Modeling of Dynamics of Cu, Ni and Mn Compounds in the Soil Profile Under Artificial Phytocenoses of MSU Soil Lysimeters

2021 ◽  
Vol 76 (3) ◽  
pp. 120-126
Author(s):  
M. V. Evdokimova ◽  
G. P. Glazunov ◽  
I. O. Plekhanova ◽  
G. V. Abrosimova
Keyword(s):  
Soil Profile ◽  
Modeling Of Dynamics ◽  
Soil Lysimeters

Chromium(VI) leaching from large undisturbed soil lysimeters following application of a simulated copper-chromium-arsenic (CCA) timber preservative

Soil Research ◽  
2002 ◽  
Vol 40 (2) ◽  
pp. 351 ◽  
Author(s):  
P. L. Carey ◽  
V. J. Bidwell ◽  
R. G. McLaren
Keyword(s):  
Organic Matter ◽  
Soil Profile ◽  
Sandy Loam ◽  
Soil Analysis ◽  
Rainfall Simulation ◽  
Soil Cores ◽  
Undisturbed Soil ◽  
First Order ◽  
Copper Chromium ◽  
Soil Lysimeters

Copper, chromium, and arsenic (CCA) solutions are commonly used in New Zealand as a means of preserving softwood timbers such as Pinus radiata. With stock working solutions of CCA salts in timber treatment plants frequently 10% w/v or more, there exists a potential for spillage and leaching of these compounds to groundwater. High concentrations of Cr(VI) (up to 52 mg Cr/L) were found in the leachates of large undisturbed soil lysimeters where a Templeton sandy loam (Immature Pallic) had received surface applications of a simulated copper, chromium, and arsenic (CCA) timber preservative. Leaching was produced by using a combination of natural and imposed rainfall simulation over the lysimeters for a period of 102 days after CCA application. An average of 26% of the applied chromium was collected in the leachates after 102 days. Of the mean 74% of Cr(VI) still retained within the soil profile after leaching ended, almost half was located in the top 100 mm of the profile. No copper or arsenic was detected in any of the lysimeter leachates, with soil analysis indicating that these elements had been retained within the soil profile. In an incubation study, soil cores sampled from the same Templeton sandy loam and split into alternate 50-mm segments (to 450 mm) were stored at 10˚C for 102 days after addition of an identical CCA solution. These were periodically extracted for available chromium. Results showed that the reduction of dichromate/chromate anions (Cr2O72–/CrO42–) to the strongly sorbed chromic cation (Cr3+) was largely first-order and greatest in surface layers where soil organic matter contents were largest. After 102 days, <1% of the added Cr(VI) was still extractable in the 0–50 mm soil cores whilst ≈60% of Cr(VI) in the 400–450 mm cores (or deeper) was still extractable after the same period. A linear systems model comprising a series of conceptual mixing cells was used to describe the individual and mean Cr(VI) leaching breakthrough curves (BTCs). This State-Space Mixing Cell model proved effective in simulating the Cr(VI) leaching using first-order kinetics to quantify rate-limited local solute adsorption coupled to advective-dispersive transport. The solute mass involved in the model process was ≈30%. The bulk of the remaining 70% of applied dichromate was assumed to have undergone reduction to the non-mobile chromium cation. This study shows that there exists a significant potential for Cr(VI) to be a serious threat to groundwater in the event of a large uncontained spillage of a concentrated CCA solution. This potential can be significantly lessened if the Cr(VI) is reduced after retention in an organic matter rich layer.

Corrigendum to: Chromium(IV) leaching from large undisturbed soil lysimeters following application of a simulated copper-chromium-arsenic (CCA) timber preservative

Soil Research ◽  
2002 ◽  
Vol 40 (4) ◽  
pp. 715 ◽  
Author(s):  
P. L. Carey ◽  
V. D. Bidwell ◽  
R. G. McLaren
Keyword(s):  
Organic Matter ◽  
Soil Profile ◽  
Sandy Loam ◽  
Soil Analysis ◽  
Rainfall Simulation ◽  
Soil Cores ◽  
Undisturbed Soil ◽  
First Order ◽  
Copper Chromium ◽  
Soil Lysimeters

