scholarly journals Removal of Rhodamine B (A Basic Dye) and Acid Yellow 17 (An Acidic Dye) from Aqueous Solutions by Ordered Mesoporous Carbon and Commercial Activated Carbon

2019 ◽  
Vol 3 (1) ◽  
pp. 30 ◽  
Author(s):  
Katarzyna Jedynak ◽  
Dariusz Wideł ◽  
Nina Rędzia
Keyword(s):  
Activated Carbon ◽  
Adsorption Isotherm ◽  
Rhodamine B ◽  
Mesoporous Carbon ◽  
Nitrogen Adsorption ◽  
Ordered Mesoporous Carbon ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Templating Method ◽  
Ordered Mesoporous

In this work, adsorption of rhodamine B (RB) and acid yellow 17 (AY17) was investigated on ordered mesoporous carbon material obtained by soft-templating method with hydrochloric acid (ST-A). For comparison, the adsorption process on commercial activated carbon CWZ-22 was also carried out. The sorbents were characterized by nitrogen adsorption/desorption isotherms and scanning electron microscopy. Langmuir and Freundlich adsorption isotherm models were applied to simulate the equilibrium data of RB and AY17. Adsorption isotherm data could be better described by the Langmuir model than the Freundlich model. The adsorption kinetics of RB and AY17 on studied carbons could be well depicted by using pseudo-second-order kinetic modeling. The adsorption capacity increased with temperature increase in the range of 298–315 K. In the whole diffusion process, the intraparticle diffusion was involved, but not the whole rate-controlling step. The calculated thermodynamic parameters, including Gibbs free energy (∆G), enthalpy (∆H), and entropy (ΔS) suggested that adsorption processes of RB and AY17 on ST-A and CWZ-22 were endothermic and spontaneous.

N-Doped ordered mesoporous carbon grafted onto activated carbon fibre composites with enhanced activity for the electro-Fenton degradation of Brilliant Red X3B dye

RSC Advances ◽  
2014 ◽  
Vol 4 (104) ◽  
pp. 60168-60175 ◽  
Author(s):  
Qiaoli Peng ◽  
Zehui Zhang ◽  
Ze'ai Huang ◽  
Wei Ren ◽  
Jie Sun
Keyword(s):  
Activated Carbon ◽  
Mesoporous Carbon ◽  
Ordered Mesoporous Carbon ◽  
Carbon Composites ◽  
Carbon Fibres ◽  
Ordered Mesoporous ◽  
Fibre Composites ◽  
Activated Carbon Fibres ◽  
Carbon Fibre Composites ◽  
Activated Carbon Fibre

N-Doped ordered mesoporous carbon (N-OMC) was successfully prepared using dicyandiamide (C2H4N4) as the nitrogen source and was grafted onto activated carbon fibres (ACFs) to form carbon composites (ACF@N-OMC).

ELECTROCHEMICAL PERFORMANCE OF ORDERED MESOPOROUS CARBON MODIFIED BY OXIDATIVE TREATMENT WITH AQUEOUS NITRIC ACID

2016 ◽  
Vol 78 (3-2) ◽  
Author(s):  
Nur Izzatie Hannah Razman ◽  
Salasiah Endud ◽  
Izan Izwan Misnon ◽  
Zainab Ramli
Keyword(s):  
Electron Microscopy ◽  
Nitric Acid ◽  
Electrochemical Performance ◽  
Mesoporous Carbon ◽  
Nitrogen Adsorption ◽  
Ordered Mesoporous Carbon ◽  
Replication Process ◽  
Oxidative Treatment ◽  
Ordered Mesoporous ◽  
Aqueous Nitric Acid

In this study, ordered mesoporous carbon (OMC) was prepared via nano-casting method by using Santa Barbara Amorphous (SBA)-15 as a template and sucrose as a carbon precursor. The OMC was subsequently oxidized with aqueous nitric acid and referred as MOMC. The physicochemical properties of OMC and MOMC were determined using nitrogen adsorption–desorption analyser, field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and Fourier transform infrared spectroscopy (FT-IR). The results proved that the carbon replication process was successful. The electrochemical performance tests were carried out using cyclic voltammetry (CV) and galvanostatic charge–discharge (GCD) in 1 M KOH electrolyte for 1000 cycles. After oxidative treatment, the specific surface area and pore volume of OMC decreased but the specific capacitance of the electrode material has significantly increased from 117      F g–1 to 344 F g–1 at a scan rate of 10 mV s–1.   

Ordered Mesoporous Carbon Nano Spheres as Electrode Material for Supercapacitors

2013 ◽  
Vol 320 ◽  
pp. 661-664
Author(s):  
Hai Jing Zhao ◽  
Dong Lin Zhao ◽  
Ji Ming Zhang ◽  
Dong Dong Zhang
Keyword(s):  
Mesoporous Carbon ◽  
Electrode Materials ◽  
Rate Capability ◽  
Nitrogen Adsorption ◽  
Ordered Mesoporous Carbon ◽  
Electrochemical Performances ◽  
Carbon Nanospheres ◽  
Electrochemical Testing ◽  
Ordered Mesoporous ◽  
Coating Method

Ordered mesoporous carbon nanospheres with uniformly penetrating channels have been successfully synthesized by a nanocasting method using mesoporous silica as a template. The ordered mesoporous carbon nanospheres were investigated as electrode materials for supercapacitors via high-resolution transmission electron microscopy, nitrogen adsorption and desorption isotherms and a variety of electrochemical testing techniques. The electrodes with ordered mesoporous carbon nanospheres prepared by coating method exhibited good rate capability and reversibility at high scan rates in electrochemical performances. Ordered mesoporous carbon nanosphere electrode with specific surface area of 904 m2/g maintained a stable specific capacitance of 210 F g-1under specific current of 0.1 A g-1for 500 cycles of charge/discharge.

