scholarly journals Validating Structural Styles in the Flysch Basin Northern Rif (Morocco) by Means of Thermal Modeling

Geosciences ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 325
Author(s):  
Achraf Atouabat ◽  
Sveva Corrado ◽  
Andrea Schito ◽  
Faouziya Haissen ◽  
Oriol Gimeno-Vives ◽  
...  
Keyword(s):  
Vitrinite Reflectance ◽  
Thermal Modeling ◽  
Hydrocarbon Generation ◽  
Thermal Maturity ◽  
Data Set ◽  
The North ◽  
Frontal Part ◽  
Rif Belt ◽  
Thermal Indicators ◽  
North Western

Vitrinite reflectance and a micro-Raman spectroscopy parameters data set have been acquired on dispersed organic matter of the Maghrebian flysch basin and the Tangiers unit across a NE-SW section in the north-western Rif belt (North Morocco). Thermal maturity shows increasing values from the hinterland to the external unit (from NE to SW). Paleo-thermal indicators show that the internal flysch basin (i.e., the Mauretanian unit) is less mature than the external one, (i.e., the Massylian unit), with Ro% and Ro eq. Raman values ranging from 0.64% to 1.02% (from early mature to late mature stages of hydrocarbon generation). 1D thermal modeling estimates the overburden now totally eroded ranging from 3.1 km to 6.0 km, and has been used as constraint to reconstruct the complete thrust wedge geometry in Miocene times. The reconstructed geometry accounts for high shortening (about 63%) due to the development of an antiformal stack in the frontal part of the wedge made up by the flysch succession. This stacking is interpreted as a consequence of the western translation of the Alboran Domain in the core of the Betic-Rif orogenic system.

Structural styles of the External Rif and Flysch Domain (Rif belt, northern Morocco) through thermal maturity and structural data

2020 ◽  
Author(s):  
Andrea Schito ◽  
Achraf Atouabat ◽  
Sveva Corrado ◽  
Faouziya Haissen ◽  
Geoffroy Mohn ◽  
...  
Keyword(s):  
Vitrinite Reflectance ◽  
Methodological Approach ◽  
Structural Evolution ◽  
Structural Data ◽  
Thermal Modelling ◽  
Thermal Maturity ◽  
North African ◽  
Data Set ◽  
The North ◽  
Rif Belt

<p>Located in northern Morocco, the Rif belt represents the western edge of the Maghrebides system. This domain underwent a significant Cenozoic alpine compressional deformation, due to the collision between the North African margin and the south-western margin of the exotic Alboran Domain. This collision led to the development of a nappe stack during the Miocene.</p><p>This contribution aims to characterize the main tectonic mechanisms driving the evolution of the Rifain wedge, its burial-exhumation paths and to understand the former architecture of the North African paleo-margin. The work focuses mainly on the Flysch domain, originated from the Maghrebian branch of the Tethys and on the External domain (namely Intrarif, Mesorif and Prerif) that belong to the former north African margin. To define the thrust sheet stacking pattern and their burial-exhumation paths, a regional transect from Chefchaouen and Ouezzane towns (Central Rif), crossing the orogenic wedge from the Flysch to the Prerif Units is constructed.</p><p>The methodological approach consists in combining petrography and Raman micro-spectroscopy on organic matter and 1D thermal modelling, together with field structural data.</p><p>A new paleo-thermal data set of vitrinite reflectance (Ro%) and Raman micro-spectroscopy displays levels of thermal maturity between early and deep diagenetic conditions (Ro% ranges from 0.50% to 1.15%).</p><p>Preliminary results show an abrupt change in the thermal maturity and the rate of shortening in the Loukkos sub-unit (Intrarif Domain) that is structurally squeezed between Tangier sub-unit (Intrarif Domain) and the “Izzaren Duplex” (Mesorif).</p><p>Furthermore, previous studies show that the thickest crust below the Rif fold-and-thrust belt is located below the Izzaren area, suggesting a deep crustal imbrication at the transition between the Intrarif and the Mesorif. These observations joined with the thermal maturity data and 1D thermal modelling allow revisiting the structural evolution of the central part of the Rif belt, by defining the rate of shortening and proposing a new geological restoration with respect to the Mesozoic North African margin structural original setting.</p>

