scholarly journals 4D Printing of Lead Zirconate Titanate Piezoelectric Composites Transducer Based on Direct Ink Writing

2021 ◽  
Vol 8 ◽  
Author(s):  
Kai Liu ◽  
Qingqing Zhang ◽  
Chenyang Zhou ◽  
Yusheng Shi ◽  
Ce Sun ◽  
...  

Lead zirconate titanate (PZT) piezoelectric composites used in transducers were fabricated via direct ink writing (DIW) combined with furnace sintering and resin impregnation. A ceramic slurry with a volume fraction of 52 vol% and suitable viscoelasticity was prepared. After post-process, the PZT ceramic specimens showed a nanoscale grain size with a density of 7.63 g/cm3, accounting for 97.8% of the theoretical density. The effects of different printing rod spacing on the electrical properties of composites were evaluated and lucubrated. Finally, an underwater acoustic transducer was assembled by using the PZT piezoelectric composites fabricated by the above method. The electrical signal generated by the underwater acoustic transducer changed autonomously with the acoustic stimulation, which indicated the application mode of 4D printing in functional devices in the future.

2008 ◽  
Vol 17 (11) ◽  
pp. 4323-4327 ◽  
Author(s):  
Lin Hai-Bo ◽  
Cao Mao-Sheng ◽  
Yuan Jie ◽  
Wang Da-Wei ◽  
Zhao Quan-Liang ◽  
...  

2017 ◽  
Vol 52 (9) ◽  
pp. 1171-1182 ◽  
Author(s):  
Abdelkader Rjafallah ◽  
Abdelowahed Hajjaji ◽  
Fouad Belhora ◽  
Daniel Guyomar ◽  
Laurence Seveyrat ◽  
...  

The microelectromechanical systems invade gradually the market with applications in many sectors of activity. Developing these micro-systems allows deploying wireless sensor networks that are useful to collect, process and transmit information from their environments without human intervention. In order to keep these micro-devices energetically autonomous without using batteries because they have a limited lifespan, an energy harvesting from ambient vibrations using electrostrictive polymers can be used. These polymers present best features against inorganic materials, as flexibility and low cost. The aims of this paper are manifold. First of all, we made elaboration of the polyurethane/lead zirconate titanate films of 100 µm thickness using a lead zirconate titanate–volume fraction of [Formula: see text]%. Therefore, we did an observation of the lead zirconate titanate grains dispersion and the electrical characterization of the polyurethane–50 vol% lead zirconate titanate composites. Finally, a detailed study of the electromechanical transduction, for the polyurethane–50 vol% lead zirconate titanate unpolarized and polarized composites sustained to the sinusoidal mechanical strain with amplitude of 1.5% and at very low frequencies ( f = 2 [Hz] and f = 4 [Hz]) and static electric field ( Edc = 10 [ V/µm]) or without it ( Edc = 0 [ V/µm]) has been presented.


2018 ◽  
Vol 53 (3) ◽  
pp. 345-352 ◽  
Author(s):  
R Farhan ◽  
M Rguiti ◽  
A Eddiai ◽  
M Mazroui ◽  
M Meddad ◽  
...  

By means of experimental tools, we have studied the effect of lead zirconate titanate volume fraction introduced in polyamide-6/lead zirconate titanate composites on dielectric, piezoelectric, mechanical, and structural properties. As the first result, we found that the insertion of lead zirconate titanate particles makes the dielectric permittivity of the polyamide-6 matrix increases from 10 to 95.8. The dielectric property studies reveal that under an electrical field of 1 kV the remnant polarization is also increased from 0.17 to 0.4, this behavior is related to both the increase of volume fraction of lead zirconate titanate from 20% to 40% and the piezoelectric coefficient changes proportionally with that of volume fraction of lead zirconate titanate. Furthermore, piezoelectric activity increases with lead zirconate titanate particle size at a range where there is a lower order of magnitude. Finally, the uniform dispersion of the ceramic lead zirconate titanate particles in polyamide matrix has been confirmed by scanning electron microscopy analysis. The performances reached by polyamide-6/lead zirconate titanate composites open new horizons for energy harvesting and actuators.


