Geochemical and Geochronological Constraints on a Granitoid Containing the Largest Indosinian Tungsten (W) Deposit in South China (SC): Petrogenesis and Implications

Chuankou tungsten (W) ore field, with an estimated WO3 reserve exceeding 300,000 tonnes, is so far the largest Indosinian (Triassic) granite-related W ore field in South China. However, the precise emplacement ages, sources of granitoids, and their relationship with W mineralization are still not well understood. In this research, four main magmatic stages (G-1 to G-4) have been identified in the Chuankou ore field, including G-1 (phase I, biotite monzogranite), G-2 (phase II, two-mica monzogranite), G-3 (phase III, fine-grained granite), and G-4 (phase IV, granite porphyry). LA-ICP-MS U-Pb dating of zircon grains from granitoids of the Chuankou W ore field yields emplacement ages of 230.8 ± 1.6 Ma, 222.1 ± 0.56 Ma, 203.1 ± 1.6 Ma, and 135.5 ± 2.4 Ma, respectively. Granitoids from the Chuankou ore field contain a large amount of peraluminous minerals such as biotite, musvite, garnet and tourmaline. Geochemically, the granitoids have high Si and Al (A/CNK > 1.1) content but low alkali, Fe, Mg, Mn, and Ca content. Moreover, there is enrichment of Rb, Zr, Hf, Th, and U, but depletions of Ba, Sr, P, and Ti. The granitoids have especially low Zr + Nb + Ce + Y and high Rb/Ba ratios, further indicating a highly fractionated S-type granite affinity with a significant crystal fractionation process in regard to K-feldspar, plagioclase, biotite, Ti-bearing minerals (except rutile), zircon, apatite, allanite, and monazite. Whole-rock εNd(t) and TDM2 values are −10.77 and 2090 Ma for G-1, −9.09 to −7.47 and 1764–1684 Ma for G-2, −10.07 to −6.53 and 1669–1471 Ma for G-3, respectively, indicating that the Chuankou granitoids were derived from two episodes of partial melting of the Paleoproterozoic to Mesoproterozoic metamorphic basement. Trace elements within the zircons and whole-rock geochemistry yielded evidence of the close relationship between W mineralization and G-1 and G-2 granitoids of the Chuankou ore field. The batholith of the Chuankou ore field was formed 20–10 Ma later than the peak age of the collisions orogeny and formed in a post-collisional setting.

Geochemistry of Granitoids in Central Sumatra: An Identification of Plate Extension during Triassic

Previous investigations of granitoids in Sumatra were focused on age dating with minimum geochemistry composition analysis. The purpose of this study is to define the geochemistry classification of the intrusions in central Sumatra and to explain the rocks' correlation to Southeast Asia tectonic activities. A polarizing microscope was used for petrography description while XRF and ICP-MS were applied for geochemistry measurements. According to the geochemistry, almost all of the intrusions are the I-type volcanic arc granitoids. The oldest studied rock is the Late Permian Ombilin Granite that should have been formed before West Sumatra and West Burma move away from the Cathaysia. Sulit Air Granite and Tanjung Gadang Granite intrusion were triggered by the subduction of Meso-Tethys beneath West Sumatra while Lassi Pluton and Lolo Pluton due to Indo-Australia and West Sumatra convergency. The Triassic Sijunjung Granite depicts A-type granite natures to suggest an extension in the West Sumatra plate.

Lithostratigraphy of the Mesoproterozoic Twakputs Gneiss

The Twakputs Gneiss is a garnetiferous, K-feldspar megacrystic, biotite granite-granodiorite orthogneiss. It represents a major unit in the Kakamas Domain of the Mesoproterozoic Namaqua-Natal Metamorphic Province extending about 250 km between Riemvasmaak in South Africa and Grünau in southern Namibia. The Twakputs Gneiss occurs as foliation-parallel, sheet-like bodies tightly infolded together with granulite-facies paragneisses into which it intrudes along with a variety of other pre-tectonic granite and leucogranite orthogneisses. These rocks were subsequently intruded by late-tectonic garnet-leucogranites, granites and charnockites. The Twakputs Gneiss is a distinctive unit characterised by large ovoid to elongate megacrysts of twinned perthitic K-feldspar, set in a coarse-grained matrix of garnet, biotite, quartz and feldspar. It contains a penetrative foliation defined by the alignment of K-feldspars and streaks of biotite that developed during the main phase D2 of the Namaqua Orogeny (~1.2 to 1.1 Ga). The foliation and an accompanying elongation lineation are more intensely developed along lithological contacts, especially at the margins of the mega-scale F3 domes and basins that refold the regional fabrics. U-Pb zircon dating of the Twakputs Gneiss has yielded concordia ages of between ~1192 and 1208 Ma. Whole-rock geochemistry shows consistent major, trace and REE elemental trends, and thus reflect chemical variability from a single fractionating magma. The Twakputs Gneiss has a granitic to granodiorite composition and is strongly peraluminous. The geochemistry and the ubiquitous presence of garnet and pelitic xenoliths indicate an S-type granite protolith. The Twakputs Gneiss is the most voluminous and widespread member of the Eendoorn Suite which comprises seven textural variants of garnetiferous, K-feldspar-megacrystic granitoid orthogneiss of the same age.