scholarly journals Middle Triassic high-K calc-alkaline effusive and pyroclastic rocks from the Zagorje-Mid-Transdanubian Zone (Mt. Kuna Gora; NW Croatia): mineralogy, petrology, geochemistry and tectonomagmatic affinity

2021 ◽  
Vol 19 ◽  
pp. 1-23
Author(s):  
Damir Slovenec ◽  
Branimir Šegvić

This study uses mineralogical, petrological, geochemical, and Sr and Nd isotope data along with K-Ar ages to infer the petrogenesis and geodynamic evolution of Middle Triassic high-K calc-alkaline lavas and their associated pyroclastics of Mt. Kuna Gora in NW Croatia. Their analogue mineralogy and bulk-rock geochemistry testify to the coeval origin of both rock types. Sanidine and plagioclase accompanied by inor augite and Ti-bearing magnetite are the major phases found in a matrix of devitrified volcanic glass and plagioclase microlites. Hydrothermal anddiagenetic processes in the pyroclastics originated the formation of chlorite and white mica, and mixed-layer clay minerals, respectively. Petrography reveals the following crystallization order: spinel→clinopyroxene→plagioclase→alkali-feldspar±Fe-Ti oxides. Geochemical and isotopic data suggests that the studied rocks had a complex origin that included the contamination of subduction-generated magmas by lithospheric mantle melts. This presumes an interplay between fertile arc mantle, subducted continental crust, and depleted or ocean island basalts-like mantle. A low degree of crustal contamination stands as a last step in the formation of such “hybrid” magmas. The subducted Paleotethyan oceanic lithosphere went through processes of partial melting at depths of ~45-49km and pressures of ≤1.6GPa and fractionation that produced melts which gave rise to the studied rocks. In the model we are proposing herein such formed partial melts are related to the demise of the northward subduction of the Paleotethys oceanic lithosphere during the Early to Middle Triassic epoch, which is consistent with an active, ensialic mature volcanic arc developing along Laurussian southern active margins.

2021 ◽  
pp. M55-2018-68 ◽  
Author(s):  
Philip T. Leat ◽  
Teal R. Riley

AbstractThe Antarctic Peninsula contains a record of continental-margin volcanism extending from Jurassic to Recent times. Subduction of the Pacific oceanic lithosphere beneath the continental margin developed after Late Jurassic volcanism in Alexander Island that was related to extension of the continental margin. Mesozoic ocean-floor basalts emplaced within the Alexander Island accretionary complex have compositions derived from Pacific mantle. The Antarctic Peninsula volcanic arc was active from about Early Cretaceous times until the Early Miocene. It was affected by hydrothermal alteration, and by regional and contact metamorphism generally of zeolite to prehnite–pumpellyite facies. Distinct geochemical groups recognized within the volcanic rocks suggest varied magma generation processes related to changes in subduction dynamics. The four groups are: calc-alkaline, high-Mg andesitic, adakitic and high-Zr, the last two being described in this arc for the first time. The dominant calc-alkaline group ranges from primitive mafic magmas to rhyolite, and from low- to high-K in composition, and was generated from a mantle wedge with variable depletion. The high-Mg and adakitic rocks indicate periods of melting of the subducting slab and variable equilibration of the melts with mantle. The high-Zr group is interpreted as peralkaline and may have been related to extension of the arc.


Author(s):  
Michele Lustrino ◽  
Claudio Chiarabba ◽  
Eugenio Carminati

ABSTRACT The Pliocene–Quaternary igneous record of the Tyrrhenian Sea area features a surprisingly large range of compositions from subalkaline to ultra-alkaline and from ultrabasic to acid. These rocks, emplaced within the basin and along its margins, are characterized by strongly SiO2-undersaturated and CaO-rich to strongly SiO2-oversaturated and peraluminous compositions, with sodic to ultrapotassic alkaline and tholeiitic to calc-alkaline and high-K calc-alkaline affinities. We focused on the different models proposed to explain the famous Roman Comagmatic Region, part of the Quaternary volcanism that spreads along the eastern side of the Tyrrhenian area, in the stretched part of the Apennines thrust-and-fold belt. We reviewed data and hypotheses proposed in the literature that infer active to fossil subduction up to models that exclude subduction entirely. Many field geology observations sustain the interpretation that the evolution of the Tyrrhenian-Apennine system was related to subduction of the western margin of Adria continental lithosphere after minor recycling of oceanic lithosphere. However, the lateral extent of the subducting slab in the last millions of years, when magmatism flared up, remains debatable. The igneous activity that developed in the last millions of years along the Tyrrhenian margin is here explained as originating from a subduction-modified mantle, regardless of whether the large-scale subduction system is still active.


