Separation of titanium and silicon oxides during plasma-arc melting of quartz-leucoxene concentrate
The aim of the work was investigation of separation of titanium’s and silicon’s oxides during plasma-arc melting of quartz-leucoxene concentrate from Yarega deposit. The melting was proceeded in laboratory plasma-arc furnace in graphite crucible at 16 – 40 kW of arc power. The microstructure and R-x phase analysis of solidified melt were investigated after arc melting. The melt separated on two layers. The upper layer consisted mainly of SiO2 in the form of glass, the lower layer — mainly of cemented titanium oxide particles ≈ 100 μm in dimension. TiO2, Ti8O15, Ti6O11, Fe3TiO3O10, Ti3O5 were observed. These particles formed during melting and moved throw liquid glass to the bottom of crucible with the speed of V ≈ 10–4 m/s. The separation of TiO2 and SiO2 required energy W ≈ 100 GJ/t of concentrate in laboratory plasma arc furnace. The possibility of industrial employment of the arc melting separation was discussed. The estimated energy requirement was about 5 GJ/t in 20-t arc furnace.