250[Formula: see text]C to 450[Formula: see text]C have been studied. The crystal structure, thickness, microstructure, and optical properties have been carried out using X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), atomic force microscope (AFM), and UV-visible transmittance spectroscopy, respectively. XRD patterns show that the obtained films are pure anatase. Simultaneously, the crystal size calculated using XRD peaks, and the grain size measured by AFM decrease with the increase in deposition temperature. Moreover, the texture of the films change and roughness decrease with the increase in deposition temperature. The spectrophotometric transmittance spectra have been used to calculate the refractive index, extinction coefficient, dielectric constant, optical energy gap, and porosity of the deposited films. While the refractive index and dielectric constant decrease with the increase of deposition temperature, the porosity shows the opposite.


2019 ◽  
Vol 15 (32) ◽  
pp. 99-113
Author(s):  
Mahdi Hasan Suhail

Polymer films of PEG and PVA and their blend with differentconcentrations of MnCl2 (0, 2, 4, 6 and 10 %.wt) were study usingcasting technique. The X-ray spectra of pure PEG, PVA andPVA:PEG films and with addition of 2% concentrations from(MnCl2) show amorphous structures. The results for FTIR show theinteraction between the filler and polymer blend results indecreasing crystallinity with rich amorphous phase. Thisamorphous nature confirms the complexation between the filler andthe polymer blend. The optical properties of (PVA:PEG/MnCl2)contain the recording of absorbance (A) and explain that theabsorption coefficient (α), refractive index (n), extinction coefficient(ko) and the dielectric constants (real and imaginary part) increasewith increasing the concentration of Composite (PVA:PEG/MnCl2).The optical energy gap for electrons transitions both are direct andindirect allowed.


Author(s):  
Nahida B. Hasan ◽  
Mohammed Ahmed Mohammed

In this paper, the design of spray pyrolysis system to prepare thin films of various materials system. The study showed that films prepared with good characteristics. films were prepared from lead oxide PbO this way. The study of the optical properties of these films and through recording the absorbance spectrum and transmittance spectrum of films prepared in the wavelength range (300-1100) nm . Optical constant for thin films prepared such as absorption coefficient, the extinction coefficient , the refractive index and the optical energy gap was calculated as well. films prepared found that it has a direct energy gap value 3.1eV.


2019 ◽  
Vol 13 (28) ◽  
pp. 162-169
Author(s):  
Jinan M. Hassan Jabir

Polyaniline polymer has been prepared by chemical oxidationpolymerization method in laboratory successfully. The PANI and(PVA+PVP) as a polymer blends in different percentage (30%, 50%,70%) from Polyaniline was prepared. The sample was studies asoptical properties by UV-vis spectrophotometer at (400-700) nm.The result of optical energy gap was 2.23 eV for pure (PVA+ PVP)and with additive was increasing with increasing PANI concentrationto become (2.49 for 30% to 2.52 for 70%) PANI. The goal of thisproject is prepare triple blend polymer and study the effect when addconductive polymer (Polyaniline) on the optical properties andcalculate optical constant as energy gap, refractive index, dielectricconstant and dielectric losses for (PVA+PVP) blends.


2006 ◽  
Vol 3 (1) ◽  
pp. 56-61
Author(s):  
Baghdad Science Journal

In this research study the effect of fish on the properties optical films thickness 1200-1800 and calculated energy gap Basra direct transport permitted and forbidden to membranes and urged decreasing values ??of Optical Energy Gap increase fish included accounts optical also calculate the constants visual as factories winding down and the refractive index and reflectivity membranes also by real part and imaginarythe dielectric constant


2014 ◽  
Vol 11 (2) ◽  
pp. 695-701
Author(s):  
Baghdad Science Journal

In this work, study the optical properties of composites consisting of poly Methyl Methacrylate and Berry Paper Mulberry. The samples of composites were prepared using casting method .The Berry Paper Mulberry (BPM) was added by different concentrations are (0, 2, 4 and 6)wt.%. The optical properties of composites have been studied in the wavelength range (200-800)nm. The absorption coefficient ,energy gap, refractive index, extinction coefficient and dielectric constants have been determined. The results show that the optical constants change with increase of BPM concentrations .