2019 ◽  
Vol 60 (12) ◽  
pp. 2317-2338 ◽  
Author(s):  
Marie-Noëlle Guilbaud ◽  
Claus Siebe ◽  
Christine Rasoazanamparany ◽  
Elisabeth Widom ◽  
Sergio Salinas ◽  
...  

Abstract The origin of the large diversity of rock types erupted along the subduction-related Trans-Mexican Volcanic Belt (TMVB) remains highly debated. In particular, several hypotheses have been proposed to explain the contemporary eruption of calc-alkaline and alkaline magmas along the belt. The Michoacán-Guanajuato Volcanic Field (MGVF) is an atypical, vast region of monogenetic activity located in the western-central part of the TMVB. Here we present new petrographic, geochemical, and isotopic (Sr–Nd–Pb–Os) data on recent volcanics in the Jorullo-Tacámbaro area that is the closest to the oceanic trench. TMVB-related volcanics in this area are Plio-Quaternary (<5 Ma) and mainly form a calc-alkaline series from basalts to dacites, with rare (<5 vol. %) alkaline rocks that range from trachybasalts to trachydacites, and transitional samples. Crystal textures are consistent with rapid crystallization at shallow depth and processes of mixing of similar magma batches (magma recharge). All of the samples exhibit an arc-type trace element pattern. Alkaline and transitional magmas have higher Na2O and K2O, lower Al2O3, and higher concentrations in incompatible elements (e.g. Sr, K, Ba, Th, Ce, P) compared to calc-alkaline rocks. Calc-alkaline rocks are similar isotopically to transitional and alkaline samples, except for a few low 87Sr/86Sr samples. Sr, Nd and Pb isotopes do not correlate with MgO or 187Os/188Os, indicating that they were not significantly influenced by crustal contamination. Isotopic and trace-element systematics suggest that the Tacámbaro magmas are produced by melting of a mantle wedge fluxed by fluids derived from a mixture of subducted sediments and altered oceanic crust. Alkaline and transitional magmas can be derived from a lower degree of partial melting of a similar source to that of the calc-alkaline rocks, whereas the few low 87Sr/86Sr calc-alkaline rocks require a lower proportion of fluid derived from oceanic sediments and crust. Volcanism at the trenchward edge of the MGVF was thus driven purely by subduction during the last 5 Ma, hence discarding slab rollback in this sector of the TMVB.


Lithos ◽  
1999 ◽  
Vol 46 (4) ◽  
pp. 773-802 ◽  
Author(s):  
R. Benito ◽  
J. López-Ruiz ◽  
J.M. Cebriá ◽  
J. Hertogen ◽  
M. Doblas ◽  
...  

2020 ◽  
Vol 57 (2) ◽  
pp. 275-291
Author(s):  
Hao-Ran Li ◽  
Ye Qian ◽  
Feng-Yue Sun ◽  
Liang Li

The Zhanbuzhale region, in the Eastern Kunlun Orogen of northwestern China, is characterized by large volumes of Phanerozoic granitoid rocks and is an ideal region for investigating the tectonic evolution of the Paleo-Tethys system. However, the exact timing of the final closure of the Paleo-Tethys Ocean and initial continental collision remains controversial because of a lack of precise geochronological and detailed geochemical data. In this paper, we report new zircon U–Pb ages and mineralogical, petrographic, and geochemical data for samples of Middle Triassic granodiorite and alkali feldspar granite from the Zhanbuzhale region. The zircon U–Pb ages indicate that the granodiorite and alkali feldspar granite formed at 239 and 236 Ma, respectively. The granodiorites are high-K calc-alkaline, metaluminous, high Sr content, high Sr/Y ratios, low Y content, and show adakite-like affinities. The alkali feldspar granites display high SiO2, extremely low MgO, and low Zr+Nb+Ce+Y contents as well as low Fe2O3t/MgO ratios, showing metaluminous to peraluminous and high-K calc-alkaline features. Geochemical and petrological characteristics of the alkali feldspar granites suggest that they are highly fractionated I-type granites. The granodiorites and alkali feldspar granites have zircon εHf(t) values ranging from –2.26 to –0.18, and from –2.17 to +2.18, respectively. Together with regional geological data, we propose that the Triassic (approximately 239–236 Ma) granitoids were generated during the later stages of northward subduction of the Paleo-Tethys oceanic plate, and that the initial stage of collision between the East Kunlun and the Bayan Har–Songpan Ganzi terrane occurred at approximately 236–227 Ma.


