Chromium(VI) leaching from large undisturbed soil lysimeters following application of a simulated copper-chromium-arsenic (CCA) timber preservative

Soil Research ◽  
2002 ◽  
Vol 40 (2) ◽  
pp. 351 ◽  
Author(s):  
P. L. Carey ◽  
V. J. Bidwell ◽  
R. G. McLaren
Keyword(s):  
Organic Matter ◽  
Soil Profile ◽  
Sandy Loam ◽  
Soil Analysis ◽  
Rainfall Simulation ◽  
Soil Cores ◽  
Undisturbed Soil ◽  
First Order ◽  
Copper Chromium ◽  
Soil Lysimeters

Copper, chromium, and arsenic (CCA) solutions are commonly used in New Zealand as a means of preserving softwood timbers such as Pinus radiata. With stock working solutions of CCA salts in timber treatment plants frequently 10% w/v or more, there exists a potential for spillage and leaching of these compounds to groundwater. High concentrations of Cr(VI) (up to 52 mg Cr/L) were found in the leachates of large undisturbed soil lysimeters where a Templeton sandy loam (Immature Pallic) had received surface applications of a simulated copper, chromium, and arsenic (CCA) timber preservative. Leaching was produced by using a combination of natural and imposed rainfall simulation over the lysimeters for a period of 102 days after CCA application. An average of 26% of the applied chromium was collected in the leachates after 102 days. Of the mean 74% of Cr(VI) still retained within the soil profile after leaching ended, almost half was located in the top 100 mm of the profile. No copper or arsenic was detected in any of the lysimeter leachates, with soil analysis indicating that these elements had been retained within the soil profile. In an incubation study, soil cores sampled from the same Templeton sandy loam and split into alternate 50-mm segments (to 450 mm) were stored at 10˚C for 102 days after addition of an identical CCA solution. These were periodically extracted for available chromium. Results showed that the reduction of dichromate/chromate anions (Cr2O72–/CrO42–) to the strongly sorbed chromic cation (Cr3+) was largely first-order and greatest in surface layers where soil organic matter contents were largest. After 102 days, <1% of the added Cr(VI) was still extractable in the 0–50 mm soil cores whilst ≈60% of Cr(VI) in the 400–450 mm cores (or deeper) was still extractable after the same period. A linear systems model comprising a series of conceptual mixing cells was used to describe the individual and mean Cr(VI) leaching breakthrough curves (BTCs). This State-Space Mixing Cell model proved effective in simulating the Cr(VI) leaching using first-order kinetics to quantify rate-limited local solute adsorption coupled to advective-dispersive transport. The solute mass involved in the model process was ≈30%. The bulk of the remaining 70% of applied dichromate was assumed to have undergone reduction to the non-mobile chromium cation. This study shows that there exists a significant potential for Cr(VI) to be a serious threat to groundwater in the event of a large uncontained spillage of a concentrated CCA solution. This potential can be significantly lessened if the Cr(VI) is reduced after retention in an organic matter rich layer.

Corrigendum to: Chromium(IV) leaching from large undisturbed soil lysimeters following application of a simulated copper-chromium-arsenic (CCA) timber preservative

Soil Research ◽  
2002 ◽  
Vol 40 (4) ◽  
pp. 715 ◽  
Author(s):  
P. L. Carey ◽  
V. D. Bidwell ◽  
R. G. McLaren
Keyword(s):  
Organic Matter ◽  
Soil Profile ◽  
Sandy Loam ◽  
Soil Analysis ◽  
Rainfall Simulation ◽  
Soil Cores ◽  
Undisturbed Soil ◽  
First Order ◽  
Copper Chromium ◽  
Soil Lysimeters

