Influence of Cr/Zr Ratio on Activity of Cr–Zr Oxide Catalysts in Non-Oxidative Propane Dehydrogenation
Keyword(s):
Two series of chromium–zirconium mixed oxide catalysts with different Cr/Zr molar ratio are prepared by co-precipitation method. Porous structure of the catalysts is studied by low-temperature N2 adsorption–desorption. Phase composition and chromium states in the catalysts are characterized by X-ray diffraction (XRD), UV-visible spectroscopy, and temperature-programmed reduction with hydrogen (TPR-H2). The mixed catalysts are tested in non-oxidative dehydrogenation of propane at 550 °C. The catalysts synthesized without ageing of precipitate show higher activity in propane dehydrogenation due to the higher content of reducible Cr+5/+6 species due to its stabilization on the ZrO2 surface.
2011 ◽
Vol 28
(4)
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pp. 1139-1143
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Keyword(s):
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