scholarly journals Nucleation Triggering of Highly Undercooled Xylitol Using an Air Lift Reactor for Seasonal Thermal Energy Storage

2019 ◽  
Vol 9 (2) ◽  
pp. 267 ◽  
Author(s):  
Marie Duquesne ◽  
Elena Palomo Del Barrio ◽  
Alexandre Godin
Keyword(s):  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
High Energy ◽  
Operating Conditions ◽  
High Energy Density ◽  
Bubble Generation ◽  
Spontaneous Nucleation ◽  
Air Lift Reactor ◽  
Air Lift

Bio-based glass-forming materials are now considered for thermal energy storage in building applications. Among them, Xylitol appears as a biosourced seasonal thermal energy storage material with high potential. It has a high energy density and a high and stable undercooling, thus allowing storing solar energy at ambient temperature and reducing thermal losses and the risk of spontaneous nucleation (i.e., the risk of losing the stored energy). Generally when the energy is needed, the discharge triggering of the storage system is very difficult as well as reaching a sufficient power delivery. Both are indeed the main obstacles for the use of pure Xylitol in seasonal energy storage. Different techniques have been hence considered to crystallize highly undercooled Xylitol. Nucleation triggering of highly undercooled pure Xylitol by using an air lift reactor has been proven here. This method should allow reaching performances matching with building applications (i.e., at medium temperatures, below 100 °C). The advantages of this technique compared to other existing techniques to activate the crystallization are discussed. The mechanisms triggering the nucleation are investigated. The air bubble generation, transportation of nucleation sites and subsequent crystallization are discussed to improve the air injection operating conditions.

scholarly journals Nucleation Triggering of Highly Undercooled Xylitol Using an Air Lift Reactor for Seasonal Thermal Energy Storage

2018 ◽  
Author(s):  
Marie DUQUESNE ◽  
Elena PALOMO DEL BARRIO ◽  
Alexandre GODIN
Keyword(s):  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
High Energy ◽  
Operating Conditions ◽  
High Energy Density ◽  
Bubble Generation ◽  
Spontaneous Nucleation ◽  
Air Lift Reactor ◽  
Air Lift

Xylitol is an organic, non-toxic, biosourced phase change material with high potential for seasonal thermal energy storage material. It has a high energy density, a high and stable undercooling allowing storing solar energy at ambient temperature thus, reducing thermal losses and the risk of spontaneous nucleation (i.e., the risk of losing the stored energy). When the energy is needed, the discharge triggering of the storage system (i.e., Nucleation triggering of highly viscous undercooled Xylitol) is very difficult as well as reaching a sufficient power delivery (i.e., the control of the subsequent crystal growth rates). Both are the mains locks for the use of Xylitol in seasonal energy storage. Different techniques to crystallize highly undercooled Xylitol have hence been considered. It has been proven that nucleation triggering of highly undercooled Xylitol using an air lift reactor would allow reaching performances matching with building applications (i.e., at medium temperatures, below 100 °C). The advantages of this technique compared to other existing techniques to activate the crystallization are discussed. The mechanisms triggering the nucleation are investigated. The air bubble generation, transportation of nucleation sites and subsequent crystallization are discussed to improve the air injection operating conditions.

scholarly journals Nucleation Triggering of Highly Undercooled Xylitol Using an Air Lift Reactor for Seasonal Thermal Energy Storage

2019 ◽  
Author(s):  
Marie Duquesne ◽  
Elena Palomo Del Barrio ◽  
Alexandre Godin
Keyword(s):  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
High Energy ◽  
Operating Conditions ◽  
High Energy Density ◽  
Bubble Generation ◽  
Spontaneous Nucleation ◽  
Air Lift Reactor ◽  
Air Lift

