scholarly journals Investigation and Control Technology on Excessive Ammonia-Slipping in Coal-Fired Plants

Energies ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 4249
Author(s):  
Xuan Yao ◽  
Man Zhang ◽  
Hao Kong ◽  
Junfu Lyu ◽  
Hairui Yang

After the implementation of the ultra-low emissions regulation on the coal-fired power plants in China, the problem of the excessive ammonia-slipping from selective catalytic reduction (SCR) seems to be more severe. This paper analyzes the operating statistics of the coal-fired plants including 300 MW/600 MW/1000-MW units. Statistics data show that the phenomenon of the excessive ammonia-slipping is widespread. The average excessive rate is over 110%, while in the small units the value is even higher. A field test data of nine power plants showed that excessive ammonia-slipping at the outlet of SCR decreased following the flue-gas process. After most ammonia reduced by the dust collector and the wet flue-gas desulfurization (FGD), the ammonia emission at the stack was extremely low. At same time, a method based on probability distribution is proposed in this paper to describe the relationship between the NH3/NOX distribution deviation and the De–NOX efficiency/ammonia-slipping. This paper also did some original work to solve the ammonia-slipping problem. A real-time self-feedback ammonia injection technology using neural network algorithm to predict and moderate the ammonia distribution is proposed to decrease the NH3/NOX deviation and excessive ammonia-slipping. The technology is demonstrated in a 600-MW unit and works successfully. The excessive ammonia-slipping problem is well controlled after the implementation of the technology.

2018 ◽  
Vol 53 ◽  
pp. 04005 ◽  
Author(s):  
Ding Yang ◽  
Yi Luo ◽  
XingLian Ye ◽  
WeiXiang Chen ◽  
Jun Guo ◽  
...  

SO3 is one of the main precursors of atmospheric PM2.5, and its emission has attracted more and more attention in the industry. This paper briefly analyzes the harm of SO3 and the method of controlled condensation to test SO3. The effect of cooperative removal of SO3 by ultra-low emission technology in some coal-fired power plants has been tested by using the method of controlled condensation. The results show that the cooperative removal of SO3 by ultra-low emission technology in coal-fired power plants is effective. The removal rate of SO3 by low-low temperature electrostatic precipitators and electrostatic-fabric integrated precipitators can be exceeded 80%, while the removal rate of SO3 by wet flue gas desulfurization equipment displays lower than the above two facilities, and the wet electrostatic precipitator shows a better removal effect on SO3. With the use of ultra-low emission technology in coal-fired power plants, the SO3 emission concentration of the tail chimney reaches less than 1 mg / Nm3.


2020 ◽  
Vol 142 (9) ◽  
Author(s):  
Ghulam Moeen Uddin ◽  
Syed Muhammad Arafat ◽  
Waqar Muhammad Ashraf ◽  
Muhammad Asim ◽  
Muhammad Mahmood Aslam Bhutta ◽  
...  

Abstract The emissions from coal power plants have serious implication on the environment protection, and there is an increasing effort around the globe to control these emissions by the flue gas cleaning technologies. This research was carried out on the limestone forced oxidation (LSFO) flue gas desulfurization (FGD) system installed at the 2*660 MW supercritical coal-fired power plant. Nine input variables of the FGD system: pH, inlet sulfur dioxide (SO2), inlet temperature, inlet nitrogen oxide (NOx), inlet O2, oxidation air, absorber slurry density, inlet humidity, and inlet dust were used for the development of effective neural network process models for a comprehensive emission analysis constituting outlet SO2, outlet Hg, outlet NOx, and outlet dust emissions from the LSFO FGD system. Monte Carlo experiments were conducted on the artificial neural network process models to investigate the relationships between the input control variables and output variables. Accordingly, optimum operating ranges of all input control variables were recommended. Operating the LSFO FGD system under optimum conditions, nearly 35% and 24% reduction in SO2 emissions are possible at inlet SO2 values of 1500 mg/m3 and 1800 mg/m3, respectively, as compared to general operating conditions. Similarly, nearly 42% and 28% reduction in Hg emissions are possible at inlet SO2 values of 1500 mg/m3 and 1800 mg/m3, respectively, as compared to general operating conditions. The findings are useful for minimizing the emissions from coal power plants and the development of optimum operating strategies for the LSFO FGD system.


2008 ◽  
Vol 89 (11) ◽  
pp. 1025-1032 ◽  
Author(s):  
Yi Zhong ◽  
Xiang Gao ◽  
Wang Huo ◽  
Zhong-yang Luo ◽  
Ming-jiang Ni ◽  
...  

1995 ◽  
Vol 10 (3) ◽  
pp. 553-561 ◽  
Author(s):  
G. Centi ◽  
B.K. Hodnett ◽  
P. Jaeger ◽  
C. Macken ◽  
M. Marella ◽  
...  

Some aspects of the industrial development of copper-on-alumina catalytic materials for the combined removal of SO2 (DeSOx and NOx (DeNOx) from flue gas of power plants are discussed. Applications of these catalytic materials for the recovery of sulfuric acid from diluted aqueous solutions of ammonium sulfate are also outlined. In particular, the following specific topics are analyzed: (i) the relationship between textural and reactivity properties. (ii) the problem of the design of samples with improved DeSOx properties in relation to the stability of the samples over extended operations, and (iii) the optimization of the regeneration characteristics of the samples. Details on the flow sheet of the technology are also given.


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