2017 ◽  
Vol 35 (2) ◽  
pp. 335-345 ◽  
Author(s):  
A.M. Abd-Elnaiem ◽  
M. Mohamed ◽  
R.M. Hassan ◽  
A.A. Abu-Sehly ◽  
M.A. Abdel-Rahim ◽  
...  

Abstract Chalcogenide glasses have attracted much attention largely due to their interesting physical and chemical properties. Though few published articles exist on the As-Te system, little is known about the optical properties of eutectic or near eutectic composition of As-Te system upon heat treatment. Therefore, this paper reports the effects of annealing temperature on the structural and optical parameters of As30Te70 thin films. The bulk and thin films of 150 nm thick As30Te70 chalcogenide glasses were prepared by melt-quenching and thermal evaporation techniques, respectively. The glass transition and crystallization reactions of the bulk samples were investigated using differential scanning calorimetry (DSC). The influence of annealing temperature on the transformation of the crystal structure was studied by X-ray diffraction (XRD), while the surface morphology of the annealed samples was examined using scanning electron microscope (SEM). The optical band gap, refractive index and extinction coefficient were also calculated. The DSC scans showed that the melting temperature remains constant at 636.56 K. In addition, other characteristic temperatures such as the glass transition temperature, the onset crystallization temperature, and the crystallization peak temperature increase with increasing the heating rate. The crystalline phases for the as-prepared and annealed films consist of orthorhombic As, hexagonal Te, and monoclinic As2Te3 phases. Furthermore, the average crystallite size, strain, and dislocation density depend on the annealing temperature. The optical absorption results revealed that the investigated films have a direct transition, and their optical energy gap decreases from 1.82 eV to 1.49 eV as the annealing temperature increases up to 433 K. However, the refractive index, extinction coefficient, dielectric constant and the ratio of free carrier concentration to its effective mass, increase with increasing the annealing temperature.


2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Tagreed K. Hamad ◽  
Rahimi M. Yusop ◽  
Wasan A. Al-Taa’y ◽  
Bashar Abdullah ◽  
Emad Yousif

The effect of continuous CO2laser radiation on the optical properties of pure polyvinyl chloride and doped of ZnO nanoparticles with two different concentrations (10, 15%) has been investigated. All samples were prepared using casting method at room temperature. Optical properties (absorption, transmission, absorption coefficient, extinction coefficient, refractive index, and optical conductivity) of all films after CO2laser irradiated have been studied as a function of the wavelength in the range (200–800) nm for three energies (300, 400 and 500 mJ). It has been found that the transmission, energy gap, and refractive index increase with increasing laser energy. The values of absorption, Urbach energy, absorption coefficient, extinction coefficient, and optical conductivity were decreased.


2013 ◽  
Vol 724-725 ◽  
pp. 176-179
Author(s):  
T. Zhang ◽  
H. Wang ◽  
Z.Y. Zhong ◽  
C.Y. Yang ◽  
Jin Hou

Transparent conducting gallium-titanium codoped zinc oxide thin films were grown onto glass substrates with magnetron sputtering technique in ambient argon gas, and the influence of argon pressure on optical properties of the films were investigated. The refractive indexes of the films were calculated. It is found that the refractive index tends to increase with increasing the photon energy. Meanwhile, the dispersion behavior of the refractive index was analyzed in terms of the single-oscillator model and the oscillator parameters were obtained. Furthermore, the optical energy gaps were evaluated by single-oscillator model and Tauc’s relation, respectively. The values of optical energy gap estimated from single-oscillator model are in agreement with those determined from Tauc’s relation.


2021 ◽  
Vol 19 (4) ◽  
pp. 27-37
Author(s):  
Doaa E. Al-Kateb ◽  
Ali R. Abdulridha

In this study preparing and investigating of the (PVA/PVP:Sr2NO3) nanocomposites films by using casting method with different concentration of Sr2NO3 as (0, 1, 3, 5, and 7 wt. %). Optical properties obtained by UV-Vis spectrometer, OM and FTIR spectra have been revealed in this study, the absorbance increased by increasing of Sr2NO3 nanoparticles concentrations, the energy-gap (allowed and forbidden) transitions decreased by increasing of the nanoparticles concentration.


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