scholarly journals Insight into Electrical and Dielectric Relaxation of Doped Tellurite Lithium-Silicate Glasses with Regard to Ionic Charge Carrier Number Density Estimation

Materials ◽  
2020 ◽  
Vol 13 (22) ◽  
pp. 5232
Author(s):  
Young Hoon Rim ◽  
Chang Gyu Baek ◽  
Yong Suk Yang
Keyword(s):  
Power Law ◽  
Direct Current ◽  
Lithium Ion ◽  
Lithium Silicate ◽  
Relaxation Processes ◽  
Ionic Charge ◽  
Potential Wells ◽  
Disordered Solids ◽  
Direct Current Conductivity ◽  
Current Activation

We investigate the role of tellurite on a lithium-silicate glass 0.1 TeO2 − 0.9 (Li2O-2SiO2) (LSTO) system proposed for the use in solid electrolyte for lithium ion batteries. The measurements of electrical impedance are performed in the frequency 100 Hz–30 MHz and temperature from 50 to 150 °C. The electrical conductivity of LSTO glass increases compared with that of Li2O-2SiO2 (LSO) glass due to an increase in the number of Li+ ions. The ionic hopping and relaxation processes in disordered solids are generally explained using Cole–Cole, power law and modulus representations. The power law conductivity analysis, which is driven by the modified Rayleigh equation, presents the estimation of the number of ionic charge carriers explicitly. The estimation counts for direct contribution of about a 14% increase in direct current conductivity in the case of TeO2 doping. The relaxation process by modulus analysis confirms that the cations are trapped strongly in the potential wells. Both the direct current and alternating current activation energies (0.62–0.67 eV) for conduction in the LSO glass are the same as those in the LSTO glass.

scholarly journals Stand-Alone Direct Current Power Network Based on Photovoltaics and Lithium-Ion Batteries for Reverse Osmosis Desalination Plant

Energies ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2772
Author(s):  
Vishwas Powar ◽  
Rajendra Singh
Keyword(s):  
Reverse Osmosis ◽  
Direct Current ◽  
Cyber Security ◽  
Large Scale ◽  
Lithium Ion ◽  
Economic Feasibility ◽  
Power Network ◽  
Variable Effect ◽  
Desalination Plant ◽  
Reverse Osmosis Desalination

Plummeting reserves and increasing demand of freshwater resources have culminated into a global water crisis. Desalination is a potential solution to mitigate the freshwater shortage. However, the process of desalination is expensive and energy-intensive. Due to the water-energy-climate nexus, there is an urgent need to provide sustainable low-cost electrical power for desalination that has the lowest impact on climate and related ecosystem challenges. For a large-scale reverse osmosis desalination plant, we have proposed the design and analysis of a photovoltaics and battery-based stand-alone direct current power network. The design methodology focusses on appropriate sizing, optimum tilt and temperature compensation techniques based on 10 years of irradiation data for the Carlsbad Desalination Plant in California, USA. A decision-tree approach is employed for ensuring hourly load-generation balance. The power flow analysis evaluates self-sufficient generation even during cloud cover contingencies. The primary goal of the proposed system is to maximize the utilization of generated photovoltaic power and battery energy storage with minimal conversions and transmission losses. The direct current based topology includes high-voltage transmission, on-the-spot local inversion, situational awareness and cyber security features. Lastly, economic feasibility of the proposed system is carried out for a plant lifetime of 30 years. The variable effect of utility-scale battery storage costs for 16–18 h of operation is studied. Our results show that the proposed design will provide low electricity costs ranging from 3.79 to 6.43 ¢/kWh depending on the debt rate. Without employing the concept of baseload electric power, photovoltaics and battery-based direct current power networks for large-scale desalination plants can achieve tremendous energy savings and cost reduction with negligible carbon footprint, thereby providing affordable water for all.

Determination of Crack-Initiation in Fracture Toughness Testing Using an Experimental Key-Curve Methodology

2021 ◽  
Author(s):  
S. Pothana ◽  
G. Wilkowski ◽  
S. Kalyanam ◽  
J. K. Hong ◽  
C. J. Sallaberry
Keyword(s):  
Fracture Toughness ◽  
Crack Initiation ◽  
Crack Growth ◽  
Power Law ◽  
Direct Current ◽  
Electric Potential ◽  
Crack Mouth Opening Displacement ◽  
Ductile Tearing ◽  
Curve Method ◽  
Unloading Compliance

