scholarly journals THE GEOCHEMICAL CHARACTERISTIC OF MAJOR ELEMENT OF GRANITOID OF NATUNA, SINGKEP, BANGKA AND SIBOLGA

2016 ◽  
Vol 30 (1) ◽  
pp. 45
Author(s):  
Ediar Usman
Keyword(s):  
Chemical Composition ◽  
Major Element ◽  
Calc Alkaline ◽  
Geochemical Characteristic ◽  
Granite Magma ◽  
Alkaline Magma ◽  
Acid Magma ◽  
Rock Types ◽  
High K ◽  
Granite Belt

A study of geochemical characteristic of major elelemnt of granitoid in Western Indonesia Region was carried out at Natuna, Bangka, Singkep and Sibolga. The SiO2 contents of the granites are 71.16 to 73.02 wt%, 71.77 to 75.56wt% and 71.16 to 73.02wt% at Natuna, Bangka, and Singkep respectively, which are classified as acid magma. While in Sibolga the SiO2 content from 60.27 to 71.44wt%, which is classified as intermediate to acid magma. Based on Harker Diagram, the granites from Natuna, Bangka and Singkep as a co-genetic. In other hand the Sibolga Granite show as a scatter pattern. Granites of Natuna, Bangka and Singkep have the alkaline-total (Na2O + K2O) between 6.03 to 8.51 wt% which are classified as granite and alkali granite regime. K2O content ranges from 3.49 to 5.34 wt% and can be classified as calc-alkaline type. The content of alkaline-total of Sibolga granite between 8.12 to 11.81 wt% and classified as a regime of syenite and granite. The range of K2O is about 5.36 to 6.94wt%, and assumed derived from high-K magma to ultra-potassic types. Granites of Natuna, Bangka and Singkep derived from the plutonic rock types and calc-alkaline magma, while Sibolga granite magma derived from K-high to ultra-potassic as a granite of islands arc. Based on the chemical composition of granite in Western Indonesian Region can be divided into two groups, namely Sibolga granite group is representing the Sumatera Island influenced by tectonic arc system of Sumatera Island. Granites of Bangka and Singkep are representing a granite belt in Western Indonesian Region waters which is influenced by tectonic of back arc.Keywords: magma, geochemical characteristic, major element and Western Indonesian Region Kajian karakteristik geokimia dari unsur utama granitoid di Kawasan Barat Indonesia telah dilakukan di daerah Natuna, Bangka, Singkep dan Sibolga. Kandungan SiO2 granit Natuna antara 71,16 - 73,02%, Bangka antara 71,77 - 75,56%, Singkep antara 72,68 - 76,81% termasuk dalam magma asam. Granit Sibolga memiliki kandungan SiO2 antara 60,27 - 71,44% termasuk dalam magma menengah - asam. Berdasarkan Diagram Harker, granit Natuna, Bangka dan Singkep mempunyai asal kejadian yang sama (ko-genetik), sedangkan granit Sibolga membentuk pola pencar. Granit Natuna, Bangka dan Singkep mengandung total alkalin (K2O+Na2O) antara 6,03 - 8,51% termasuk dalam jenis rejim granit dan alkali granit. Berdasarkan kandungan K2O antara 3,49 - 5,34 %berat, bersifat kalk-alkali. Granit Sibolga mengandung total alkali antara 8,12 - 11,81% termasuk dalam rejim syenit dan granit, dan berdasarkan kandungan K2O antara 5,36 - 6,94% berasal dari jenis magma K-tinggi sampai ultra-potassik. Granit Natuna, Bangka dan Singkep berasal dari jenis batuan beku dalam dan magma kalk-alkalin yang berhubungan dengan penunjaman, sedangkan granit Sibolga berasal dari jenis magma K-tinggi - ultra-potassik sebagai granit busur kepulauan. Berdasarkan komposisi unsur kimia utama, granit di Kawasan Barat Indonesia dapat dibagi dalam dua, yaitu granit Sibolga yang mewakili P. Sumatera, dipengaruhi oleh sistem tektonik busur P. Sumatera. Granit Bangka dan Singkep dapat mewakili suatu jalur granit di perairan Kawasan Barat Indonesia yang dipengaruhi oleh tektonik busur belakang. Kata kunci: jenis magma, karakteristik geokimia, unsur utama, dan Kawasan Barat Indonesia

scholarly journals Trace Element Composition of Igneous and Hydrothermal Magnetite from Porphyry Deposits: Relationship to Deposit Subtypes and Magmatic Affinity