The structuration of the External Rif (Rif belt: Northern Morocco). An insights from paleo-thermal and structural analyses

2021 ◽  
Author(s):  
Achraf Atouabat ◽  
Sveva Corrado ◽  
Dominique Frizon de Lamotte ◽  
Geoffroy Mohn ◽  
Faouziya Haissen ◽  
...  
Keyword(s):  
Upper Cretaceous ◽  
Vitrinite Reflectance ◽  
Structural Evolution ◽  
Structural Data ◽  
Passive Margin ◽  
Thermal Maturity ◽  
North African ◽  
Tectonic Structures ◽  
The North ◽  
Rif Belt

<p>Belonging to the Maghrebides system, the Rif belt (Northern Morocco) suffered an important Cenozoic Alpine compressional deformation as a consequence of the closure of the Maghrebian Tethys and the westward translation and docking of the Alboran Domain onto the African margin during the Late Burdigalian. The Mesozoic North African Margin is still partially preserved in the Eastern Rif (e.g., Senhadja Jurassic-Cretaceous unit) and inverted in its Central portion (North of the Nekor Fault Zone) due to the high shortening in this area. It is in agreement with sub-surface data suggesting that the thickest crust along the chain is located in the central Rif (Izzaren Area, External Rif), and can be interpreted as a deep-rooted crustal imbrication.</p><p>This contribution aims to characterize the role of the structural inheritance of the rifted North African margin in the development and the propagation of the Rif belt by the combination of paleothermal and structural data collected along a NE-SW regional transect (between Chefchaouen and Ouezzane provinces), focusing mainly on the external zones (namely, Intrarif, Mesorif and Prerif) sampling the deformed domains originally developed along the North African paleo-passive margin. A new paleo-thermal dataset of vitrinite reflectance (Ro%), micro-Raman spectroscopy on organic matter and XRD on clayey fraction of sediments displays levels of thermal maturity between early and deep diagenetic conditions (Ro% from 0.49% to 1.15%). The highest thermal maturity values along the section are concentrated in the Lower to middle Cretaceous Loukkos Intrarifain sub-unit that is structurally squeezed between Tangier Intrarif Upper Cretaceous sub-unit and the Mesorif “Izzaren Duplex”. It attests for an important amount of shortening leading to the development of an imbricate fan of thrusts.</p><p>The geometry of the “Izzaren Duplex”, limited at surface by two first-order thrust faults, is controlled by pre-existing tectonic structures, probably inherited by the former architecture of the North African paleomargin. Moreover, the Chattian-Middle Miocene siliciclastic succession filling the Zoumi basin is in a stratigraphic continuity with the Izzaren Upper Jurassic-Upper Cretaceous substratum, sheding new light on its geodynamic meaning. This observation is supported by the homogeneity of deformation and the absence of thermal jump between the Mesozoic and Cenozoic successions, attesting for an active compressive deformation in the area between the Late Serravalian and Late Tortonian.</p><p>In conclusion, the combination of paleo-thermal and structural analysis allowed to reconstruct robust tectono-thermal model in order to propose an accurate reconstruction of the structural evolution and a new geological restoration of the Rif belt with respect to the geometry of the rifted paleo-margin.</p>

STABLE HYDROGEN ISOTOPE RATIOS OF SEDIMENTARY HYDROCARBONS: A POTENTIAL METHOD FOR ASSESSING THERMAL MATURITY?

