scholarly journals Three-dimensional Porous Graphene/Polyaniline Hybrids for High Performance Supercapacitor Electrodes

2020 ◽  
Vol 2 (1) ◽  
Author(s):  
Zhaoxia HOU ◽  
Peng SHI ◽  
Shengnan ZOU
Keyword(s):  
High Performance ◽  
Oxidative Polymerization ◽  
Three Dimensional ◽  
Koh Activation ◽  
Nanorod Arrays ◽  
Chemical Oxidative Polymerization ◽  
Porous Graphene ◽  
Initial Capacity ◽  
2D To 3D

Graphene-based composites took extensive attraction as electrodes for supercacitors these years. Three-dimensional cross-linking porous graphene (3D rGO-m) was obtained by KOH activation to graphene modified by 1,2,4-triaminobenzene. 3D porous graphene/ polyaniline hybrids (3D rGO-m/PANI) was prepared by the in-situ chemical oxidative polymerization. The rGO-m are reconstructed from 2D to 3D porous structure after KOH activation. The PANI nanorod arrays are successfully decorated on the surface of the 3D porous graphene sheets. The specific capacitance of the 3D rGO-m/PANI hybrids reach 985 F/g at 0.5 A/g. The capacitance retention of 3D rGO-m/PANI maintains 90% of its initial capacity after 1000 cycles, while rGO-m/PANI only keeps 83% of its initial capacity, the cycling stability of both hybrids are higher than that of pure PANI (69%).

Hierarchical CuO nanorod arrays in situ generated on three-dimensional copper foam via cyclic voltammetry oxidation for high-performance supercapacitors

2018 ◽  
Vol 6 (22) ◽  
pp. 10474-10483 ◽  
Author(s):  
Ying Liu ◽  
Xueying Cao ◽  
Degang Jiang ◽  
Dedong Jia ◽  
Jingquan Liu
Keyword(s):  
Cyclic Voltammetry ◽  
High Performance ◽  
Three Dimensional ◽  
Chemical Oxidation ◽  
Superior Performance ◽  
Nanorod Arrays ◽  
Supercapacitor Electrode ◽  
Copper Foam

A supercapacitor electrode with superior performance based on hierarchical CuO nanorod arrays on copper foam is achieved by successive in situ chemical oxidation, calcination and cyclic voltammetry oxidation strategies.

Zinc Oxide/Polyaniline Transparent Conductive Film Prepared by In Situ Polymerization Deposition

2014 ◽  
Vol 997 ◽  
pp. 368-370
Author(s):  
Ping Zhong ◽  
Lin Xiu Cheng ◽  
Xing Lu
Keyword(s):  
Zinc Oxide ◽  
Oxidative Polymerization ◽  
Optimal Conditions ◽  
Chemical Oxidative Polymerization ◽  
Reaction Conditions ◽  
Transparent Conductive Film ◽  
Conductive Film

In this paper，ZnO/PANI transparent conductive film has been prepared by in situ chemical oxidative polymerization, APS as an oxidant. The conductivity and transmittance of ZnO/PANI was measured. It has been investigated of the effects of reaction conditions and the doping component on conductivity, transmissivity and adhesion. With the increase of doping ZnO, the conductivity of ZnO/PANI transparent conductive film, transmittance and adhesion reduced. The optimal conditions is that the concentration of An, APS and PVA are 0.75 mol / L, 0.8 mol / L and 0.5wt%, respectively.

Fabrication of nitrogen-doped hierarchical porous carbons from Sargassum as advanced electrode materials for supercapacitors

2021 ◽  
Author(s):  
Feiqiang Guo ◽  
Yinbo Zhan ◽  
Xiaopeng Jia ◽  
Huiming Zhou ◽  
Shuang Liang ◽  
...  
Keyword(s):  
High Performance ◽  
Nitrogen Doping ◽  
Electrode Materials ◽  
Three Dimensional ◽  
Koh Activation ◽  
Porous Carbons ◽  
Nitrogen Doped ◽  
Novel Approach ◽  
Hierarchical Porous ◽  
Hierarchical Porous Carbons

Using Sargassum as the precursor, a novel approach was developed to synthesize three-dimensional porous carbons as high-performance electrode materials for supercapacitors via KOH activation and subsequent nitrogen-doping employing melamine as...

scholarly journals Synthesis and Physical Characterization of Carbon Nanotubes Coated by Conducting Polypyrrole

2011 ◽  
Vol 364 ◽  
pp. 50-54 ◽  
Author(s):  
Afarin Bahrami ◽  
Z.A. Talib ◽  
W. Mahmood Mat Yunus ◽  
Kasra Behzad ◽  
Nayereh Soltani
Keyword(s):  
Carbon Nanotubes ◽  
Oxidative Polymerization ◽  
Feed Ratio ◽  
Multiwall Carbon Nanotube ◽  
Chemical Oxidative Polymerization ◽  
Conducting Polypyrrole ◽  
Multiwall Carbon ◽  
Thermal Stability Of

This study describes the preparation of polypyrrole multiwall carbon nanotube (PPy/MWNT) composites by in situ chemical oxidative polymerization. Various ratios of functionalized MWNTs are dispersed in the water, and PPy are then synthesized via in-situ chemical oxidative polymerization on the surface of the carbon nanotubes. The morphology of the resulting complex nanotubes (MWNT-PPY) was characterized by field-emission scanning electron microscopy (FESEM). The conductivity of each composite showed a maximum in the temperature scale of 120 – 160 °C and then decreased dramatically with the increase of temperature. The resultant PPy/MWNT nanotubes enhanced electrical conductivity and thermal stability of nanocomposite compared to PPy which was strongly influenced by the feed ratio of pyrrole to MWNTs.

Applying multi-scale silica-like three-dimensional networks in PEO matrix via in-situ crosslinking for high-performance solid composite electrolyte

2021 ◽  
Author(s):  
Jiawei Wu ◽  
Jing Chen ◽  
Xiaodong Wang ◽  
An'an Zhou ◽  
Zhenglong Yang
Keyword(s):  
Solid State ◽  
High Performance ◽  
Low Cost ◽  
Three Dimensional ◽  
Electrochemical Stability ◽  
Composite Electrolyte ◽  
Solid State Electrolyte ◽  
Multi Scale ◽  
In Situ Crosslinking

For the higher safety and energy density, solid-state electrolyte with better mechanical strength, thermal and electrochemical stability is a perfect choice. To improve the performance of PEO, usage of low-cost...

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