Copper, chromium, and arsenic (CCA) solutions are commonly used in New Zealand as a means of preserving softwood timbers such as Pinus radiata. With stock working solutions of CCA salts in timber treatment plants frequently 10% w/v or more, there exists a potential for spillage and leaching of these compounds to groundwater. High concentrations of Cr(VI) (up to 52 mg Cr/L) were found in the leachates of large undisturbed soil lysimeters where a Templeton sandy loam (Immature Pallic) had received surface applications of a simulated copper, chromium, and arsenic (CCA) timber preservative. Leaching was produced by using a combination of natural and imposed rainfall simulation over the lysimeters for a period of 102 days after CCA application. An average of 26% of the applied chromium was collected in the leachates after 102 days. Of the mean 74% of Cr(VI) still retained within the soil profile after leaching ended, almost half was located in the top 100 mm of the profile. No copper or arsenic was detected in any of the lysimeter leachates, with soil analysis indicating that these elements had been retained within the soil profile. In an incubation study, soil cores sampled from the same Templeton sandy loam and split into alternate 50-mm segments (to 450 mm) were stored at 10˚C for 102 days after addition of an identical CCA solution. These were periodically extracted for available chromium. Results showed that the reduction of dichromate/chromate anions (Cr2O72–/CrO42–) to the strongly sorbed chromic cation (Cr3+) was largely first-order and greatest in surface layers where soil organic matter contents were largest. After 102 days, <1% of the added Cr(VI) was still extractable in the 0–50 mm soil cores whilst ≈60% of Cr(VI) in the 400–450 mm cores (or deeper) was still extractable after the same period. A linear systems model comprising a series of conceptual mixing cells was used to describe the individual and mean Cr(VI) leaching breakthrough curves (BTCs). This State-Space Mixing Cell model proved effective in simulating the Cr(VI) leaching using first-order kinetics to quantify rate-limited local solute adsorption coupled to advective-dispersive transport. The solute mass involved in the model process was ≈30%. The bulk of the remaining 70% of applied dichromate was assumed to have undergone reduction to the non-mobile chromium cation. This study shows that there exists a significant potential for Cr(VI) to be a serious threat to groundwater in the event of a large uncontained spillage of a concentrated CCA solution. This potential can be significantly lessened if the Cr(VI) is reduced after retention in an organic matter rich layer.

Carbon mineralisation and pore size classes in undisturbed soil cores

Soil Research ◽  
2013 ◽  
Vol 51 (1) ◽  
pp. 14 ◽  
Author(s):  
Liesbeth Bouckaert ◽  
Steven Sleutel ◽  
Denis Van Loo ◽  
Loes Brabant ◽  
Veerle Cnudde ◽  
...  
Keyword(s):  
Organic Matter ◽  
Pore Network ◽  
Order Kinetic ◽  
Soil Cores ◽  
Undisturbed Soil ◽  
Soil Matrix ◽  
X Ray ◽  
C Mineralisation ◽  
The Impact ◽  
Undisturbed Soil Cores

Soil pore network effects on organic matter turnover have, until now, been studied indirectly because of lack of data on the 3D structure of the pore network. Application of X-ray computed tomography (X-ray CT) to quantify the distribution of pore neck size and related pore sizes from undisturbed soil cores, with simultaneous assessment of carbon (C) mineralisation, could establish a relationship between soil organic matter (SOM) decomposition and soil pore volumes. Eighteen miniature soil cores (diameter 1.2 cm, height 1.2 cm) covering a range of bulk densities were incubated at 20°C for 35 days. Respiration was modelled with a parallel first- and zero-order kinetic model. The cores were scanned at 9.44 µm resolution using an X-ray CT scanner developed in-house. Correlation analysis between the slow pool C mineralisation rate, ks, and pore volume per pore neck class yielded significant (P < 0.05) positive correlations: r = 0.572, 0.598, and 0.516 for the 150–250, 250–350, and >350 µm pore neck classes, respectively. Because larger pores are most probably mainly air-filled, a positive relation with ks was ascribed to enhanced aeration of smaller pores surrounding large pores. The weak and insignificant relationship between the smallest pore neck class (<9.44 µm) and ks could be explained by obstructed microbial activity and mobility or diffusion of exo-enzymes and hydrolysis products as a result of limited oxygen availability. This study supports the hypothesis that the impact of soil structure on microbial processes occurs primarily via its determination of soil water distribution, which is possibly the main driver for the location of C mineralisation in the soil matrix.