Bio-based glass-forming materials are now considered for thermal energy storage in building applications. Among them, Xylitol appears as a biosourced seasonal thermal energy storage material with high potential. It has a high energy density, a high and stable undercooling allowing storing solar energy at ambient temperature thus, reducing thermal losses and the risk of spontaneous nucleation (i.e., the risk of losing the stored energy). Generally when the energy is needed, the discharge triggering of the storage system is very difficult as well as reaching a sufficient power delivery. Both are indeed the mains locks for the use of pure Xylitol in seasonal energy storage. Different techniques have been hence considered to crystallize highly undercooled Xylitol. Nucleation triggering of highly undercooled pure Xylitol by using an air lift reactor has been proven here. This method should allow reaching performances matching with building applications (i.e., at medium temperatures, below 100 °C). The advantages of this technique compared to other existing techniques to activate the crystallization are discussed. The mechanisms triggering the nucleation are investigated. The air bubble generation, transportation of nucleation sites and subsequent crystallization are discussed to improve the air injection operating conditions.

Towards High Energy Density, High Conductivity Thermal Energy Storage Composites

2012 ◽  
Author(s):  
Patrick J. Shamberger ◽  
Daniel E. Forero
Keyword(s):  
Thermal Conductivity ◽  
Energy Storage ◽  
Energy Density ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Nitrate ◽  
Nitrate Trihydrate ◽  
Graphitic Foam

Thermal energy storage (TES) materials absorb transient pulses of heat, allowing for rapid storage of low-quality thermal energy for later use, and effective temperature regulation as part of a thermal management system. This paper describes recent development of salt hydrate-based TES composites at the Air Force Research Laboratory. Salt hydrates are known to be susceptible to undercooling and chemical segregation, and their bulk thermal conductivities remain too low for rapid heat transfer. Here, we discuss recent progress towards solving these challenges in the composite system lithium nitrate trihydrate/graphitic foam. This system takes advantage of both the high volumetric thermal energy storage density of lithium nitrate trihydrate and the high thermal conductivity of graphitic foams. We demonstrate a new stable nucleation agent specific to lithium nitrate trihydrate which decreases undercooling by up to ∼70% relative to previously described nucleation agents. Furthermore, we demonstrate the compatibility of lithium nitrate trihydrate and graphitic foam with the addition of a commercial nonionic silicone polyether surfactant. Finally, we show that thermal conductivity across water-graphite interfaces is optimized by tuning the surfactant concentration. These advances demonstrate a promising route to synthesizing high energy density, high thermal conductivity TES composites.

scholarly journals Solvothermal method as a green chemistry solution for micro-encapsulation of phase change materials for high temperature thermal energy storage

2018 ◽  
Vol 5 ◽  
pp. 4 ◽  
Author(s):  
Albert Ioan Tudor ◽  
Adrian Mihail Motoc ◽  
Cristina Florentina Ciobota ◽  
Dan. Nastase Ciobota ◽  
Radu Robert Piticescu ◽  
...  
Keyword(s):  
High Temperature ◽  
Energy Storage ◽  
Phase Change ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Phase Change Materials ◽  
Solvothermal Method ◽  
High Energy ◽  
High Energy Density ◽  
Latent Heat Storage

Thermal energy storage systems using phase change materials (PCMs) as latent heat storage are one of the main challenges at European level in improving the performances and efficiency of concentrated solar power energy generation due to their high energy density. PCM with high working temperatures in the temperature range 300–500 °C are required for these purposes. However their use is still limited due to the problems raised by the corrosion of the majority of high temperature PCMs and lower thermal transfer properties. Micro-encapsulation was proposed as one method to overcome these problems. Different micro-encapsulation methods proposed in the literature are presented and discussed. An original process for the micro-encapsulation of potassium nitrate as PCM in inorganic zinc oxide shells based on a solvothermal method followed by spray drying to produce microcapsules with controlled phase composition and distribution is proposed and their transformation temperatures and enthalpies measured by differential scanning calorimetry are presented.

