scholarly journals Electrochemical and Spectroscopic Studies of Nanocomposites Laden with BaTiO3-grafted-graphene Oxide

Author(s):  
S. Padmaja ◽  
R. Nimma Elizabeth

The electrochemical behavior of lithium-sulfur batteries was investigated by means of electrochemical impedance spectroscopy (EIS). Films of NCPEs (PEO+LiCF3SO3+BaTiO3-g-GO) were cast using a novel hot-press technique. The addition of filler in fractional amount to the solid polymer matrix at room temperature further enhances the ionic conductivity. The membranes were subjected to cycling, FT-IR and Raman spectroscopic analyses. The occurrence of ion-ion pairs interaction has been identified using FT-IR and Raman analysis. Cells with this electrolyte have a high coulombic efficiency of 98% and a high cycling stability.

2007 ◽  
Vol 9 (9) ◽  
pp. 850-854 ◽  
Author(s):  
Raluca Ciceo Lucacel ◽  
Carmen Marcus ◽  
V. Timar ◽  
I. Ardelean

ChemInform ◽  
2007 ◽  
Vol 38 (50) ◽  
Author(s):  
Raluca Ciceo Lucacel ◽  
Carmen Marcus ◽  
V. Timar ◽  
I. Ardelean

2010 ◽  
Vol 24 (01) ◽  
pp. 51-58 ◽  
Author(s):  
S. C. BAIDOC ◽  
I. ARDELEAN

Structural analysis of x Ag 2 O · (100-x)[ B 2 O 3 · As 2 O 3] glass system, with 0 ≤ x ≤ 10 mol%, was performed by means of FT-IR and Raman spectroscopies. The purpose of this work is to investigate the structural changes that appear in the B 2 O 3 · As 2 O 3 glass matrix with the addition and increase of silver ion content. Boroxol rings, pyro-, ortho-, di-, tri-, tetra- and penta-borate groups, structural units characteristic to As 2 O 3 were found in the structure of the studied glasses. FT-IR spectroscopy measurements show that BO 3 units are the main structural units of the glass system. The presence of structural units characteristic to Ag 2 O were not directly evidenced by FT-IR spectroscopy. The Raman analysis leads to similar conclusions as the FT-IR measurements.


2007 ◽  
Vol 21 (26) ◽  
pp. 1767-1774 ◽  
Author(s):  
L. GRIGUTA ◽  
I. ARDELEAN

Glasses from x Gd 2 O 3 · (100-x)[ B 2 O 3 · TeO 2] system with 0 ≤ x ≤ 10 mol% have been prepared and studied by means of FT-IR absorption and Raman scattering. Being complementary spectroscopic techniques, both types of measurements FT-IR and Raman revealed that the network structure of the studied glasses is based on BO 3 and BO 4 units placed in different structure groups and also TeO 4, TeO 3 structural units. No absorption characteristic for Gd 2 O 3 was evidenced but some changes in the structure of B 2 O 3 · TeO 2 glass matrix are due to its presence.


2016 ◽  
Vol 10 (3) ◽  
pp. 329-339 ◽  
Author(s):  
Shaik Kareem Ahmmad ◽  
M.A. Samee ◽  
S.M. Taqiullah ◽  
Syed Rahman

1993 ◽  
Vol 26 (2) ◽  
pp. 293-304
Author(s):  
Mahmut Acimiş ◽  
Sevim Akyüz ◽  
Ayşen Alaman

Biopolymers ◽  
1984 ◽  
Vol 23 (4) ◽  
pp. 623-627 ◽  
Author(s):  
V. Renugopalakrishnan ◽  
P. H. B. Kloumann ◽  
Rajendra S. Bhatnagar

2017 ◽  
Vol 19 (1) ◽  
pp. 81-88 ◽  
Author(s):  
Meral Yildirim ◽  
Azmi Seyhun Kipcak ◽  
Emek Moroydor Derun

Abstract In this study, sonochemical-assisted magnesium borate synthesis is studied from different boron sources. Various reaction parameters are successfully applied by a simple and green method. X-ray diffraction (XRD), Fourier transform infrared (FT-IR) and Raman spectroscopies are used to characterize the synthesized magnesium borates on the other hand surface morphologies are investigated by using scanning electron microscope (SEM). The XRD analyses showed that the products were admontite [MgO(B2O3)3 · 7(H2O)] with JCPDS (Joint Committee on Powder Diffraction Standards) no. of 01-076-0540 and mcallisterite [Mg2(B6O7(OH)6)2 · 9(H2O)] with JCPDS no. of 01-070-1902. The results that found in the spectroscopic studies were in a good agreement with characteristic magnesium borate bands in both regions of infra-red and visible. According to SEM results, obtained borates were in micro and sub-micro scales. By the use of ultrasonication, reaction yields were found between 84.2 and 97.9%. As a result, it is concluded that the sonochemical approach is a practicable synthesis method to get high efficiency and high crystallinity in the synthesis magnesium borate compounds.


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