scholarly journals Hyperspectral imaging for high-resolution mapping of soil profile organic carbon distribution in an Austrian Alpine landscape

2020 ◽  
Author(s):  
Yaser Ostovari ◽  
Baptist Köppendörfer ◽  
Julien Guigue ◽  
Jan Willem Van Groenigen ◽  
Rachel Creamer ◽  
...  
Keyword(s):  
Machine Learning ◽  
Organic Carbon ◽  
Hyperspectral Imaging ◽  
Soil Profile ◽  
Partial Least Square ◽  
Learning Approaches ◽  
Soil Cores ◽  
Undisturbed Soil ◽  
Undisturbed Soil Cores ◽  
Soc Stocks

&lt;p&gt;Studies on soil organic carbon (SOC) stocks mostly focus on topsoils (&lt; 30 cm). However, 30 to 63% of the SOC are stored in the subsoils (30 to 100 cm), and the factors controlling SOC storage in subsoils may be substantially different than in topsoils. The low mean SOC content in subsoils makes its quantification and characterization challenging. Thus, new approaches are required to depict the SOC stocks distribution in full soil profile. Hyperspectral imaging of soil core samples can provide high spatial resolution of the vertical distribution of SOC in a soil profile. The main objective of the ongoing study, within the Horizon 2020 European Project Circular Agronomics, is to apply laboratory hyperspectral imaging with a variety of machine learning approaches for the mapping of OC distribution in undisturbed soil cores. Soil cores were collected down to a depth of one meter in grasslands of 15 organic farms located in the Lungau Valley, in Austria. Some samples were divided into five depths in the field for classical bulk soil measurements (total carbon and nitrogen, texture, pH, EC and bulk density) on disturbed samples. Undisturbed soil cores were sliced vertically for laboratory hyperspectral imaging in the range of Vis-NIR (400-1000 nm). We were able to reveal the hotspots of OC and map the OC distribution in soil profile by applying a variety of machine learning approaches (i.e. partial least square and random forest regression) as a function of spectral responses. A digital elevation model was further exploited to investigate the effects of topographical factors such as elevation, aspect and slope on SOC profile distribution. Landsat 8 data were also used to depict the spatial variability of land insensitive cover/vegetation in study area.&lt;/p&gt;

Influence of dicyandiamide on nitrogen transformation and losses in cow-urine-amended soil cores from grazed pasture

2009 ◽  
Vol 49 (3) ◽  
pp. 253 ◽  
Author(s):  
Jagrati Singh ◽  
S. Saggar ◽  
N. S. Bolan
Keyword(s):  
Sandy Loam ◽  
Field Capacity ◽  
N Leaching ◽  
N2o Emissions ◽  
Gaseous Emissions ◽  
Soil Cores ◽  
N Losses ◽  
Mineral N ◽  
Undisturbed Soil ◽  
N Transformations

In New Zealand, urine deposited by grazing animals represents the largest source of nitrogen (N) losses, as gaseous emissions of ammonia (NH3) and nitrous oxide (N2O), and leaching of nitrate (NO3−).We determined the effect of dicyandiamide (DCD) on gaseous emissions from pasture with increasing rates of urine-N application, mineral N transformations and potential leaching of N using undisturbed soil cores of Manawatu sandy loam at field capacity. The treatments included four levels of urine-N applied at 0 (control), 14.4, 29.0 and 57.0 g N/m2 with and without DCD at 2.5 g/m2. Results showed a significant (P < 0.05) increase in NH3 and N2O-N emissions as urine application was increased. The addition of DCD to corresponding urine treatments reduced N2O emissions by 33, 56 and 80%, respectively. The addition of DCD with urine to the intact soil cores at field capacity moisture content resulted in a significant increase in the soil ammonium-N (NH4+-N) concentration but little change in NH3 emissions. Addition of DCD to urine reduced potential NO3−-N leaching by 60–65% but potential NH4+-N leaching increased by 2–3.5 times. There was no difference in pasture dry matter production with and without DCD treatments.

