Porous, multi-layered piezoelectric composites based on highly oriented PZT/PVDF electrospinning fibers for high-performance piezoelectric nanogenerators

Piezoelectric nanogenerators (PENGs) that can harvest mechanical energy from ambient environment have broad prospects for multi-functional applications. Here, multi-layered piezoelectric composites with a porous structure based on highly oriented Pb(Zr0.52Ti0.48)O3/PVDF (PZT/PVDF) electrospinning fibers are prepared via a laminating method to construct high-performance PENGs. PZT particles as piezoelectric reinforcing phases are embedded in PVDF fibers and facilitate the formation of polar β phase in PVDF. The multi-layered, porous structure effectively promotes the overall polarization and surface bound charge density, resulting in a highly efficient electromechanical conversion. The PENG based on 10 wt% PZT/PVDF composite fibers with a 220 µm film thickness outputs an optimal voltage of 62.0 V and a power of 136.9 µW, which are 3.4 and 6.5 times those of 10 wt% PZT/PVDF casting film-based PENG, respectively. Importantly, the PENG shows a high sensitivity of 12.4 V·N−1, presenting a significant advantage in comparison to PENGs with other porous structures. In addition, the composites show excellent flexibility with a Young’s modulus of 227.2 MPa and an elongation of 262.3%. This study shows a great potential application of piezoelectric fiber composites in flexible energy harvesting devices.

Direct ink write multi-material printing of PDMS-BTO composites with MWCNT electrodes for flexible force sensors

With recent advances of additive manufacturing (AM) technology, direct ink write (DIW) printing has allowed to incorporate multi-material printing of various materials with freedom of design and complex geometric shapes to complete functional sensors in a one-step fabrication. This paper introduces the use of DIW 3D printing of polydimethylsiloxane (PDMS) with barium titanate (BTO) filler as stretchable composites with tunable piezoelectric properties that can be used for force sensors applications. To improve the bonding between stretchable piezoelectric composites and electrodes, multi-walled carbon nanotubes (MWCNT) was included in the fabrication of electrodes at a fixed ratio of 11 wt. %. The alignment of the BTO dipoles was achieved through corona poling method, which applies an electric charge on the surface layer of the functional material, aligning the dipoles in the desired direction and thus gaining the piezoelectricity. Different BTO mixing ratios (10-50 wt. %) were evaluated in order to obtain tunable piezoelectric properties and compare the sensitivity with respect their elastic properties. Tensile testing and piezoelectric testing were carried out to characterize mechanical and piezoelectric properties. Results showed that fabricated PDMS with 50 wt. % BTO gave the highest piezoelectric coefficient (d33) of 11.5 pC/N and with an output voltage of 385 mV under compression loading of >200 lbF. This demonstrates feasibility of using multi-material DIW printing to fabricate piezoelectric force sensors with integrated electrodes in one-step without compromising the flexibility of the material.

Dynamic Response of Electro-Mechanical Properties of Cement-Based Piezoelectric Composites

By employing ordinary Portland cement as a matrix and PZT-5H piezoelectric ceramic as the functional body, 1-3 and 2-2 cement-based piezoelectric composites were prepared. Quasi-static compression tests were performed along with dynamic impact loading tests to study the electro-mechanical response characteristics of 1-3 and 2-2 cement-based piezoelectric composites. The research results show that both composites exhibit strain rate effects under quasi-static compression and dynamic impact loading since they are strain-rate sensitive materials. The sensitivity of the two composites has a non-linear mutation point: in the quasi-static state, the sensitivity of 1-3 and 2-2 composites is 157 and 169 pC/N, respectively; in the dynamic state, the respective sensitivity is 323 and 296 pC/N. Although the sensitivity difference is not significant, the linear range of the 2-2 composite is 24.8% and 61.3% larger than that of the 1-3 composite under quasi-static compression and dynamic impact loading, respectively. Accordingly, the 2-2 composite exhibits certain advantages as a sensor material, irrespective of whether it is subjected to quasi-static or dynamic loading.

Design of Planar Array Transducers Based on Connected 1–3 Piezoelectric Composites

To improve the transmission performance and preparation of a transducer array, two planar array transducers based on connected 1–3 piezoelectric composites as a matrix were designed. Each transducer contained 25 array elements with a gap of 1 mm between them. The length, width and height of each array element were 1 mm, 26 mm and 5 mm, respectively. Two kinds of array transducers were tested through finite element simulation and experiments. The array transducer prototype was fabricated based on two kinds of composite materials, and the fabrication cycle was short. Our results show that the maximum transmission voltage response of the two-phase 1–3 full array driver is up to 179 dB at 200–400 kHz and the acoustic radiation intensity can be increased by up to 22% compared with the traditional splicing transducer array. It is suitable for short-range target positioning and measurement. Moreover, in the single element mode, the beam of the three-phase 1–3 transducer has no sidelobe and a single element −3 dB beam width of up to 91°. Furthermore, the beam width of the two-phase 1–3 type is 54°, and the acoustic radiation breadth is improved by 40.6%. The three-phase 1–3 type array transducer has the characteristics of concentrated acoustic transmission energy of the whole array, and its −3 dB beam width is 3.5°. The beam width decreased by 12.5%, indicating that the three-phase 1–3 type transducer is suitable for short-range target detection and perception. The two array transducers have their own advantages in transmitting the voltage response and beam width, which must be selected on the basis of the requirements of practical applications.