scholarly journals Reverse Coarsening and the Control of Particle Size Distribution through Surfactant

2020 ◽  
Vol 10 (15) ◽  
pp. 5359
Author(s):  
Victor M. Burlakov ◽  
Alain Goriely

The minimization of surface area, as a result of the minimization of (positive) surface energy, is a well-known driving force behind the spontaneous broadening of (nano) particle size distribution. We show that surfactant molecules binding to particle surfaces effectively decrease the surface energy and may change its sign. In this case, contrary to the expected broadening behavior, a minimum of free energy is achieved at the maximum surface area for all particles, i.e., when the particles are identical. Numerical simulations based on the classical Lifshitz–Slyozov–Wagner theory with surfactant-induced surface energy renormalization confirm the collapse of the particle size distribution. As the particle size evolution is much slower than particle nucleation and growth, the manipulation of surface energy with in-situ replacement of surfactant molecules provides a method for controlling particle size distribution with great potential for creating mono-disperse nanoparticles, a key goal of nanotechnology.

2003 ◽  
Vol 42 (22) ◽  
pp. 5568-5575 ◽  
Author(s):  
Jun Yang ◽  
Ting-Jie Wang ◽  
Hong He ◽  
Fei Wei ◽  
Yong Jin

JOM ◽  
2019 ◽  
Vol 71 (11) ◽  
pp. 4050-4058 ◽  
Author(s):  
Swapnil Morankar ◽  
Monalisa Mandal ◽  
Nadia Kourra ◽  
Mark A. Williams ◽  
Rahul Mitra ◽  
...  

Processes ◽  
2019 ◽  
Vol 7 (6) ◽  
pp. 381 ◽  
Author(s):  
Johann Landauer ◽  
Petra Foerst

Triboelectric charging is a potentially suitable tool for separating fine dry powders, but the charging process is not yet completely understood. Although physical descriptions of triboelectric charging have been proposed, these proposals generally assume the standard conditions of particles and surfaces without considering dispersity. To better understand the influence of particle charge on particle size distribution, we determined the in situ particle size in a protein–starch mixture injected into a separation chamber. The particle size distribution of the mixture was determined near the electrodes at different distances from the separation chamber inlet. The particle size decreased along both electrodes, indicating a higher protein than starch content near the electrodes. Moreover, the height distribution of the powder deposition and protein content along the electrodes were determined in further experiments, and the minimum charge of a particle that ensures its separation in a given region of the separation chamber was determined in a computational fluid dynamics simulation. According to the results, the charge on the particles is distributed and apparently independent of particle size.


2002 ◽  
Vol 36 (1) ◽  
pp. 59-69 ◽  
Author(s):  
Teresa Serra ◽  
Xavier Casamitjana ◽  
Jordi Colomer ◽  
Timothy C. Granata

An in situ laser particle size analyzer (LISST-100, Sequoia Scientific, Inc.) has been used to study the particle size distribution and concentration of biological and non biological particles in the water column of a Mediterranean coastal system. Two field campaigns have been carried out during low and high energy conditions of the flow, caused by the passage of a storm front. For the low energy period, the water column remained stratified, whereas for the high energetic period the water column was warmer and well mixed. The first study dealt with the distribution of particles near the bottom of the coastal area. Here, two regions were taken into account. The first region was a sea-grass meadow of Posidonia oceanica and the second region was a barren sand area. The second study dealt with the determination of the vertical distribution of suspended particles in the whole water column of the system. The results showed a decrease in the vertical concentration of suspended particles in the water column with the passage of the storm front, which was associated with advection of warm water mass rather than by vertical mixing. In contrast, vertical resuspension determined the fate of suspended particles at the bottom of the water column and an increase of their concentration was found.


2015 ◽  
Vol 54 (20) ◽  
pp. 6367 ◽  
Author(s):  
Yuanzhi Zhang ◽  
Zhaojun Huang ◽  
Chuqun Chen ◽  
Yijun He ◽  
Tingchen Jiang

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