Copper, chromium, and arsenic (CCA) solutions are commonly used in New Zealand as a means of preserving softwood timbers such as Pinus radiata. With stock working solutions of CCA salts in timber treatment plants frequently 10% w/v or more, there exists a potential for spillage and leaching of these compounds to groundwater. High concentrations of Cr(VI) (up to 52 mg Cr/L) were found in the leachates of large undisturbed soil lysimeters where a Templeton sandy loam (Immature Pallic) had received surface applications of a simulated copper, chromium, and arsenic (CCA) timber preservative. Leaching was produced by using a combination of natural and imposed rainfall simulation over the lysimeters for a period of 102 days after CCA application. An average of 26% of the applied chromium was collected in the leachates after 102 days. Of the mean 74% of Cr(VI) still retained within the soil profile after leaching ended, almost half was located in the top 100 mm of the profile. No copper or arsenic was detected in any of the lysimeter leachates, with soil analysis indicating that these elements had been retained within the soil profile. In an incubation study, soil cores sampled from the same Templeton sandy loam and split into alternate 50-mm segments (to 450 mm) were stored at 10˚C for 102 days after addition of an identical CCA solution. These were periodically extracted for available chromium. Results showed that the reduction of dichromate/chromate anions (Cr2O72–/CrO42–) to the strongly sorbed chromic cation (Cr3+) was largely first-order and greatest in surface layers where soil organic matter contents were largest. After 102 days, <1% of the added Cr(VI) was still extractable in the 0–50 mm soil cores whilst ≈60% of Cr(VI) in the 400–450 mm cores (or deeper) was still extractable after the same period. A linear systems model comprising a series of conceptual mixing cells was used to describe the individual and mean Cr(VI) leaching breakthrough curves (BTCs). This State-Space Mixing Cell model proved effective in simulating the Cr(VI) leaching using first-order kinetics to quantify rate-limited local solute adsorption coupled to advective-dispersive transport. The solute mass involved in the model process was ≈30%. The bulk of the remaining 70% of applied dichromate was assumed to have undergone reduction to the non-mobile chromium cation. This study shows that there exists a significant potential for Cr(VI) to be a serious threat to groundwater in the event of a large uncontained spillage of a concentrated CCA solution. This potential can be significantly lessened if the Cr(VI) is reduced after retention in an organic matter rich layer.

KARAKTERISTIK TANAH DAN PERBANDINGAN PRODUKSI KELAPA SAWIT (Elaeis guineensis Jacq.) DENGAN METODE TANAM LUBANG BESAR DAN PARIT DRAINASE 2:1 PADA LAHAN SPODOSOL DI KABUPATEN BARITO TIMUR PROPINSI KALIMANTAN TENGAH - INDONESIA

2015 ◽  
Vol 2 (2) ◽  
pp. 148-158
Author(s):  
Surianto
Keyword(s):  
Soil Texture ◽  
Oil Palm ◽  
Soil Profile ◽  
Chemical Properties ◽  
Exchangeable Cations ◽  
Soil Horizon ◽  
Soil Profiles ◽  
Negative Effect ◽  
Hole Profile ◽  
And Chemical Properties