scholarly journals Physical-hydraulic properties of a sandy loam typic paleudalf soil under organic cultivation of 'montenegrina' mandarin (Citrus deliciosa Tenore)¹

2014 ◽  
Vol 38 (6) ◽  
pp. 1882-1889
Author(s):  
Caroline Valverde dos Santos ◽  
Renato Levien ◽  
Sérgio Francisco Schwarz ◽  
Michael Mazurana ◽  
Henrique Belmonte Petry ◽  
...  
Keyword(s):  
Physical Properties ◽  
Hydraulic Properties ◽  
Sandy Loam ◽  
Soil Analysis ◽  
Sampling Site ◽  
Soil Physical Properties ◽  
Water Infiltration ◽  
Undisturbed Soil ◽  
Organic Cultivation ◽  
Citrus Deliciosa

Citrus plants are the most important fruit species in the world, with emphasis to oranges, mandarins and lemons. In Rio Grande do Sul, Brazil, most fruit production is found on small properties under organic cultivation. Soil compaction is one of the factors limiting production and due to the fixed row placement of this crop, compaction can arise in various manners in the interrows of the orchard. The aim of this study was to evaluate soil physical properties and water infiltration capacity in response to interrow management in an orchard of mandarin (Citrus deliciosa Tenore 'Montenegrina') under organic cultivation. Interrow management was performed through harrowing, logs in em "V", mowing, and cutting/knocking down plants with a knife roller. Soil physical properties were evaluated in the wheel tracks of the tractor (WT), between the wheel tracks (BWT), and in the area under the line projection of the canopy (CLP), with undisturbed soil samples collected in the 0.00-0.15, 0.15-0.30, 0.30-0.45, and 0.45-0.60 m layers, with four replicates. The soil water infiltration test was performed using the concentric cylinder method, with a maximum time of 90 min for each test. In general, soil analysis showed a variation in the physical-hydraulic properties of the Argissolo Vermelho-Amarelo distrófico arênico (sandy loam Typic Paleudalf) in the three sampling sites in all layers, regardless of the management procedure in the interrows. Machinery traffic leads to heterogeneity in the soil physical-hydraulic properties in the interrows of the orchard. Soil porosity and bulk density are affected especially in the wheel tracks of the tractor (WT), which causes a reduction in the constant rate of infiltration and in the accumulated infiltration of water in this sampling site. The use of the disk harrow and mower leads to greater harmful effects on the soil, which can interfere with mandarin production.

Isoproturon movement and dissipation in undisturbed soil cores from a grassed buffer strip

Agronomie ◽  
2000 ◽  
Vol 20 (3) ◽  
pp. 297-307 ◽  
Author(s):  
Pierre Benoit ◽  
Enrique Barriuso ◽  
Philippe Vidon ◽  
Benoit Réal
Keyword(s):  
Soil Cores ◽  
Undisturbed Soil ◽  
Buffer Strip ◽  
Undisturbed Soil Cores

scholarly journals Influence of Physicochemical Characteristics of Bean Crop Soil in Trichoderma spp. Development

Agronomy ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 274
Author(s):  
Sara Mayo-Prieto ◽  
Alejandra J. Porteous-Álvarez ◽  
Sergio Mezquita-García ◽  
Álvaro Rodríguez-González ◽  
Guzmán Carro-Huerga ◽  
...  
Keyword(s):  
Organic Matter ◽  
Sandy Loam ◽  
C:N Ratio ◽  
Physicochemical Characteristics ◽  
Soil Parameters ◽  
Physical Parameters ◽  
Silt Loam ◽  
Chemical Methods ◽  
Trichoderma Spp ◽  
Trichoderma Species