2015 ◽  
Vol 66 (5) ◽  
pp. 361-374 ◽  
Author(s):  
Esmaiel Darvishi ◽  
Mahmoud Khalili ◽  
Roy Beavers ◽  
Mohammad Sayari

AbstractThe Marziyan granites are located in the north of Azna and crop out in the Sanandaj-Sirjan metamorphic belt. These rocks contain minerals such as quartz, K-feldspars, plagioclase, biotite, muscovite, garnet, tourmaline and minor sillimanite. The mineral chemistry of biotite indicates Fe-rich (siderophyllite), low TiO2, high Al2O3, and low MgO nature, suggesting considerable Al concentration in the source magma. These biotites crystallized from peraluminous S-type granite magma belonging to the ilmenite series. The white mica is rich in alumina and has muscovite composition. The peraluminous nature of these rocks is manifested by their remarkably high SiO2, Al2O3and high molar A/CNK (> 1.1) ratio. The latter feature is reflected by the presence of garnet and muscovite. All field observations, petrography, mineral chemistry and petrology evidence indicate a peraluminous, S-type nature of the Marziyan granitic rocks that formed by partial melting of metapelite rocks in the mid to upper crust possibly under vapour-absent conditions. These rocks display geochemical characteristics that span the medium to high-K and calc-alkaline nature and profound chemical features typical of syn-collisional magmatism during collision of the Afro-Arabian continental plate and the Central Iranian microplate.


2021 ◽  
Vol 50 (2) ◽  
pp. 315-326
Author(s):  
Oluwatoyin O. Akinola ◽  
Azman A. Ghani ◽  
Elvaene James

Idanre granite batholith in southwestern Nigeria contain three rock types, namely, Older granite undifferentiated (OGu), Older granite porphyritic (OGp) and Older granite fine-grained (OGf). The granitoids intruded into a basement rock of primarily migmatite gneiss. Petrography indicates that quartz, orthoclase, hornblende, and biotite are common to all members while microcline is more prominent in OGp and plagioclase is poorly represented in OGf. Despite minor differences in petrographic features, the granite units generally have similar geochemical relationships. The average SiO2 contents in OGp (70.49%), OGu (68.7%) and OGf (65.8%) are comparable to similar Pan-African suites located in eastern and northern Nigeria. Na2O+K2O-CaO versus SiO2 diagram shows all the granite members are calcic, K2O vs SiO2 plot classify the granites as high-K calcic alkali to shoshonitic. ANK vs ACNK plot indicatesthey are peraluminous. Plot of A/CNK vs SiO2 and K2O vs Na2O diagrams classified the rock as S-type granite. The granitoids are calc-alkaline with elevated Na2O (>2.6%) and Al/(Na2O+CaO) contents (OGu, 2.1-3.4; OGp, 2.4-3.1 and OGf, 2.2-2.9). The tectonic diagram (Rb vs (Y+Nb) indicatesthatthe batholith is Within Plate Granite (WPG.


2021 ◽  
Vol 72 (3) ◽  
Author(s):  
Jaroslav Lexa ◽  
Peter Varga ◽  
Peter Uhlík ◽  
Peter Koděra ◽  
Adrián Biroň ◽  
...  

Perlites in the Central Slovakia Volcanic Field are associated with with rhyolite dykes, cryptodomes, extrusive domes, coulées and volcanoclastic rocks of the Jastrabá Fm. (12.3–11.4 Ma). From numerous occurrences only the Lehôtka pod Brehmi (LPB) and Jastrabá (JST) represent deposits of economic interest. The LPB deposit exploits a pile of extruded hyaloclastite breccia composed of grey porous and dark dense fragments. The JST deposit exploits glassy rhyolite breccia composed of grey porous fragments associated with an extrusive dome/coulée. The perlites at both deposits are peraluminous, calc-alkaline of the high-K type, poor in phenocrysts (around 5 %) of plagioclase, biotite and minor amphibole (LPB) or sanidine/anorthoclase (JST). Glass at both deposits is silica rich (75.4–79.5 wt. % dry) with Al2O3, K2O and Na2O as other major constituents. It is inhomogeneous showing domains enriched in Na2O or K2O. Glass water content (3.0–6.0 wt. %) shows a weak positive correlation with its silica content and a negative correlation with its Na2O content. Perlites show porosities of 5–16 % (dark dense), 16–30 % (grey porous) and 30–44 % (pale grey ­pumiceous). Narrow stretched pores represent remnants after outgassing of ascending magma while open undeformed pores grew at a low pressure before quenching. The transformation of volcanic glass into perlite took place owing to the hydration by heated fluids of meteoric origin. The hydration was supported by a significant porosity with inter­connected pores and by sustained elevated temperature. Perlites at both deposits show a low content of tightly-bound water and a low Na/K ratio. These properties are responsible for their relatively low degree of expansion. On the other hand, due to the same reason, the perlites have a good mechanical stability.