Thermal Energy Storage Through Melting of a Commercial Phase Change Material in an Annulus with Radially Divergent Longitudinal Fins

2020 ◽  
Vol 7 (1) ◽  
Author(s):  
Tonny Tabassum Mainul Hasan ◽  
Latifa Begum
Keyword(s):  
Energy Storage ◽  
Phase Change ◽  
Phase Change Material ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Storage System ◽  
Operating Conditions ◽  
Melting Time ◽  
Bottom Part ◽  
Change Material

This study reports on the unsteady two-dimensional numerical investigations of melting of a paraffin wax (phase change material, PCM) which melts over a temperature range of 8.7oC. The PCM is placed inside a circular concentric horizontal-finned annulus for the storage of thermal energy. The inner tube is fitted with three radially diverging longitudinal fins strategically placed near the bottom part of the annulus to accelerate the melting process there. The developed CFD code used in Tabassum et al., 2018 is extended to incorporate the presence of fins. The numerical results show that the average Nusselt number over the inner tube surface, the total melt fraction, the total stored energy all increased at every time instant in the finned annulus compared to the annulus without fins. This is due to the fact that in the finned annulus, the fins at the lower part of the annulus promotes buoyancy-driven convection as opposed to the slow conduction melting that prevails at the bottom part of the plain annulus. Fins with two different heights have been considered. It is found that by extending the height of the fin to 50% of the annular gap about 33.05% more energy could be stored compared to the bare annulus at the melting time of 82.37 min for the identical operating conditions. The effects of fins with different heights on the temperature and streamfunction distributions are found to be different. The present study can provide some useful guidelines for achieving a better thermal energy storage system.

Numerical Analysis of Latent Thermal Energy Storage System With Embedded Thermosyphons

2012 ◽  
Author(s):  
Karthik Nithyanandam ◽  
Ranga Pitchumani
Keyword(s):  
Thermal Conductivity ◽  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Solar Power ◽  
Storage System ◽  
High Energy ◽  
Concentrating Solar Power ◽  
Discharge Performance ◽  
Low Thermal Conductivity

Latent thermal energy storage (LTES) system offers high energy storage density and nearly isothermal operation for concentrating solar power generation. However, the low thermal conductivity possessed by the phase change material (PCM) used in LTES system limits the heat transfer rates. Utilizing thermosyphons to charge or discharge a LTES system offers a promising engineering solution to compensate for the low thermal conductivity of the PCM. The present work numerically investigates the enhancement in the thermal performance of charging and discharging process of LTES system by embedding thermosyphons. A transient, computational analysis of the LTES system with embedded thermosyphons is performed for both charging and discharging cycles. The influence of the design configuration of the system and the arrangement of the thermosyphons on the charge and discharge performance of the LTES installed in a concentrating solar power plant (CSP) is analyzed to identify configurations that lead to improved effectiveness.

Thermal Analysis of Elemental Sulfur in a Shell-and-Tube Configuration for Thermal Energy Storage Applications

2016 ◽  
Author(s):  
Mitchell Shinn ◽  
Karthik Nithyanandam ◽  
Amey Barde ◽  
Richard Wirz
Keyword(s):  
Heat Transfer ◽  
High Temperature ◽  
Energy Storage ◽  
Numerical Model ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Elemental Sulfur ◽  
Low Cost ◽  
High Energy ◽  
Shell And Tube

Currently, concentrated solar power (CSP) plants utilize thermal energy storage (TES) in order to store excess energy so that it can later be dispatched during periods of intermittency or during times of high energy demand. Elemental sulfur is a promising candidate storage fluid for high temperature TES systems due to its high thermal mass, moderate vapor pressure, high thermal stability, and low cost. The objective of this paper is to investigate the behavior of encapsulated sulfur in a shell and tube configuration. An experimentally validated, transient, two-dimensional numerical model of the shell and tube TES system is presented. Initial results from both experimental and numerical analysis show high heat transfer performance of sulfur. The numerical model is then used to analyze the dynamic response of the elemental sulfur based TES system for multiple charging and discharging cycles. A sensitivity analysis is performed to analyze the effect of geometry (system length), cutoff temperature, and heat transfer fluid on the overall utilization of energy stored within this system. Overall, this paper demonstrates a systematic parametric study of a novel low cost, high performance TES system based on elemental sulfur as the storage fluid that can be utilized for different high temperature applications.

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