Spain has ranked 6th on the harvested bean area and 8th in bean production in the European Union (EU). The soils of this area have mixed silt loam and sandy loam texture, with moderate clay content, neutral or acidic pH, rich in organic matter and low carbonate levels, providing beans with high water absorption capacity and better organoleptic qualities after cooking. Similar to other crops, it is attacked by some phytopathogens. Hitherto, chemical methods have been used to control these organisms. However, with the Reform of the Community Agrarian Policy in the EU, the number of authorized plant protection products has been reduced to prevail food security, as well as to be sustainable in the long term, giving priority to the non-chemical methods that use biological agents, such as Trichoderma. This study aimed to investigate the relative importance of various crop soil parameters in the adaptation of Trichoderma spp. autoclaved soils (AS) and natural soils (NS) from the Protected Geographical Indication (PGI) “Alubia La Bañeza—León” that were inoculated with Trichoderma velutinum T029 and T. harzianum T059 and incubated in a culture chamber at 25 °C for 15 days. Their development was determined by quantitative PCR. Twelve soil samples were selected and analyzed from the productive zones of Astorga, La Bañeza, La Cabrera, Esla-Campos and Páramo. Their physicochemical characteristics were different by zone, as the texture of soils ranged between sandy loam and silt loam and the pH between strongly acid and slightly alkaline, as well as the organic matter (OM) concentration between low and remarkably high. Total C and N concentrations and their ratio were between medium and high in most of the soils and the rest of the micronutrients had an acceptable concentration except for Paramo’s soil. Both Trichoderma species developed better in AS than in NS, T. velutinum T029 grew better with high levels of OM, total C, ratio C:N, P, K, Fe, and Zn than T. harzianum T059 in clay soils, with the highest values of cation exchange capacity (CEC), pH, Ca, Mg and Mn. These effects were validated by Canonical Correlation Analysis (CCA), texture, particularly clay concentration, OM, electrical conductivity (EC), and pH (physical parameters) and B and Cu (soil elements) are the main factors explaining the influence in the Trichoderma development. OM, EC, C:N ratio and Cu are the main soil characteristics that influence in T. velutinum T029 development and pH in the development of T. harzianum T059.

scholarly journals Chemical and Phytocoenological Characteristics of Two Different Slovak Peatlands

Plants ◽  
2021 ◽  
Vol 10 (7) ◽  
pp. 1290
Author(s):  
Danica Fazekašová ◽  
Gabriela Barančíková ◽  
Juraj Fazekaš ◽  
Lenka Štofejová ◽  
Ján Halas ◽  
...  
Keyword(s):  
Organic Matter ◽  
Soil Profile ◽  
Agricultural Land ◽  
Nitrogen Supply ◽  
Point Of View ◽  
Statistical Testing ◽  
Plant Residues ◽  
Soil Reaction ◽  
Chemical Parameters

This paper presents the results of pedological and phytocoenological research focused on the detailed research of chemical parameters (pH, organic carbon, and nutrients), risk elements (As-metalloid, Cd, Co, Cr, Cu, Ni, Pb, and Zn), and species composition of the vegetation of two different peatlands on the territory of Slovakia—Belianske Lúky (a fen) and Rudné (a bog). Sampling points were selected to characterize the profile of the organosol within the peatland, the soil profile between the peatland and the agricultural land, and the soil profile of the outlying agricultural land, which is used as permanent grassland. Based on phytocoenological records, a semi-quantitative analysis of taxa in accordance with the Braun–Blanquet scale was performed. The study revealed that the thickness of the peat horizon of the fen in comparison with the bog is very low. In terms of the quality of organic matter, the monitored peatlands are dominated by fresh plant residues such as cellulose and lignin. Differences between individual types of peatlands were also found in the soil reaction and the supply of nitrogen to the organic matter of peat. The values of the soil exchange reaction were neutral on the fen, as well as slightly alkaline but extremely low on the bog. A significantly higher nitrogen supply was found in the organic matter of the fen in contrast to the bog. At the same time, extremely low content of accessible P and an above-limit content of As in the surface horizons were also found on the fen. From the phytocoenological point of view, 22 plant species were identified on the fen, while only five species were identified on the bog, which also affected the higher diversity (H’) and equitability (e). The results of the statistical testing confirmed the diversity of the studied peatlands and the different impact of environmental variables on plant diversity.

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