2002 ◽  
Vol 736 ◽  
Author(s):  
Farhad Mohammadi ◽  
Ajmal Khan ◽  
Richard B. Cass

ABSTRACTPower generation from lead zirconate titanate (PZT) piezoelectric fibers in the form of 1–3 composites under application of an external force was investigated. Green fibers consisting of PZT powder dispersed in a cellulose binder were made by the Viscous Suspension Spinning Process (VSSP). The composites were made by firing sheets of parallel green PZT fibers at 1270 °C, and then laminating the sintered sheets in epoxy. Composites of several PZT fiber diameters (15, 45, 120, and 250 μm), with the fiber volume fraction fixed at ∼0.4, were investigated. Transducers comprised of electrode and poled plates of the composites, in which the plate thickness direction was in the fiber axis direction, were made. Power generation experiments were conducted by dropping a 33 g stainless steel ball onto the electroded face of each transducer from a height of 10 cm and recording the output voltage on an oscilloscope. A peak voltage of 350 V corresponding to 120 mW of peak power was obtained. The output voltage and power was the highest for the transducers made with the smallest diameter fibers (15μm) and increased with increasing of transducer thickness. The average piezoelectric coefficient, d33, of the transducers was about 300 pC/N and decreased with decreasing transducer thickness. In this paper, the power generation capability and dielectric properties of the laminated 1–3 fiber composites are discussed.


Author(s):  
Can Yang ◽  
Xiao-Hong Yin ◽  
Shiju E ◽  
Junwu Kan ◽  
Zhonghua Zhang ◽  
...  

In the present work, novelly structured poly(vinylidene fluoride)/lead zirconate titanate (PVDF/PZT) piezoelectric composites with controlled filler orientation were designed. The material coefficients of the proposed composites including elastic stiffness constant (C), piezoelectric constant (e) and dielectric constant (ε) were numerically determined. Specifically, the Comsol Multiphysics connected with Matlab was utilized to create the unit cells representing the piezoelectric composites. In the calculations, the whisker-shaped PZT content was varied in a relatively low range of volume fraction (i.e., 0.3∼3.5 vol.%). Furthermore, the PZT orientation and PZT length-reduction were considered in order to simulate the flow-field effect of micro-injection molding (μIM). The results showed that using a low PZT content was effective for modifying the composite’s material coefficients. In addition, the PZT orientation was identified as an important factor influencing the composite’s properties, which was believed to result from the apparently changed amount of the PZT whiskers along the direction of interest. Finally, the effect of the PZT length-reduction during μIM was found insignificant, which suggests that μIM can be safely adopted to fabricate PVDF/PZT piezoelectric composites taking full use of its advantages such as high efficiency and low cost, without worrying about PZT’s length-reduction.


Author(s):  
S. Banerjee ◽  
K. A. Cook-Chennault

Two-phase PZT-epoxy piezoelectric composites and three phase PZT-epoxy-Al composites were fabricated using a poling voltage of 0.2 kV/mm. The influence of aluminum inclusion size (nano and micron) and (lead zirconate titanate) PZT volume fraction on the dielectric properties of the three phase PZT-epoxy-aluminum composites were experimentally investigated. In general, dielectric and piezoelectric properties of the PZT-epoxy matrix were improved with the addition of aluminum particles. Composites that were comprised of micron scale aluminum inclusions demonstrated higher piezoelectric d33-strain-coefficients, and higher dielectric loss compared to composites that were comprised of nanosize aluminum inclusions. Specifically, composites comprised of micron sized aluminum particles and PZT volume fractions of 20%, 30%, and 40% had dielectric constants equal to 405.7, 661.4, and 727.8 (pC/N), respectively, while composites comprised of nanosize aluminum particles with the same PZT volume fractions, had dielectric constants equal to 233.28, 568.81, and 657.41 (pC/N), respectively. The electromechanical properties of the composites are influenced by several factors: inclusion agglomeration, contact resistance between particles, and air voids. These composites may be useful for several applications: structural health monitoring, energy harvesting, and acoustic liners.


Author(s):  
M.L.A. Dass ◽  
T.A. Bielicki ◽  
G. Thomas ◽  
T. Yamamoto ◽  
K. Okazaki

Lead zirconate titanate, Pb(Zr,Ti)O3 (PZT), ceramics are ferroelectrics formed as solid solutions between ferroelectric PbTiO3 and ant iferroelectric PbZrO3. The subsolidus phase diagram is shown in figure 1. PZT transforms between the Ti-rich tetragonal (T) and the Zr-rich rhombohedral (R) phases at a composition which is nearly independent of temperature. This phenomenon is called morphotropism, and the boundary between the two phases is known as the morphotropic phase boundary (MPB). The excellent piezoelectric and dielectric properties occurring at this composition are believed to.be due to the coexistence of T and R phases, which results in easy poling (i.e. orientation of individual grain polarizations in the direction of an applied electric field). However, there is little direct proof of the coexistence of the two phases at the MPB, possibly because of the difficulty of distinguishing between them. In this investigation a CBD method was found which would successfully differentiate between the phases, and this was applied to confirm the coexistence of the two phases.


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