2005 ◽  
Vol 45 (1) ◽  
pp. 253
Author(s):  
D. Dawson ◽  
K. Grice ◽  
R. Alexander
Keyword(s):  
Vitrinite Reflectance ◽  
Potential Method ◽  
Source Rocks ◽  
Crude Oils ◽  
Thermal Maturity ◽  
Peak Oil ◽  
Data Set ◽  
High Maturity ◽  
The Difference ◽  
Hydrogen Isotope Ratios

A relationship has been identified between the maturity level of source rocks and the stable hydrogen isotopic compositions (δD) of extracted saturated hydrocarbons, based on the analysis of nine sediments and five crude oils from the Perth Basin (WA). The sediments cover the immature to late mature range. Distinct δD signatures are observed for the immature sediments where pristane and phytane are significantly depleted in deuterium (D) relative to the n-alkanes. With increasing maturity the difference between the δD values of n-alkanes and isoprenoids reduces as pristane and phytane become progressively enriched in D. The n-alkane–isoprenoid δD signature of the crude oils, including one from a different source facies, is similar to mature–late mature sediments representative of the peak oil–generative window. Enrichment of D in isoprenoids is attributed to isotopic exchange associated with thermal maturation. Average δD values of pristane and phytane correlate well with vitrinite reflectance, as does the biomarker maturity parameter Ts/Tm. The limited data set suggests that δD values of aliphatic hydrocarbons may be useful for establishing thermal maturity, particularly when other maturity parameters are not appropriate. Furthermore, we suggest δD values may be useful over a wider maturity range than traditional parameters, particularly at very high maturity where biomarker parameters are no longer effective.

scholarly journals Thermal and structural modeling of the Scillato wedge-top basin source-to-sink system: Insights into the Sicilian fold-and-thrust belt evolution (Italy)

2019 ◽  
Vol 131 (11-12) ◽  
pp. 1763-1782 ◽  
Author(s):  
Martina Balestra ◽  
Sveva Corrado ◽  
Luca Aldega ◽  
Maurizio Gasparo Morticelli ◽  
Attilio Sulli ◽  
...  
Keyword(s):  
Short Range ◽  
Vitrinite Reflectance ◽  
Sediment Provenance ◽  
Hydrocarbon Generation ◽  
Thermal Maturity ◽  
Thrust Belt ◽  
Ordered Structures ◽  
Source To Sink ◽  
Fold And Thrust Belt ◽  
Basin Fill

Abstract Temperature-dependent clay mineral assemblages, vitrinite reflectance, and one-dimensional (1-D) thermal and three-dimensional (3-D) geological modeling of a Neogene wedge-top basin in the Sicilian fold-and-thrust belt and its pre-orogenic substratum allowed us to: (1) define the burial history of the sedimentary succession filling the wedge-top basin and its substratum, (2) reconstruct the wedge-top basin geometry, depocenter migration, and sediment provenance through time in the framework of a source-to-sink system, and (3) shed new light into the kinematic evolution of the Apennine-Maghrebian fold-and-thrust belt. The pre-orogenic substratum of the Scillato basin shows an increase in levels of thermal maturity as a function of stratigraphic age that is consistent with maximum burial to 3.5 km in deep diagenetic conditions. In detail, Ro% values range from 0.40% to 0.94%, and random ordered illite-smectite (I-S) first converts to short-range ordered structures and then evolves to long-range ordered structures at the base of the Imerese unit. The wedge-top basin fill experienced shallow burial (∼2 km) and levels of thermal maturity in the immature stage of hydrocarbon generation and early diagenesis. Vitrinite reflectance and mixed-layer I-S values show two populations of authigenic and inherited phases. The indigenous population corresponds to macerals with Ro% values of 0.33%–0.45% and I-S with no preferred sequence in stacking of layers, whereas the reworked group corresponds to macerals with Ro% values of 0.42%–0.47% and short-range ordered I-S with no correlation as a function of depth. Authigenic and reworked components of the Scillato basin fill allowed us to unravel sediment provenance during the Neogene, identifying two main source areas feeding the wedge-top basin (crystalline units of the European domain and sedimentary units of the African domain), and to detect an early phase of exhumation driven by low-angle extensional faults that predated Neogene compression.

