Abstract. During rain events, herbicides can be transported from their point of application to surface waters where they may harm aquatic organisms. Since the spatial pattern of mobilisation and transport is heterogeneous, the contributions of different fields to the herbicide load in the stream may differ considerably within one catchment. Therefore, the prediction of contributing areas could help to target mitigation measures efficiently to those locations where they reduce herbicide pollution the most. Such spatial predictions require sufficient insight into the underlying transport processes. To improve the understanding of the process chain of herbicide mobilisation on the field and the subsequent transport through the catchment to the stream, we performed a controlled herbicide application on corn fields in a small agricultural catchment (ca. 1 km2) with intensive crop production in the Swiss Plateau. For two months after application in 2009, water samples were taken at different locations in the catchment (overland flow, tile drains and open channel) with a high temporal resolution during rain events. We also analysed soil samples from the experimental fields and measured discharge, groundwater level, soil moisture and the occurrence of overland flow at several locations. Several rain events with varying intensities and magnitudes occurred during the study period. Overland flow and erosion were frequently observed in the entire catchment. Infiltration excess and saturation excess overland flow were both observed. However, the main herbicide loss event was dominated by infiltration excess. This is in contrast to earlier studies in the Swiss Plateau, demonstrating that saturation excess overland flow was the dominant process. Despite the frequent and wide-spread occurrence of overland flow, most of this water did not directly reach the channel. It mostly got retained in small sinks in the catchment. From there, it reached the stream via macropores and tile drains. Manholes of the drainage system and catch basins for road and farmyard runoff acted as additional shortcuts to the stream. Although fast flow processes like overland and macropore flow reduce the influence of herbicide properties due to short travel times, sorption properties influenced the herbicide transfer from ponding overland flow to tile drains (macropore flow). However, no influence of sorption was observed during the mobilisation of the herbicides from soil to overland flow. These two observations on the role of herbicide properties contradict, to some degrees, previous findings. They demonstrate that valuable insight can be gained by spatially detailed observations along the flow paths.
Saturation excess overland flow accelerates the spread of a generalist soil-borne pathogen
