Analysis of process of emulsions transport in hydrophilic/oleophilic granular porous media driven by capillary force

2018 ◽  
Vol 2 (21) ◽  
pp. 85-101
Author(s):  
Olga Shtyka ◽  
Łukasz Przybysz ◽  
Mariola Błaszczyk ◽  
Jerzy P. Sęk

The research focuses on the issues concerning a process of multiphase liquids transport in granular porous media driven by the capillary pressure. The current publication is meant to introduce the results of experimental research conducted to evaluate the kinetics of the imbibition and emulsions behavior inside the porous structures. Moreover, the influence of the dispersed phase concentration and granular media structure on the mentioned process was considered. The medium imbibition with emulsifier-stabilized emulsions composed of oil as the dispersed phase in concentrations of 10 vol%, 30 vol%, and 50 vol%, was investigated. The porous media consisted of oleophilic/hydrophilic beads with a fraction of 200–300 and 600–800 μm. The experimental results provided that the emulsions imbibition in such media depended stronger on its structure compare to single-phase liquids. The increase of the dispersed phase concentration caused an insignificant mass decreasing of the imbibed emulsions and height of its penetration in a sorptive medium. The concentrations of the imbibed dispersions exceeded their initial values, but reduced with permeants front raise in the granular structures that can be defined as the influential factor for wicking process kinetics.

Author(s):  
Wojciech Sobieski

AbstractThe paper describes the so-called Waterfall Algorithm, which may be used to calculate a set of parameters characterising the spatial structure of granular porous media, such as shift ratio, collision density ratio, consolidation ratio, path length and minimum tortuosity. The study is performed for 1800 different two-dimensional random pore structures. In each geometry, 100 individual paths are calculated. The impact of porosity and the particle size on the above-mentioned parameters is investigated. It was stated in the paper, that the minimum tortuosity calculated by the Waterfall Algorithm cannot be used directly as a representative tortuosity of pore channels in the Kozeny or the Carman meaning. However, it may be used indirect by making the assumption that a unambiguous relationship between the representative tortuosity and the minimum tortuosity exists. It was also stated, that the new parameters defined in the present study are sensitive on the porosity and the particle size and may be therefore applied as indicators of the geometry structure of granular media. The Waterfall Algorithm is compared with other methods of determining the tortuosity: A-Star Algorithm, Path Searching Algorithm, Random Walk technique, Path Tracking Method and the methodology of calculating the hydraulic tortuosity based on the Lattice Boltzmann Method. A very short calculation time is the main advantage of the Waterfall Algorithm, what meant, that it may be applied in a very large granular porous media.


2012 ◽  
Vol 2012 ◽  
pp. 1-10
Author(s):  
Aliaksandr Alevanau ◽  
Pawel Donaj ◽  
Weihong Yang ◽  
Wlodzimierz Blasiak

Experimental research on the pyrolysis and gasification of randomly packed straw pellets was conducted with an emphasis on the reactive properties of the shrinking porous structure of the pellets. The apparent kinetics of such pyrolysis was approximated by the random pore, grain, and volumetric models. The best approximation results were obtained with the grain and random pore models. The self-organized oscillations of the pellet conversion rate during pyrolysis were observed. Two complementary explanations of the phenomenon are proposed.


2010 ◽  
Vol 112 (1-4) ◽  
pp. 91-102 ◽  
Author(s):  
A. Massoudieh ◽  
C. Crain ◽  
E. Lambertini ◽  
K.E. Nelson ◽  
T. Barkouki ◽  
...  

1971 ◽  
Vol 11 (04) ◽  
pp. 363-366
Author(s):  
Candelario Perez-Rosales ◽  
Juan J. Martinez

Abstract A statistical method, based upon the surface analysis of samples, is presented for determining simultaneously the following structural characteristics of granular porous media: porosity, mean pore width, mean grain thickness, specific surface, true sphericity of grains, number of grains per unit volume, and surface area of individual grains. per unit volume, and surface area of individual grains. Since a two-dimensional analysis is used as a means for obtaining information about three-dimensional systems, the applicability of the proposed method is restricted to homogeneous and isotropic media. Introduction The study of the geometrical properties of granular porous media is of importance in a variety of scientific and technological disciplines, such as fluid mechanics, soil mechanics, sedimentology, stratigraphy and petrophysics. The literature available in this field reveals that relatively little is known about the actual internal structure of granular media with a random distribution of irregular grains. When a quantitative description of the structural characteristics of these systems is required, it has become a practice to postulate idealized geometric models as representative of the real media. Thus, models consisting of packings of spheres and spheroids have been used for studying fluid flow and capillary behavior in granular media, such as soils and natural sands. Similar systems have been employed as models for filter cakes and beds of catalyst pellets. Likewise, cylindrical and parallel-plate pore models have been postulated for studying pore structure of real media. These simplified models, however, usually have the disadvantage of giving only approximate results; and sometimes large discrepancies between theory and observation are obtained. In view of the difficulty of giving a proper geometrical characterization of granular porous media by standard procedures, it is concluded that new methods of procedures, it is concluded that new methods of analysis leading to a better understanding of the anatomy of porous materials are needed. Accordingly, a method which allows a detailed structural description of granular porous media is presented in this paper. The guiding idea in the presented in this paper. The guiding idea in the development of the method has been the belief that a proper analysis of the surface of a homogeneous and isotropic porous material must provide all the basic information to characterize adequately the internal structure of the medium. The results obtained to date have shown that, if a cross-section of a granular porous sample is analyzed by means of a square grid, it is possible to determine in a simple and accurate way the following structural characteristics: porosity, mean pore width, mean grain thickness, specific surface, true sphericity of grains, number of grains per unit volume, and surface area of individual grains. To improve the consistency between the mathematical symbols and their meaning, the nomenclature employed in this paper is somewhat different from that used in the related previous papers. papers. IMPORTANT RELATIONSHIPS In addition to porosity, one of the most important geometrical characteristics of a porous sample is the specific surface. In the strict sense, there are two basic types of specific surface for a granular porous material: pore specific surface, Ssp, and porous material: pore specific surface, Ssp, and grain specific surface, Ssg. The former is defined as the surface area of the pore walls, Sp, per unit bulk volume, Vt, namely, and the latter is defined as the surface area of grains Sg also per unit bulk volume; that is If the contacts between grains were mathematical points, the two types of specific surface would have points, the two types of specific surface would have the same value. However, for a real granular medium, the contacts always have associated a given surface area, and hence these parameters are necessarily different. SPEJ P. 363


2021 ◽  
Author(s):  
Jimmy Xuekai Li ◽  
Reza Rezaee ◽  
Tobias M. Müller ◽  
Mahyar Madadi ◽  
Rupeng Ma ◽  
...  

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