High Efficient Photoreduction CO2 with H2O on Metal Cu-Modified Graphitic Ordered Mesoporous Carbon Supported TiO2 Catalysts under Simulated Solar

2014 ◽  
Vol 906 ◽  
pp. 39-44
Author(s):  
Cheng Li Zhang ◽  
Shi Fei Kang ◽  
Qian Yu Zhang ◽  
Xi Li
Keyword(s):  
Electron Microscopy ◽  
Mesoporous Carbon ◽  
Nitrogen Adsorption ◽  
High Specific Surface Area ◽  
Ordered Mesoporous Carbon ◽  
Solar Irradiation ◽  
Transmission Electron Microscopy Analysis ◽  
Ordered Mesoporous ◽  
High Efficient ◽  
Electron Microscopy Analysis

Cu-modified graphitic ordered mesoporous carbon supported TiO2 catalyst was synthesized based on a hard template method. X-ray diffraction, nitrogen adsorption-desorption, scanning electron microscopy and transmission electron microscopy analysis techinques were used to characterize the sample. It was observed that copper and anatase TiO2 nanoparticles were well dispersed in the Cu-modified mesoporous graphitic carbon, and the resulting composite with ordered mesostructure and high specific surface area exhibited an exceptionally high activity in the photocatalytic reduction of CO2 with H2O under simulated solar irradiation.

Enhanced adsorption of humic acids on ordered mesoporous carbon compared with microporous activated carbon

2011 ◽  
Vol 30 (4) ◽  
pp. 793-800 ◽  
Author(s):  
Fengling Liu ◽  
Zhaoyi Xu ◽  
Haiqin Wan ◽  
Yuqiu Wan ◽  
Shourong Zheng ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Humic Acids ◽  
Mesoporous Carbon ◽  
Ordered Mesoporous Carbon ◽  
Ordered Mesoporous ◽  
Enhanced Adsorption

Synthesis of ordered mesoporous carbon films, powders, and fibers by direct triblock-copolymer-templating method using an ethanol/water system

Carbon ◽  
2009 ◽  
Vol 47 (11) ◽  
pp. 2688-2698 ◽  
Author(s):  
Shunsuke Tanaka ◽  
Anna Doi ◽  
Norihito Nakatani ◽  
Yugo Katayama ◽  
Yoshikazu Miyake
Keyword(s):  
Mesoporous Carbon ◽  
Triblock Copolymer ◽  
Water System ◽  
Carbon Films ◽  
Ordered Mesoporous Carbon ◽  
Templating Method ◽  
Ordered Mesoporous

Adsorption of Direct Yellow 12 onto Ordered Mesoporous Carbon and Activated Carbon

2009 ◽  
Vol 54 (11) ◽  
pp. 3043-3050 ◽  
Author(s):  
Fengling Liu ◽  
Jiahong Wang ◽  
Liyuan Li ◽  
Yun Shao ◽  
Zhaoyi Xu ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Mesoporous Carbon ◽  
Ordered Mesoporous Carbon ◽  
Ordered Mesoporous

Preparation of ordered mesoporous carbon membranes by a soft-templating method

Carbon ◽  
2011 ◽  
Vol 49 (10) ◽  
pp. 3184-3189 ◽  
Author(s):  
Shunsuke Tanaka ◽  
Norihito Nakatani ◽  
Anna Doi ◽  
Yoshikazu Miyake
Keyword(s):  
Mesoporous Carbon ◽  
Ordered Mesoporous Carbon ◽  
Templating Method ◽  
Carbon Membranes ◽  
Ordered Mesoporous ◽  
Soft Templating

Synthesis, Characterization and Physiochemical Properties of Platinum Supported on Mesoporous Carbon

2011 ◽  
Author(s):  
Salam J. J. Titinchi ◽  
Waheed Saban ◽  
Leslie Petrik ◽  
Hanna S. Abbo
Keyword(s):  
Surface Area ◽  
Pore Volume ◽  
Mesoporous Carbon ◽  
Chemical Vapour ◽  
Nitrogen Adsorption ◽  
Ordered Mesoporous Carbon ◽  
Pt Catalyst ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ordered Mesoporous

Ordered mesoporous carbon (OMC) has been prepared by impregnating the pores of the silica template (SBA-15) with liquid petroleum gas (LPG) or sucrose. The desired support (OMC) was obtained after dissolution with NaOH. Platinum nanoparticles were dispersed on ordered mesoporous carbons using Chemical Vapour Deposition (CVD) method and Pt(acac)2 as metal source. The resulting ordered mesoporous carbon possess a large surface area with high microporosity, and a controlled pore size distribution, High-quality carbon replicas of SBA-15 show an X-ray diffraction peak at low angle, which indicates that the structural periodicity of the (111) planes has been maintained. Their pore volume and specific surface area are high and the pore volume is almost entirely microporous. The synthesized Pt/OMC was characterized by powder X-Ray diffraction, HR-TEM, HR-SEM, EDS, thermogravimetric analysis, and nitrogen adsorption. The performance of Pt catalyst supported OMC was evaluated by electrochemical studies, which shows almost similar activity to the commercial catalyst.

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