2019 ◽  
Vol 114 (5) ◽  
pp. 917-952 ◽  
Author(s):  
Xiao-Wen Huang ◽  
Anne-Aurélie Sappin ◽  
Émilie Boutroy ◽  
Georges Beaudoin ◽  
Sheida Makvandi
Keyword(s):  
Chemical Composition ◽  
Oxygen Fugacity ◽  
Trace Element Composition ◽  
Element Composition ◽  
Calc Alkaline ◽  
Porphyry Deposits ◽  
Alkaline Magma ◽  
Porphyry Cu ◽  
Skarn Deposits ◽  
Higher Temperature

Abstract The trace element composition of igneous and hydrothermal magnetite from 19 well-studied porphyry Cu ± Au ± Mo, Mo, and W-Mo deposits was measured by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) and then classified by partial least squares-discriminant analysis (PLS-DA) to constrain the factors explaining the relationships between the chemical composition of magnetite and the magmatic affinity and porphyry deposit subtypes. Igneous magnetite can be discriminated by relatively high P, Ti, V, Mn, Zr, Nb, Hf, and Ta contents but low Mg, Si, Co, Ni, Ge, Sb, W, and Pb contents, in contrast to hydrothermal magnetite. Compositional differences between igneous and hydrothermal magnetite are mainly controlled by the temperature, oxygen fugacity, cocrystallized sulfides, and element solubility/mobility that significantly affect the partition coefficients between magnetite and melt/fluids. Binary diagrams based on Ti, V, and Cr contents are not enough to discriminate igneous and hydrothermal magnetite in porphyry deposits. Relatively high Si and Al contents discriminate porphyry W-Mo hydrothermal magnetite, probably reflecting the control by high-Si, highly differentiated, granitic intrusions for this deposit type. Relatively high Mg, Mn, Zr, Nb, Sn, and Hf but low Ti and V contents discriminate porphyry Au-Cu hydrothermal magnetite, most likely resulting from a combination of mafic to intermediate intrusion composition, high chlorine in fluids, relatively high oxygen fugacity, and low-temperature conditions. Igneous or hydrothermal magnetite from Cu-Mo, Cu-Au, and Cu-Mo-Au deposits cannot be discriminated from each other, probably due to similar intermediate to felsic intrusion composition, melt/fluid composition, and conditions such as temperature and oxygen fugacity for the formation of these deposits. The magmatic affinity of porphyritic intrusions exerts some control on the chemical composition of igneous and hydrothermal magnetite in porphyry systems. Igneous and hydrothermal magnetite related to alkaline magma is relatively rich in Mg, Mn, Co, Mo, Sn, and high field strength elements (HFSEs), perhaps due to high concentrations of chlorine and fluorine in magma and exsolved fluids, whereas those related to calc-alkaline magma are relatively rich in Ca but depleted in HFSEs, consistent with the high Ca but low HFSE magma composition. Igneous and hydrothermal magnetite related to high-K calc-alkaline magma is relatively rich in Al, Ti, Sc, and Ta, due to a higher temperature of formation or enrichment of these elements in melt/fluids. Partial least squares-discriminant analysis on hydrothermal magnetite compositions from porphyry Cu, iron oxide copper-gold (IOCG), Kiruna-type iron oxide-apatite (IOA), and skarn deposits around the world identify important discriminant elements for these deposit types. Magnetite from porphyry Cu deposits is characterized by relatively high Ti, V, Zn, and Al contents, whereas that from IOCG deposits can be discriminated from other types of magnetite by its relatively high V, Ni, Ti, and Al contents. IOA magnetite is discriminated by higher V, Ti, and Mg but lower Al contents, whereas skarn magnetite can be separated from magnetite from other deposit types by higher Mn, Mg, Ca, and Zn contents. Decreased Ti and V contents in hydrothermal magnetite from porphyry Cu and IOA, to IOCG, and to skarn deposits may be related to decreasing temperature and increasing oxygen fugacity. The relative depletion of Al in IOA magnetite is due to its low magnetite-silicate melt partition coefficient, immobility of Al in fluids, and earlier, higher-temperature magmatic or magmatic-hydrothermal formation of IOA deposits. The relative enrichment of Ni in IOCG magnetite reflects more mafic magmatic composition and less competition with sulfide, whereas elevated Mn, Mg, Ca, and Zn in skarn magnetite results from enrichment of these elements in fluids via more intensive fluid-carbonate rock interaction.