Thermal imprints along conjugated continental margins in response to the opening of the northern North Atlantic - case studies from eastern North Greenland and western Svalbard

2021 ◽  
Author(s):  
Katrin Meier ◽  
Paul O'Sullivan ◽  
Malte Jochmann ◽  
Patrick Monien ◽  
Karsten Piepjohn ◽  
...  
Keyword(s):  
Heat Flow ◽  
North Atlantic ◽  
Thermal History ◽  
Vitrinite Reflectance ◽  
Continental Margins ◽  
Thermal Maturity ◽  
Quartz Veins ◽  
The North ◽  
Reflectance Data ◽  
North Greenland

<p>Prior to break up of Greenland and Svalbard, the Wandel sea basin with Carboniferous to Cenozoic deposits formed in eastern North Greenland. These deposits were affected by the last major period of Arctic tectonism, the Eocene Eurekan deformation. Vitrinite reflectance data from late Cretaceous rocks long the east coast of North Greenland indicate unusual high thermal maturity in association with a swarm of quartz veins, which exceeds the thermal maturity associated with the Eurekan deformation further inland. This pattern is also observed in Cenozoic sediments further to the north as well as along the conjugated North Atlantic margin, in western Svalbard. However, cause and origin of the elevated heat flow indicated by thermal maturity values are not known so far and the timing is not well constrained. We test the hypothesis whether this pattern was established coevally along both margins of the North Atlantic and marks a post-Eurekan thermal event. Vitrinite reflectance data indicate temperatures high enough to reset low temperature chronometers, therefore we used apatite fission track (AFT) and (U-Th-Sm)/He (AHe) thermochronology to determine the age of the high thermal maturation and associated quartz veins formation.</p><p>Our data reveals a more complex thermal history than hypothesized:<br>For the eastern North Greenland margin thermal history modelling of the combined AFT and AHe ages indicates a pre-Eurekan phase of elevated heat flow between 72 Ma and 66 Ma causing the high vitrinite reflectance and the formation of the quartz veins in the late Cretaceous rocks. Additional petrographic and electron microprobe analysis reveals the growth of feldspar, hematite, amphibole, and tourmaline within the quartz veins. According to most paleogeographic reconstructions, northern Greenland was located to the south of Svalbard close to a volcanic province near Bear Island. Heating may thus be associated with incipient igneous activity of that area, related to initial North Atlantic opening. A second phase of elevated heat flow between 58 Ma and 52 Ma is indicated by thermal history modelling of the AFT and AHe ages from the Cenozoic rocks further north. This frames the timing of the initiation of the dextral displacement between Greenland and Svalbard and might be associated with heat transfer along the transform fault from the active spreading centres in the North Atlantic and the Arctic Ocean.<br>Contrasting to the results of North Greenland, thermal history modelling of AFT and AHe ages from the Cenozoic rocks of western Svalbard reveals heating throughout the Eocene and onset of cooling only during the early Oligocene for the Svalbard margin. Thus, even though we cannot exclude a similar thermal history during the Paleocene to early Eocene, the eastern North Greenland and western Svalbard margins are characterized by a differential thermal evolution during the ~middle Eocene to Oligocene.</p><p>In conclusion, our data show that the thermal history of the conjugated continental margins along the northern North Atlantic is characterized by episodic heat flow variations predominantly controlled by oceanic plate tectonic processes.</p>

scholarly journals Burial history, thermal history and hydrocarbon generation modelling of the Jurassic source rocks in the basement of the Polish Carpathian Foredeep and Outer Carpathians (SE Poland)

2012 ◽  
Vol 63 (4) ◽  
pp. 335-342 ◽  
Author(s):  
Paweł Kosakowski ◽  
Magdalena Wróbel
Keyword(s):  
Organic Matter ◽  
Thermal History ◽  
Vitrinite Reflectance ◽  
Source Rocks ◽  
Hydrocarbon Generation ◽  
Thermal Maturity ◽  
Burial History ◽  
Se Poland ◽  
Carpathian Foredeep ◽  
Outer Carpathians