1985 ◽  
Vol 22 (8) ◽  
pp. 1204-1216 ◽  
Author(s):  
Lee C. Pigage ◽  
Robert G. Anderson

The Anvil plutonic suite consists of three phases: a peraluminous muscovite–biotite granite (Mount Mye phase) and two metaluminous to peraluminous hornblende–biotite granodiorite and minor granite intrusions (Orchay and Marjorie phases). The suite is massive or foliated, equigranular or seriate, and contains alkali-feldspar megacrysts. The Marjorie phase is characteristically porphyritic.Geochemical trends are irregular for the suite and for individual phases. High-K2O, low-CaO, and low-MgO compositions typify the silicic, calc-alkaline suite. Hornblende-bearing phases contain less SiO2, K2O, and Rb and more cafemic oxides, TiO2, Sr, Ba, and Y than the Mount Mye phase and are compositionally similar to coeval South Fork volcanics.Isochrons from some of the Orchay phase whole-rock samples (t = 99 ± 2.5 Ma; 87Sr/86Sri = 0.7161 ± 0.0001) and from whole rocks and minerals of the Mount Mye phase (t = 100 ± 2 Ma; 87Sr/86Sri = 0.7405 ± 0.0001) indicate they are coeval but not comagmatic, accounting for the lithologic, petrographic, and geochemical distinctions. Similar K–Ar isotopic ages (81–102 Ma) suggest rapid cooling and therefore high-level emplacement. Together, the isotopic ages provide a minimum (youngest) age for the main deformation of the surrounding metasediments and a maximum (oldest) age for movement along the Tintina Fault.A petrographically and geochemically distinct sample from the Orchay phase yielded a Rb–Sr isochron age of 61 ± 1.5 Ma and an initial 87Sr/86Sr ratio of 0.7090 ± 0.0001, implying intrusive activity in the Paleocene.Field relations, lithology, petrography, geochronometry, and geochemistry suggest that the Orchay and Marjorie phases are plutonic equivalents of the South Fork volcanics. Similarities in plutonic style characterize the extensive mid-Cretaceous igneous event in southeast Yukon.


2001 ◽  
Vol 172 (2) ◽  
pp. 189-200 ◽  
Author(s):  
Olivier Blein ◽  
Henriette Lapierre ◽  
Richard A. Schweickert ◽  
Arnaud Pecher ◽  
Cedric Reynaud