scholarly journals Petrography and Geochemical Characterization of a Granite Batholith in Idanre, Southwestern Nigeria

2021 ◽  
Vol 50 (2) ◽  
pp. 315-326
Author(s):  
Oluwatoyin O. Akinola ◽  
Azman A. Ghani ◽  
Elvaene James
Keyword(s):  
Calc Alkaline ◽  
Southwestern Nigeria ◽  
Geochemical Characterization ◽  
Fine Grained ◽  
Rock Types ◽  
Pan African ◽  
High K ◽  
Granite Batholith ◽  
Type Granite

Idanre granite batholith in southwestern Nigeria contain three rock types, namely, Older granite undifferentiated (OGu), Older granite porphyritic (OGp) and Older granite fine-grained (OGf). The granitoids intruded into a basement rock of primarily migmatite gneiss. Petrography indicates that quartz, orthoclase, hornblende, and biotite are common to all members while microcline is more prominent in OGp and plagioclase is poorly represented in OGf. Despite minor differences in petrographic features, the granite units generally have similar geochemical relationships. The average SiO2 contents in OGp (70.49%), OGu (68.7%) and OGf (65.8%) are comparable to similar Pan-African suites located in eastern and northern Nigeria. Na2O+K2O-CaO versus SiO2 diagram shows all the granite members are calcic, K2O vs SiO2 plot classify the granites as high-K calcic alkali to shoshonitic. ANK vs ACNK plot indicatesthey are peraluminous. Plot of A/CNK vs SiO2 and K2O vs Na2O diagrams classified the rock as S-type granite. The granitoids are calc-alkaline with elevated Na2O (>2.6%) and Al/(Na2O+CaO) contents (OGu, 2.1-3.4; OGp, 2.4-3.1 and OGf, 2.2-2.9). The tectonic diagram (Rb vs (Y+Nb) indicatesthatthe batholith is Within Plate Granite (WPG.

scholarly journals Middle Triassic high-K calc-alkaline effusive and pyroclastic rocks from the Zagorje-Mid-Transdanubian Zone (Mt. Kuna Gora; NW Croatia): mineralogy, petrology, geochemistry and tectonomagmatic affinity

2021 ◽  
Vol 19 ◽  
pp. 1-23
Author(s):  
Damir Slovenec ◽  
Branimir Šegvić
Keyword(s):  
Middle Triassic ◽  
Crustal Contamination ◽  
Volcanic Glass ◽  
Alkali Feldspar ◽  
Oceanic Lithosphere ◽  
White Mica ◽  
Calc Alkaline ◽  
Rock Types ◽  
Active Margins ◽  
High K