Spodosol soil of Typic Placorthod sub-group of East Barito District is one of the problem soils with the presence of hardpan layer, low fertility, low water holding capacity, acid reaction and it is not suitable for oil palm cultivation without any properly specific management of land preparation and implemented best agronomic practices. A study was carried out to evaluate the soil characteristic of a big hole (A profile) and no big hole (B profile) system and comparative oil palm productivity among two planting systems. This study was conducted in Spodosol soil at oil palm plantation (coordinate X = 0281843 and Y = 9764116), East Barito District, Central Kalimantan Province on February 2014, by surveying of placic and ortstein depth and observing soil texture and chemical properties of 2 (two) oil palm's soil profiles that have been planted in five years. Big hole system of commercial oil palm field planting on the Spodosol soil area was designed for the specific purpose of minimizing the potential of a negative effect of shallow effective planting depth for oil palms growing due to the hardpan layer (placic and ortstein) presence as deep as 0.25 - 0.50 m. The big hole system is a planting hole type which was vertical-sided with 2.00 m x 1.50 m on top and bottom side and 3.00 m depth meanwhile the 2:1 drain was vertical-sided also with 1.50 m depth and 300 m length. Oil palm production was recorded from the year 2012 up to 2014. Results indicated that the fractions both big hole profile (A profile) and no big hole profile (B profile) were dominated by sands ranged from 60% to 92% and the highest sands content of non-big hole soil profile were found in A and E horizons (92%). Better distribution of sand and clay fractions content in between layers of big hole soil profiles of A profile sample is more uniform compared to the B profile sample. The mechanical holing and material mixing of soil materials of A soil profile among the upper and lower horizons i.e. A, E, B and C horizons before planting that resulted a better distribution of both soil texture (sands and clay) and chemical properties such as acidity value (pH), C-organic, N, C/N ratio, CEC, P-available and Exchangeable Bases. Investigation showed that exchangeable cations (Ca, Mg, K), were very low in soil layers (A profile) and horizons (B profile) investigated. The low exchangeable cations due to highly leached of bases to the lower layers and horizons. Besides, the palm which was planted on the big hole system showed good adaptation and response positively by growing well of tertiary and quaternary roots that the roots were penetrable into deeper rooting zone as much as >1.00 m depth. The roots can grow well and penetrate much deeper in A profile compared to the undisturbed hardpan layer (B profile). The FFB (fresh fruit bunches) production of the non-big hole block was higher than the big hole block for the first three years of production. This might be due to the high variation of monthly rainfall in-between years of observation from 2009 to 2014. Therefore, the hardness of placic and ortstein as unpenetrable agents by roots and water to prevent water loss and retain the water in the rhizosphere especially in the drier weather. In the high rainfall condition, the 2:1 drain to prevent water saturation in the oil palm rhizosphere by moving some water into the drain. Meanwhile, the disturbed soil horizon (big hole area) was drier than un disturbance immediately due to water removal to deeper layers. We concluded that both big hole and 2:1 drain are a suitable technology for Spodosol soil land especially in preparing palms planting to minimize the negative effect of the hardpan layer for oil palm growth.

SOLUTION OF THE RICHARDS EQUATION IN A SOIL PROFILE WITH TWO LAYERS USING THE METHOD OF LINES

2020 ◽  
Author(s):  
Diego Sousa Lopes ◽  
Augusto Cezar Cordeiro Jardim ◽  
Diego Estumano ◽  
Emanuel Macêdo ◽  
João Quaresma
Keyword(s):  
Soil Profile ◽  
Method Of Lines ◽  
Richards Equation ◽  
The Method Of Lines

scholarly journals Digital mapping of a soil profile

2018 ◽  
Vol 70 (1) ◽  
pp. 27-41 ◽  
Author(s):  
Y. Zhang ◽  
A. E. Hartemink
Keyword(s):  
Soil Profile ◽  
Digital Mapping

Caesium-137 and strontium-90 distribution in a soil profile

1993 ◽  
Vol 136 (3) ◽  
pp. 251-258 ◽  
Author(s):  
P CHAMARD ◽  
R VELASCO ◽  
M BELLI ◽  
G DISILVESTRO ◽  
G INGRAO ◽  
...  
Keyword(s):  
Soil Profile ◽  
Strontium 90

scholarly journals Implementation of Machine Learning Algorithms in Spectral Analysis of Surface Waves (SASW) Inversion

2021 ◽  
Vol 11 (6) ◽  
pp. 2557
Author(s):  
Sadia Mannan Mitu ◽  
Norinah Abd. Rahman ◽  
Khairul Anuar Mohd Nayan ◽  
Mohd Asyraf Zulkifley ◽  
Sri Atmaja P. Rosyidi
Keyword(s):  
Spectral Analysis ◽  
Surface Waves ◽  
Soil Profile ◽  
Field Tests ◽  
Iteration Process ◽  
Machine Learning Algorithms ◽  
Support Vector ◽  
Complex Processes ◽  
Inversion Procedure ◽  
Inversion Analysis

One of the complex processes in spectral analysis of surface waves (SASW) data analysis is the inversion procedure. An initial soil profile needs to be assumed at the beginning of the inversion analysis, which involves calculating the theoretical dispersion curve. If the assumption of the starting soil profile model is not reasonably close, the iteration process might lead to nonconvergence or take too long to be converged. Automating the inversion procedure will allow us to evaluate the soil stiffness properties conveniently and rapidly by means of the SASW method. Multilayer perceptron (MLP), random forest (RF), support vector regression (SVR), and linear regression (LR) algorithms were implemented in order to automate the inversion. For this purpose, the dispersion curves obtained from 50 field tests were used as input data for all of the algorithms. The results illustrated that SVR algorithms could potentially be used to estimate the shear wave velocity of soil.

