Morphologic, chemical, and spectral analyses of combustion products of micro- and nano-dispersed particles of aluminium borides

2019 ◽  
Vol 484 (1) ◽  
pp. 44-47
Author(s):  
D. A. Yagodnikov ◽  
Sh. L. Guseinov ◽  
P. A. Storozhenko ◽  
A. P. Shpara ◽  
A. V. Sukhov ◽  
...  

This study presents the findings of an investigation of flame propagation in air suspension of nanodispersed polyboride particles, and provides spectral, morphological, and mass-spectrometric analyses of condensed combustion products generated during an air suspension combustion.

Author(s):  
A. Korotkikh ◽  
◽  
I. Sorokin ◽  
◽  

The paper presents the results of thermodynamic calculations of the effect of pure boron additives on combustion characteristics of high-energy materials (HEM) based on ammonium perchlorate, ammonium nitrate, active fuel-binder, and powders of aluminum Al, titanium Ti, magnesium Mg, and boron B. The combustion parameters and the equilibrium composition of condensed combustion products (CCPs) of HEM model compositions were obtained with thermodynamic calculation program “Terra.” The compositions of solid propellants with different ratios of metals (Al/B, Ti/B, Mg/B, and Al/Mg/B) were considered. The combustion temperature Tad in a combustion chamber, the vacuum specific impulse J at the nozzle exit, and the mass fraction ma of the CCPs for HEMs were determined.


2021 ◽  
Vol 30 (2) ◽  
pp. 23-34
Author(s):  
O. N. Korolchenko ◽  
S. G. Tsarichenko ◽  
N. I. Konstantinova

Introduction. At present, the house-building industry, that produces timber structures, is in the process of sufficiently intensive development; however, high flammability of wood is the factor that restrains widespread use of timber in construction. The purpose of this work is to optimize the conditions of application of fire-retardant timber in the construction industry. The co-authors believe that the following problems are to be solved to attain this objective:● a comparative analysis of the fireproofing efficiency of several fire-proofing agents applied to different species of wood;● determination of the character of influence produced by fire proofing agents on fire retardant properties of wood.Methods of research. The fire proofing efficiency of sample compositions designated for wood was measured in compliance with the benchmark testing method specified in GOST R 53292 (p. 6.2). Experiments were launched pursuant to the methodology and with the help of measurement instruments specified in GOST 30244–94 (Method 2) to study the extent of the pine-tree timber flammability suppression. Critical values of thermal loads that may trigger inflammation and flame propagation in timber structures, that can be described using values of the critical surface density of the heat flow, were determined pursuant to GOST 30402–96 and GOST R 51032–97. The toxicity of combustion products and the smoke generation ability of fire-retardant pine-tree samples was assessed using standard methods and measurement instruments pursuant to GOST 12.1.044–89 (paragraphs 4.18 and 4.20).Research results and discussion. Biological flame retardants, integrated biological flame retardants that also ensure moisture protection, intumescent coatings, lacquers and varnishes that are ready for use and labelled as having group I and II fire-retardant efficiency pursuant to GOST R 53292, were studied in the course of this research project. The co-authors have identified that the mass loss by all fire-retardant compositions is below 9 %, if applied to samples of larch and oak-tree timber, same as if it were applied to standard samples of pine-tree timber.The findings of the experiment conducted to assess the flammability, ignitibility, flame propagation, smoke generation ability and toxicity of combustion products have proven the maximal efficiency of the composition designated for full-cell pressure impregnation of timber that ensures the properties of the material labelled as G1, V1, RP1, T2, D2.Conclusions. Hence, the research results have enabled the co-authors to assess the discrepancy between average mass loss values demonstrated by the samples of different species of timber (alder, linden, pine-tree, larch, and oak-tree).The comprehensive study of flammability properties of timber, treated by compositions that vary in their chemical composition and mode of action of the fire proofing agent, enabled the co-authors to identify the impact produced by versatile fire-proofing agents on different flammability properties of pine-tree timber with regard taken of the fire-safe use of construction materials and constructions of buildings and structures.


2013 ◽  
Vol 735 ◽  
pp. 176-202 ◽  
Author(s):  
Philipp A. Boettcher ◽  
Shyam K. Menon ◽  
Brian L. Ventura ◽  
Guillaume Blanquart ◽  
Joseph E. Shepherd

AbstractIn experiments of hot surface ignition and subsequent flame propagation, a puffing flame instability is observed in mixtures that are stagnant and premixed prior to ignition. By varying the size of the hot surface, power input, and combustion vessel volume, it was determined that the instability is a function of the interaction of the flame, with the fluid flow induced by the combustion products rather than the initial plume established by the hot surface. Pressure ranges from 25 to 100 kPa and mixtures of n-hexane/air with equivalence ratios between $\phi = 0. 58$ and 3.0 at room temperature were investigated. Equivalence ratios between $\phi = 2. 15$ and 2.5 exhibited multiple flame and equivalence ratios above $\phi = 2. 5$ resulted in puffing flames at atmospheric pressure. The phenomenon is accurately reproduced in numerical simulations and a detailed flow field analysis revealed competition between the inflow velocity at the base of the flame and the flame propagation speed. The increasing inflow velocity, which exceeds the flame propagation speed, is ultimately responsible for creating a puff. The puff is then accelerated upward, allowing for the creation of the subsequent instabilities. The frequency of the puff is proportional to the gravitational acceleration and inversely proportional to the flame speed. A scaling relationship describes the dependence of the frequency on gravitational acceleration, hot surface diameter, and flame speed. This relation shows good agreement for rich n-hexane/air and lean hydrogen/air flames, as well as lean hexane/hydrogen/air mixtures.


Author(s):  
A. G. Korotkikh ◽  
◽  
V. A. Arkhipov ◽  
O. G. Glotov ◽  
I. V. Sorokin ◽  
...  

The burning rate control of the high-energy materials (HEM) is mainly achieved by introducing the catalysts in composite solid propellant as well as by partial or complete replacement of ammonium perchlorate (AP) and ammonium nitrate by nitramines that change the equivalence ratio of formulation, or by varying the particle size of oxidizer and metal fuels. Promising metallic fuels are highly dispersed aluminum powders, which are characterized by different dispersity and passivation method, as well as bimetallic powders or mixtures of aluminum and other metals, their alloys, and metal powders with various coatings. In this study, the Al-based, Al/B-based, and Al/Fe-based HEM compositions have been used for comparative analysis of the ignition, combustion, and agglomeration characteristics. At the use of boron additive in the Al-based HEM, the ignition time is decreased by a factor of 1.2-1.4 and the burning rate is virtually unchanged as compared with that for the Al-based HEM. However, the agglomeration is significantly enhanced, which is manifested in the increase in the agglomerate particle content in condensed combustion products (CCP), increase in the agglomerate mean diameter, and increase in the unburned metal fraction in agglomerates.


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