This study uses mineralogical, petrological, geochemical, and Sr and Nd isotope data along with K-Ar ages to infer the petrogenesis and geodynamic evolution of Middle Triassic high-K calc-alkaline lavas and their associated pyroclastics of Mt. Kuna Gora in NW Croatia. Their analogue mineralogy and bulk-rock geochemistry testify to the coeval origin of both rock types. Sanidine and plagioclase accompanied by inor augite and Ti-bearing magnetite are the major phases found in a matrix of devitrified volcanic glass and plagioclase microlites. Hydrothermal anddiagenetic processes in the pyroclastics originated the formation of chlorite and white mica, and mixed-layer clay minerals, respectively. Petrography reveals the following crystallization order: spinel→clinopyroxene→plagioclase→alkali-feldspar±Fe-Ti oxides. Geochemical and isotopic data suggests that the studied rocks had a complex origin that included the contamination of subduction-generated magmas by lithospheric mantle melts. This presumes an interplay between fertile arc mantle, subducted continental crust, and depleted or ocean island basalts-like mantle. A low degree of crustal contamination stands as a last step in the formation of such “hybrid” magmas. The subducted Paleotethyan oceanic lithosphere went through processes of partial melting at depths of ~45-49km and pressures of ≤1.6GPa and fractionation that produced melts which gave rise to the studied rocks. In the model we are proposing herein such formed partial melts are related to the demise of the northward subduction of the Paleotethys oceanic lithosphere during the Early to Middle Triassic epoch, which is consistent with an active, ensialic mature volcanic arc developing along Laurussian southern active margins.

Laramide to Miocene syn-extensional plutonism in the Puerta del Sol area, central Sonora, Mexico

2017 ◽  
Vol 34 (1) ◽  
pp. 45 ◽  
Author(s):  
Elizard González-Becuar ◽  
Efrén Pérez-Segura ◽  
Ricardo Vega-Granillo ◽  
Luigi Solari ◽  
Carlos Manuel González-León ◽  
...  
Keyword(s):  
Metamorphic Core Complex ◽  
Primitive Mantle ◽  
Isotopic Ratios ◽  
Magmatic Evolution ◽  
Calc Alkaline ◽  
Core Complex ◽  
High K ◽  
Sierra Madre ◽  
Plutonic Rocks ◽  
Metamorphic Core

Plutonic rocks of the Puerta del Sol area, in central Sonora, represent the extension to the south of the El Jaralito batholith, and are part of the footwall of the Sierra Mazatán metamorphic core complex, whose low-angle detachment fault bounds the outcrops of plutonic rocks to the west. Plutons in the area record the magmatic evolution of the Laramide arc and the Oligo-Miocene syn-extensional plutonism in Sonora. The basement of the area is composed by the ca. 1.68 Ga El Palofierral orthogneiss that is part of the Caborca block. The Laramide plutons include the El Gato diorite (71.29 ± 0.45 Ma, U-Pb), the El Pajarito granite (67.9 ± 0.43 Ma, U-Pb), and the Puerta del Sol granodiorite (49.1 ± 0.46 Ma, U-Pb). The younger El Oquimonis granite (41.78 ± 0.32 Ma, U-Pb) is considered part of the scarce magmatism that in Sonora records a transition to the Sierra Madre Occidental magmatic event. The syn-extensional plutons are the El Garambullo gabbro (19.83 ± 0.18 Ma, U-Pb) and the Las Mayitas granodiorite (19.2 ± 1.2 Ma, K-Ar). A migmatitic event that affected the El Palofierral orthogneiss, El Gato diorite, and El Pajarito granite between ca. 68 and 59 Ma might be related to the emplacement of the El Pajarito granite. The plutons are metaluminous to slightly peraluminous, with the exception of El Oquimonis granite, which is a peraluminous two-mica, garnet-bearing granite. They are mostly high-K calc-alkaline with nearly uniform chondrite-normalized REE and primitive-mantle normalized multielemental patterns that are characteristic of continental margin arcs and resemble patterns reported for other Laramide granites of Sonora. The Laramide and syn-extensional plutons also have Sr, Nd and Pb isotopic ratios that plot within the fields reported for Laramide granites emplaced in the Caborca terrane in northwestern and central Sonora. Nevertheless, and despite their geochemical affinity to continental magmatic arcs, the El Garambullo gabbro and Las Mayitas granodiorite are syn-extensional plutons that were emplaced at ca. 20 Ma during development of the Sierra Mazatán metamorphic core complex. The 40Ar/39Ar and K-Ar ages obtained for the El Palofierral orthogneiss, the Puerta del Sol granodiorite, the El Oquimonis granite, and the El Garambullo gabbro range from 26.3 ± 0.6 to 17.4 ± 1.0 Ma and are considered cooling ages associated with the exhumation of the metamorphic core complex.

