Abstract. Conversion of natural forest (NF) to other land uses could lead to significant
changes in catchment hydrology, but the nature of these changes has been
insufficiently investigated in tropical montane catchments, especially in
Africa. To address this knowledge gap, we aimed to identify stream water
(RV) sources and flow paths in three tropical montane sub-catchments (27–36 km2)
with different land use (natural forest, NF; smallholder agriculture,
SHA; and commercial tea and tree plantations, TTP) within a 1021 km2 catchment
in the Mau Forest complex, Kenya. Weekly samples were collected from stream
water, precipitation (PC) and mobile soil water for 75 weeks and analysed for
stable isotopes of water (δ2H and δ18O) for mean transit
time (MTT) estimation with two lumped parameter models (gamma model, GM; and exponential
piston flow model, EPM) and for the calculation of the young water fraction.
Weekly samples from stream water and potential endmembers were collected
over a period of 55 weeks and analysed for Li, Na, Mg, K, Rb, Sr and Ba for
endmember mixing analysis (EMMA). Solute concentrations in precipitation were lower
than in stream water in all catchments (p < 0.05), whereas
concentrations in springs, shallow wells and wetlands were generally more
similar to stream water. The stream water isotope signal was considerably
damped compared to the isotope signal in precipitation. Mean transit time
analysis suggested long transit times for stream water (up to 4 years) in the
three sub-catchments, but model efficiencies were very low. The young water
fraction ranged from 13 % in the smallholder agriculture sub-catchment to
15 % in the tea plantation sub-catchment. Mean transit times of mobile
soil water ranged from 3.2–3.3 weeks in forest soils and 4.5–7.9 weeks in
pasture soils at 15 cm depth to 10.4–10.8 weeks in pasture soils at 50 cm
depth. The contribution of springs and wetlands to stream discharge increased
from a median of 16.5 (95 % confidence interval: 11.3–22.9), 2.1
(−3.0–24.2) and 50.2 (30.5–65.5) % during low flow to 20.7
(15.2–34.7), 53.0 (23.0–91.3) and 69.4 (43.0–123.9) % during high flow
in the natural forest, smallholder agriculture and tea plantation
sub-catchments, respectively. Our results indicate that groundwater is an
important component of stream water, irrespective of land use. The results
further suggest that the selected transit time models and tracers might not
be appropriate in tropical catchments with highly damped stream water isotope
signatures. A more in-depth investigation of the discharge dependence of the
young water fraction and transit time estimation using other tracers, such as
tritium, could therefore shed more light on potential land use effects on the
hydrological behaviour of tropical montane catchments.