Abstract A new approach was implemented to confirm the start of ductile tearing relative to assessments by other methods such as direct-current Electric Potential (d-c EP) method in coupon specimens. This approach was developed on the Key-Curve methodology by Ernst/Joyce and is similar to the ASTM E-1820 Load Normalization procedure used to determine J-R curves directly from load versus Load-Line Displacement (LLD) record of the test specimen. It is consistent with Deformation Plasticity relationships for fully plastic behavior. Using this Experimental Key-Curve method, crack initiation can be determined directly from load versus LLD data or load versus Crack-Mouth Opening Displacement (CMOD) obtained from a fracture test without the need for additional instrumentation required for crack initiation detection. It is based on the fact that plastic deformation of homogeneous metals at the crack tip follows a power-law function until the crack tearing initiates. Crack tearing initiation is determined at the point where the power-law fit to the load versus plastic part of CMOD or LLD curve deviates from the total experimental load versus plastic-CMOD or LLD curve. The procedure for fitting of the data requires some care to be exercised such that the fitted data is beyond the elastic region and early small-scale plastic region of the Load-CMOD or Load-LLD curve but include data before crack initiation. An iterative regression analysis was done to achieve this, which is shown in this paper. The iterative fitting in this region typically results with a coefficient of determination (R2) values that are greater than 0.990. This method can be either used in conjunction with other methods such as direct-current Electric Potential (d-c EP) or unloading-compliance methods as a secondary (or primary) confirmation of crack tearing initiation (and even for crack growth); or can be used alone when other methods cannot be used. Furthermore, when using instrumentation methods for determining crack-initiation such as d-c EP method in a fracture toughness test, it is good to have a secondary confirmation of the initiation point in case of instrumentation malfunction or high signal to noise ratio in the measured d-c EP signals. In addition, the Experimental Key-Curve procedure provides relatively smooth data for the fitting procedure, while unloading-compliance data when used to get small crack growth values frequently has significant variability, which is part of the reason that JIC by ASTM E1820 is determined using an offset with some growth past the very start of ductile tearing. In this work, the Experimental Key-Curve method had been successfully used to determine crack tearing initiation and demonstrate the applicability for different fracture toughness specimen geometries such as SEN(T), and C(T) specimens. In all the cases analyzed, the Experimental Key-Curve method gave consistent results that were in good agreement with other crack tearing initiation measuring method such as d-c EP but seemed to result in less scatter.

LONG RANGE CORRELATION PROPERTIES OF AFTERSHOCK RELAXATION SIGNALS

Fractals ◽  
1995 ◽  
Vol 03 (04) ◽  
pp. 839-847 ◽  
Author(s):  
A. VESPIGNANI ◽  
A. PETRI ◽  
A. ALIPPI ◽  
G. PAPARO ◽  
M. COSTANTINI
Keyword(s):  
Time Series ◽  
Acoustic Emission ◽  
Statistical Analysis ◽  
Power Spectrum ◽  
Power Law ◽  
Amplitude Distribution ◽  
Relaxation Processes ◽  
Critical Dynamics ◽  
Range Correlation ◽  
Correlation Properties

Relaxation processes taking place after microfracturing of laboratory samples give rise to ultrasonic acoustic emission signals. Statistical analysis of the resulting time series has revealed many features which are characteristic of critical phenomena. In particular, the autocorrelation functions obey a power-law behavior, implying a power spectrum of the kind 1/f. Also the amplitude distribution N(V) of such signals follows a power law, and the obtained exponents are consistent with those found in other experiments: N(V) dV≃V–γ dV, with γ=1.7±0.2. We also analyzed the distribution N(τ) of the delay time τ between two consecutive acoustic emission events. We found that a N(τ) distribution rather close to a power law constitutes a common feature of all the recorded signals. These experimental results can be considered as a striking evidence for a critical dynamics underlying the microfracturing processes.

scholarly journals Scale properties as a basis of power law relaxation processes

2007 ◽  
Vol 228 (2) ◽  
pp. 107-111 ◽  
Author(s):  
A. Fondado ◽  
J. Mira ◽  
J. Rivas
Keyword(s):  
Power Law ◽  
Relaxation Processes ◽  
Scale Properties

scholarly journals Slow Magnetic Relaxation in a One-Dimensional Coordination Polymer Constructed from Hepta-Coordinate Cobalt(II) Nodes

2020 ◽  
Vol 6 (4) ◽  
pp. 45
Author(s):  
Amit Kumar Mondal ◽  
Arpan Mondal ◽  
Sanjit Konar
Keyword(s):  
Magnetic Susceptibility ◽  
Coordination Polymer ◽  
Magnetic Anisotropy ◽  
Ab Initio Calculations ◽  
Direct Current ◽  
Magnetic Relaxation ◽  
Relaxation Processes ◽  
Ac Magnetic Susceptibility ◽  
One Dimensional ◽  
Slow Magnetic Relaxation

A one-dimensional coordination polymer was synthesized employing hepta-coordinate CoII as nodes and dicyanamide as linkers. Detailed direct current (DC) and alternating current (AC) magnetic susceptibility measurements reveal the presence of field-induced slow magnetic relaxation behavior of the magnetically isolated seven-coordinate CoII center with an easy-plane magnetic anisotropy. Detailed ab initio calculations were performed to understand the magnetic relaxation processes. To our knowledge, the reported complex represents the first example of slow magnetic relaxation in a one-dimensional coordination polymer constructed from hepta-coordinate CoII nodes and dicyanamide linkers.

scholarly journals Power-law decay in first-order relaxation processes

2005 ◽  
Vol 72 (2) ◽  
Author(s):  
A. Fondado ◽  
J. Mira ◽  
J. Rivas
Keyword(s):  
Power Law ◽  
Relaxation Processes ◽  
First Order ◽  
Power Law Decay
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