Early Cretaceous crust–mantle interaction linked to rollback of the Palaeo-Pacific flat-subducting slab: constraints from the intermediate–felsic volcanic rocks of the northern Great Xing’an Range, NE China

2021 ◽  
pp. 1-22
Author(s):  
Jia-Hao Jing ◽  
Hao Yang ◽  
Wen-Chun Ge ◽  
Yu Dong ◽  
Zheng Ji ◽  
...  
Keyword(s):  
Early Cretaceous ◽  
Volcanic Rocks ◽  
Geochemical Data ◽  
Calc Alkaline ◽  
Ne China ◽  
Asthenospheric Mantle ◽  
High K ◽  
Wide Range ◽  
Great Xing’An Range ◽  
Subducting Slab

Abstract Late Mesozoic igneous rocks are important for deciphering the Mesozoic tectonic setting of NE China. In this paper, we present whole-rock geochemical data, zircon U–Pb ages and Lu–Hf isotope data for Early Cretaceous volcanic rocks from the Tulihe area of the northern Great Xing’an Range (GXR), with the aim of evaluating the petrogenesis and genetic relationships of these rocks, inferring crust–mantle interactions and better constraining extension-related geodynamic processes in the GXR. Zircon U–Pb ages indicate that the rhyolites and trachytic volcanic rocks formed during late Early Cretaceous time (c. 130–126 Ma). Geochemically, the highly fractionated I-type rhyolites exhibit high-K calc-alkaline, metaluminous to weakly peraluminous characteristics. They are enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) but depleted in high-field-strength elements (HFSEs), with their magmatic zircons ϵHf(t) values ranging from +4.1 to +9.0. These features suggest that the rhyolites were derived from the partial melting of a dominantly juvenile, K-rich basaltic lower crust. The trachytic volcanic rocks are high-K calc-alkaline series and exhibit metaluminous characteristics. They have a wide range of zircon ϵHf(t) values (−17.8 to +12.9), indicating that these trachytic volcanic rocks originated from a dominantly lithospheric-mantle source with the involvement of asthenospheric mantle materials, and subsequently underwent extensive assimilation and fractional crystallization processes. Combining our results and the spatiotemporal migration of the late Early Cretaceous magmatic events, we propose that intense Early Cretaceous crust–mantle interaction took place within the northern GXR, and possibly the whole of NE China, and that it was related to the upwelling of asthenospheric mantle induced by rollback of the Palaeo-Pacific flat-subducting slab.

Felsic plutonic rocks from the southern portion of the New Caledonian Ultramafic Belt

1973 ◽  
Vol 110 (5) ◽  
pp. 431-446 ◽  
Author(s):  
K. A. Rodgers
Keyword(s):  
New Caledonia ◽  
Ultramafic Rocks ◽  
Calc Alkaline ◽  
Mafic Rocks ◽  
Alkaline Magma ◽  
Southwest Pacific ◽  
Plutonic Rocks

SummaryGranodiorite stocks were intruded into the alpine peridotites of southern New Caledonia in the Eocene following overthrusting of the ultramafics onto the sialic core of the island. Strong zoning, from mela-diorite to granodiorite, is developed in one pluton and is believed to be the result of assimilation of ultramafic and mafic rocks by the calc-alkaline magma. Evidence in favour of a consanguineous relationship between the felsic and ultramafic rocks is largely circumstantial. In their petrography, mineralogy and chemistry, the rocks show few differences from other felsic plutonics of Tertiary age in the southwest Pacific.

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