Burial history, thermal history and hydrocarbon generation modelling of the Jurassic source rocks in the basement of the Polish Carpathian Foredeep and Outer Carpathians (SE Poland)Burial history, thermal maturity, and timing of hydrocarbon generation were modelled for the Jurassic source rocks in the basement of the Carpathian Foredeep and marginal part of the Outer Carpathians. The area of investigation was bounded to the west by Kraków, to the east by Rzeszów. The modelling was carried out in profiles of wells: Będzienica 2, Dębica 10K, Góra Ropczycka 1K, Goleszów 5, Nawsie 1, Pławowice E1 and Pilzno 40. The organic matter, containing gas-prone Type III kerogen with an admixture of Type II kerogen, is immature or at most, early mature to 0.7 % in the vitrinite reflectance scale. The highest thermal maturity is recorded in the south-eastern part of the study area, where the Jurassic strata are buried deeper. The thermal modelling showed that the obtained organic matter maturity in the initial phase of the "oil window" is connected with the stage of the Carpathian overthrusting. The numerical modelling indicated that the onset of hydrocarbon generation from the Middle Jurassic source rocks was also connected with the Carpathian thrust belt. The peak of hydrocarbon generation took place in the orogenic stage of the overthrusting. The amount of generated hydrocarbons is generally small, which is a consequence of the low maturity and low transformation degree of kerogen. The generated hydrocarbons were not expelled from their source rock. An analysis of maturity distribution and transformation degree of the Jurassic organic matter shows that the best conditions for hydrocarbon generation occurred most probably in areas deeply buried under the Outer Carpathians. It is most probable that the "generation kitchen" should be searched for there.

scholarly journals Geochemistry and petrology of selected sediments from Bukit Song, Miri, Sarawak, Malaysia, with emphasis on organic matter characterization

2021 ◽  
Vol 11 (10) ◽  
pp. 3663-3688
Author(s):  
Amin Tavakoli
Keyword(s):  
Organic Matter ◽  
Depositional Environment ◽  
Vitrinite Reflectance ◽  
Xrd Analysis ◽  
Source Rocks ◽  
Hydrocarbon Generation ◽  
Thermal Maturity ◽  
Petroleum Potential ◽  
Type Iv ◽  
Two Samples

AbstractThe aim of this study is to provide a better understanding of the type of source input, quality, quantity, the condition of depositional environment and thermal maturity of the organic matter from Bukit Song, Sarawak, which has not been extensively studied for hydrocarbon generation potential. Petrological and geochemical analyses were performed on 13 outcrop samples of the study location. Two samples, having type III and mixed kerogen, showed very-good-to-excellent petroleum potential based on bitumen extraction and data from Rock–Eval analysis. The rest of the samples are inert—kerogen type IV. In terms of thermal maturity based on vitrinite reflectance, the results of this paper are akin to previous studies done in the nearby region reported as either immature or early mature. Ph/n-C18 versus Pr/n-C17 data showed that the major concentration of samples is within peat coal environment, whilst two samples were associated with anoxic marine depositional environment, confirmed by maceral content as well. Macerals mainly indicated terrestrial precursors and, overall, a dominance of vitrinite. Quality of the source rock based on TOC parameter indicated above 2 wt. % content for the majority of samples. However, consideration of TOC and S2 together showed only two samples to have better source rocks. Existence of cutinite, sporinite and greenish fluorescing resinite macerals corroborated with the immaturity of the analysed coaly samples. Varying degrees of the bitumen staining existed in a few samples. Kaolinite and illite were the major clays based on XRD analysis, which potentially indicate low porosity. This study revealed that hydrocarbon-generating potential of Bukit Song in Sarawak is low.