scholarly journals Investigating the Impact of Root-Lesion Nematodes (Pratylenchus thornei) and Crown Rot (Fusarium pseudograminearum) on Diverse Cereal Cultivars in a Conservation Farming System

Agronomy ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 867
Author(s):  
John P. Thompson ◽  
Timothy G. Clewett
Keyword(s):  
Grain Yield ◽  
Soil Profile ◽  
Crown Rot ◽  
Tolerance Index ◽  
Initial Population ◽  
Fusarium Pseudograminearum ◽  
Conservation Farming ◽  
Pratylenchus Thornei ◽  
Fourth Experiment ◽  
The Impact

In two experiments on a farm practicing conservation agriculture, the grain yield of a range of wheat cultivars was significantly (p < 0.001) negatively related to the post-harvest population densities of Pratylenchus thornei in the soil profile to 45 cm depth. In a third and fourth experiment with different rotations, methyl bromide fumigation significantly (p < 0.05) decreased (a) a low initial population density of P. thornei in the soil profile to 90 cm depth and (b) a high initial population of P. thornei to 45 cm depth, and a medium level of the crown rot fungus, Fusarium pseudograminearum, at 0–15 cm depth to a low level. For a range of wheat and durum cultivars, grain yield and response to fumigation were highly significantly (p < 0.001) related to (a) the P. thornei tolerance index of the cultivars in the third experiment, and (b) to both the P. thornei tolerance index and the crown rot resistance index in the fourth experiment. In the latter, grain yield was significantly (p < 0.001) positively related to biomass at anthesis and negatively related to percentage whiteheads at grain fill growth stage. One barley cultivar was more tolerant to both diseases than the wheat and durum cultivars. Crop rotation, utilizing crop cultivars resistant and tolerant to both P. thornei and F. pseudograminearum, is key to success for conservation farming in this region.

scholarly journals Source and Health Risk Assessment of Heavy Metals in Soil–Ginger System in the Jing River Basin of Shandong Province, North China

2021 ◽  
Vol 18 (13) ◽  
pp. 6749
Author(s):  
Songtao Wang ◽  
Zongjun Gao ◽  
Yuqi Zhang ◽  
Hairui Zhang ◽  
Zhen Wu ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
River Basin ◽  
Soil Profile ◽  
Pollution Index ◽  
Potential Ecological Risk ◽  
Average Concentration ◽  
Anthropogenic Factors ◽  
Multivariate Statistical ◽  
Cr Content

This study investigated the characteristics and sources of heavy metals in a soil–ginger system and assessed their health risks. To this end, 321 topsoil samples and eight soil samples from a soil profile, and 18 ginger samples with root–soil were collected from a ginger-planting area in the Jing River Basin. The average concentration of heavy metals in the topsoil followed the order: Cr > Zn > Pb > Ni > Cu > As > Cd > Hg. In the soil profile, at depths greater than 80 cm, the contents of Cr, Ni, and Zn tended to increase with depth, which may be related to the parent materials, whereas As and Cu contents showed little change. In contrast, Pb content decreased sharply from top to bottom, which may be attributable to external environmental and anthropogenic factors. Multivariate statistical analysis showed that Cr, Ni, Cu, Zn, and Cd contents in soil are affected by natural sources, Pb and As contents are significantly affected by human activities, and Hg content is affected by farmland irrigation. Combined results of the single pollution index (Pi), geo-accumulation index (Igeo), and potential ecological risk assessment (Ei and RI) suggest that soil in the study area is generally not polluted by heavy metals. In ginger, Zn content was the highest (2.36 mg/kg) and Hg content was the lowest (0.0015 mg/kg). Based on the bioconcentration factor, Cd and Zn have high potential for enrichment in ginger. With reference to the limit of heavy metals in tubers, Cr content in ginger exceeds the standard in the study area. Although Cr does not accumulate in ginger, Cr enrichment in soil significantly increases the risk of excessive Cr content in ginger.

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