Abstract Two types of island-arc occur in the North American Cordillera during the Permian-Triassic times. The first type is exposed in the eastern Klamath and Blue Mountains (fig. 1). Its stratigraphy is continuous from Permian to Triassic, and is composed of arc-tholeiites with minor calc-alkaline lavas. This suite shows high epsilon Nd (sub (T)) values similar to the range of intra-oceanic island-arc [Lapierre et al., 1987; Brouxel et al., 1987, 1988; Charvet et al., 1990; Lapierre et al., 1990, 1994]. In contrast, the second type, exposed in northern Sierra Nevada and central-western Nevada (Black Dyke) (fig. 1), is characterized by an early Permian calc-alkaline suite, with positive to negative epsilon Nd (sub (T)) values. Its basement is inferred to present continental affinities [Rouer et Lapierre, 1989; Rouer et al., 1989; Blein et al., 1996, 2000]. In western Nevada, volcanic rocks of early Triassic age are present in few localities: (1) the Triassic Koipato Group in central Nevada (fig. 1); (2) the Pablo Formation in the Shoshone mountains and the Paradise Range (figs. 1 and 2); and (3) the Garfield Flat formation in the Excelsior mountains (figs. 1 and 2). Silberling [1959] has subdivided the Pablo formation into three members: clastic, limestone, and greenstone (fig. 3). The clastic member consists of andesites, interbedded with volcaniclastic turbidites. The contact between the clastic and the limestone members is gradational and interlensing. The limestones are locally bioclastic with shell fragments, indicating a shallow-water deposition. They yielded a reworked late Permian fauna which suggests a late Permian or younger age. The clastic and limestone members could represent the recurrent rapid deposition in a shallow marine basin of volcanic flows, reworked material from a nearby terrane of volcanic, granitic, and sedimentary rocks. The greenstone member is composed of andesites, volcanic breccias and tuffs. The middle Triassic Granstville formation rests conformably on the Pablo formation. Both formations are affected by Mesozoic polyphase deformations [Oldow, 1985]. The Permian and/or Triassic Garfield Flat formation is composed of ignimbrites and pyroclastic breccia interlayered with conglomerates, sandstones, calcareous and red pelites (fig. 4). The Jurassic-Triassic Gabbs-Sunrise formation rests unconformably on the Garfield Flat formation. Both formations are affected by Mesozoic polyphase deformations [Oldow, 1985]. In the Pablo formation, lavas are shoshonitic basalts and calc-alkaline andesites, while calc-alkaline andesites and rhyolites predominate in the Garfield Flat formation. Basalts and andesites exhibit enriched LREE patterns (fig. 6) with slight negative anomalies in TiO 2 , Nb and Ta typical of subducted-related magmas in the primitive mantle-normalized spidergrams (fig. 7). The lavas show epsilon Sr (sub (T)) and epsilon Nd (sub (T)) values which range between -0.4 to +19.6, and -1.4 to +0.8 respectively (fig. 8). Most of the samples are displaced from the mantle array toward higher epsilon Sr (sub (T)) values, due to the alteration. The epsilon Nd (sub (T)) values, close to the Bulk Earth composition, record an interaction between material from a juvenile pole (mantle or young crust) and from an old crust. The Pablo and Garfield Flat formations differ from the Permian Black Dyke formation. This latter is characterized by calc-alkaline basalts and mafic andesites enriched in LREE, and a mantle source contaminated by subducted sediments or arc-basement [Blein et al., 2000]. The Pablo and Garfield Flat formations show many similarities with the Koipato Group. In central Nevada, the Koipato Group is a sequence of andesites, dacites and rhyolites interbedded with tuffs and volcaniclastic sediments. It rests with a marked angular unconformity on folded Upper Paleozoic oceanic rocks [Silberling and Roberts, 1962]. Fission-track dating on zircon [McKee and Burke, 1972] indicate an age of 225+ or -30 Ma for the Koipato Group. Ammonites, near the top, are considered to be upper early Triassic [Silberling, 1973]. The Pablo and Garfield Flat lavas share in common with the Koipato Group: (1) late Permian to middle Triassic ages; (2) abundant andesites and rhyolites with minor basalts, associated with felsic pyroclastic breccias; (3) LILE and LREE enrichement; (4) low epsilon Nd (sub (T)) values suggesting a juvenile source with slight contamination by a crustal component; (5) La/Nb ratios close to the lower limit of orogenic andesites [Gill, 1981]; and (6) high Nb/Zr ratios suggesting a generation far from a subduction zone [Thieblemont and Tegyey, 1994]. This Triassic high-K calc-alkaline to shoshonitic magmatism is enriched in K, Rb, Th, Nb and Ta relative to the calc-alkaline Black Dyke lavas, and is mainly juvenile judging from Nd isotopic ratios. The source may correspond either to a juvenile crust composed of high-K andesites [Roberts and Clemens, 1993], which could be the Black Dyke lavas, or to phlogopite-K-richterite enriched lithospheric mantle. In both cases, the generation of the high-K calc-alkaline magmatism needs the former existence of an important subduction phase to generate its source. The lavas of the Pablo and Garfield Flat formations are similar to calc-alkaline and shoshonitic lavas emitted in post-collisional setting. Post-collisional arc/continent magmatism is varied from intermediate to felsic, calc-alkaline to shoshonitic, low to high-K and meta-aluminous to hyper-aluminous. The studied lavas may be compared to the arc/passive margin collision of Papua-New Guinea, where a post-collisional magmatism characterized by high-K basalts, andesites and shoshonites [McKenzie, 1976]. In Nevada, this post-collisional event develops after the accretion of the Permian Black Dyke island-arc (Type 2), and before the accretion of the intra-oceanic Permo-Triassic arc (Type 1).


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