THE SUPPRESSION OF VITRINITE REFLECTANCE IN SOME NORTH WEST SHELF WELLS: BARROW-1, JUPITER-1 AND FLAMINGO-1

1992 ◽  
Vol 32 (1) ◽  
pp. 300 ◽  
Author(s):  
R.W.T. Wilkins ◽  
J.R. Wilmshurst ◽  
G. Hladky ◽  
M.V. Ellacott ◽  
C.P. Buckingham
Keyword(s):  
Organic Matter ◽  
Vitrinite Reflectance ◽  
Accurate Determination ◽  
Petroleum Exploration ◽  
Thermal Maturity ◽  
North West ◽  
The North ◽  
The Individual ◽  
Reflectance Data

The sediments of the North West Shelf pose several problems for the accurate determination of thermal maturity by vitrinite reflectance. There are some serious discrepancies between the results of different workers; in some wells there is a surprisingly small increase of reflectance with depth, and it is sometimes difficult to honour these data in thermal maturity modelling. There appear to be two major sources of error in the reflectance data. These are firstly, the effect known as 'suppression' of vitrinite reflectance, and secondly, the difficulty of identifying the vitrinite population in dispersed organic matter.These problems may be addressed by the fluorescence alteration technique which is closely related to vitrinite reflectance but has two special advantages. Firstly, it depends on an analysis of the fluorescence alteration response of a small representative population of organic matter in which the individual macerals need not be identified. Secondly, anomalous vitrinites with suppressed vitrinite reflectance are readily characterized, and the corrected equivalent reflectances determined.The technique has been tested on three North West Shelf petroleum exploration wells, Barrow-1, Jupiter-1 and Flamingo-1. Major discrepancies between measured and equivalent vitrinite reflectance appear to originate in part from the difficulty of identifying the vitrinite population in dispersed organic matter from marine sediments. There is also evidence of suppression of vitrinite reflectance in most samples from Barrow-1, in the Flamingo Group and Plover Formation of Flamingo-1, and in the upper part of the Mungaroo Formation of Jupiter-1.A model is proposed to facilitate the assessment of measured vitrinite reflectance data from Carnarvon or Bonaparte Basin wells. Suppression effects are likely to have influenced measured vitrinite reflectance results from wells for which the strongest data are obtained from the Lower Cretaceous fluvio-deltaic Barrow Group sediments or their equivalents.

MATURATION PATTERNS IN THE PERTH BASIN

1979 ◽  
Vol 19 (1) ◽  
pp. 94 ◽  
Author(s):  
A. J. Kantsler ◽  
A. C. Cook
Keyword(s):  
Vitrinite Reflectance ◽  
Upper Jurassic ◽  
Source Rocks ◽  
Hydrocarbon Generation ◽  
Geothermal Gradients ◽  
The North ◽  
Reservoir Conditions ◽  
Igneous Activity ◽  
Hydrocarbon Deposits ◽  
Very High

Vitrinite reflectance data from wells drilled in the Perth Basin show that major variations exist in the pattern of rank distribution within the basin. Generally, rank gradients are low and near linear, but some wells show curvature of the rank profile in the Early Jurassic and Triassic parts of their sections. Curvature of the rank profile is generally associated with a shallow depth to basement, but the presence of very high ranks in parts of the Permian section on the Beagle Ridge suggests that a Permian to Jurassic thermal event associated with local igneous activity or the initiation of rifting, or both, may also be a controlling factor. Low, linear rank gradients from parts of the basin such as the Bunbury Trough and the thick Upper Jurassic sections of some of the deeper sub-basins are taken to indicate that low geothermal gradients have operated since the Permian,in the former instance and certainly since the Jurassic in the latter. Such conditions imply slow generation of hydrocarbons.Higher geothermal gradients and rank gradients in parts of the basin as in the north Dandaragan Trough and Vlaming Sub-basin imply enhanced hydrocarbon generation, particularly as calculated palaeotemperatures indicate that the advent of higher geothermal gradients is likely to have been relatively recent. Potential source rocks occur throughout the basin and provided that suitable structural and reservoir conditions can be delineated, the prospects of discovering more commercial hydrocarbon deposits are high.

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