scholarly journals Rejuvenation of Zr-Based Bulk Metallic Glasses by Ultrasonic Vibration-Assisted Elastic Deformation

Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4397
Author(s):  
Yan Lou ◽  
Shenpeng Xv ◽  
Zhiyuan Liu ◽  
Jiang Ma
Keyword(s):  
Amorphous Alloy ◽  
Free Volume ◽  
Elastic Deformation ◽  
Ultrasonic Vibration ◽  
Metallic Glasses ◽  
Bulk Metallic Glasses ◽  
Supercooled Liquid ◽  
Deformation Region ◽  
Vibration Stress ◽  
The Relationship

The rejuvenation of Zr52.5Cu17.9Ni14.6Al10Ti5 bulk metallic glasses (BMGs) by ultrasonic vibration-assisted elastic deformation (UVEF) was studied herein. The UVEF-treated samples demonstrate an obvious rejuvenation and have a higher relaxation enthalpy and a smaller range of supercooled liquid regions than the as-cast samples. The fracture of the rejuvenated amorphous alloy is mainly ductile fracture, and shear deformation occurs in the deformation region. It is also found that as the amplitude increases, the free volume of the rejuvenated amorphous alloy increases, the yield strength and the elastic modulus decrease, and the formability increases. The free-volume content is used to characterize the degree of rejuvenation, and a mathematical model of the relationship between the ultrasonic amplitude and free volume is established. In addition, it is found that the ultrasonic vibration stress induces the additional free volume in the Zr-based bulk metallic glasses and improves the plasticizing behavior. The temperature rise caused by the ultrasonic thermal effect does not induce additional free volume.

Characteristic free volume change of bulk metallic glasses

2012 ◽  
Vol 111 (8) ◽  
pp. 083523 ◽  
Author(s):  
Qiang Hu ◽  
Xie-Rong Zeng ◽  
M. W. Fu
Keyword(s):  
Free Volume ◽  
Volume Change ◽  
Metallic Glasses ◽  
Bulk Metallic Glasses

Fe-based bulk metallic glasses with a larger supercooled liquid region and high ductility

2008 ◽  
Vol 498 (1-2) ◽  
pp. 464-467 ◽  
Author(s):  
K.Q. Qiu ◽  
J. Pang ◽  
Y.L. Ren ◽  
H.B. Zhang ◽  
C.L. Ma ◽  
...  
Keyword(s):  
Metallic Glasses ◽  
Bulk Metallic Glasses ◽  
Supercooled Liquid ◽  
Supercooled Liquid Region ◽  
Liquid Region ◽  
High Ductility

Ultrasonic vibration accelerated aging in La-based bulk metallic glasses

2020 ◽  
Vol 535 ◽  
pp. 119967 ◽  
Author(s):  
Siyuan Chen ◽  
Song Li ◽  
Jiang Ma ◽  
Haibin Yu ◽  
Huashan Liu ◽  
...  
Keyword(s):  
Ultrasonic Vibration ◽  
Metallic Glasses ◽  
Bulk Metallic Glasses ◽  
Accelerated Aging

Correlation between effective activation energy and pre-exponential factor for diffusion in bulk metallic glasses

1999 ◽  
Vol 14 (8) ◽  
pp. 3200-3203 ◽  
Author(s):  
S. K. Sharma ◽  
F. Faupel
Keyword(s):  
Activation Energy ◽  
Metallic Glasses ◽  
Effective Activation Energy ◽  
Bulk Metallic Glasses ◽  
Supercooled Liquid ◽  
The Novel ◽  
Effective Activation ◽  
Exponential Factor ◽  
Liquid States ◽  
Fitting Parameters

The values of effective activation energy (Q) and pre-exponential factor (D0) reported in the literature for diffusion in the novel bulk metallic glasses, both in the glassy and the deeply supercooled liquid regions, are found to follow the same correlation as reported earlier in conventional metallic glasses, namely D0 = A exp(Q/B), where A and B are fitting parameters with values A = 4.8 × 10−19 m2 s−1 and B = 0.056 eV atom−1. A possible explanation for the observed values of A and B is given by combining an activation energy and a free volume term. The interpretation favors a cooperative mechanism for diffusion in the glassy and deeply supercooled liquid states.

Ultrasound-Induced Structural Anomaly of Supercooled Liquid in Some Bulk Metallic Glasses

2004 ◽  
Vol 45 (4) ◽  
pp. 1189-1193 ◽  
Author(s):  
Tetsu Ichitsubo ◽  
Eiichiro Matsubara ◽  
Kazuhiro Anazawa ◽  
Nobuyuki Nishiyama ◽  
Satoshi Kai ◽  
...  
Keyword(s):  
Metallic Glasses ◽  
Bulk Metallic Glasses ◽  
Supercooled Liquid ◽  
Structural Anomaly
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