scholarly journals Role of Sintering Temperature in Production of Nepheline Ceramics-Based Geopolymer with Addition of Ultra-High Molecular Weight Polyethylene

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1077
Author(s):  
Romisuhani Ahmad ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Wan Mastura Wan Ibrahim ◽  
Kamarudin Hussin ◽  
Fakhryna Hannanee Ahmad Zaidi ◽  
...  

The primary motivation of developing ceramic materials using geopolymer method is to minimize the reliance on high sintering temperatures. The ultra-high molecular weight polyethylene (UHMWPE) was added as binder and reinforces the nepheline ceramics based geopolymer. The samples were sintered at 900 °C, 1000 °C, 1100 °C, and 1200 °C to elucidate the influence of sintering on the physical and microstructural properties. The results indicated that a maximum flexural strength of 92 MPa is attainable once the samples are used to be sintered at 1200 °C. It was also determined that the density, porosity, volumetric shrinkage, and water absorption of the samples also affected by the sintering due to the change of microstructure and crystallinity. The IR spectra reveal that the band at around 1400 cm−1 becomes weak, indicating that sodium carbonate decomposed and began to react with the silica and alumina released from gels to form nepheline phases. The sintering process influence in the development of the final microstructure thus improving the properties of the ceramic materials.

2019 ◽  
Vol 967 ◽  
pp. 286-291
Author(s):  
Romisuhani Ahmad ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Kamaruddin Hussin ◽  
Andrei Victor Sandu ◽  
Mohammed Binhussain

Geopolymer are being considered for a variety of application including formation of ceramics. The addition of Ultra High Molecular Weight Polyethylene as binder in geopolymer based ceramic is purposely to enhance the strength and toughness of the ceramic materials. This paper aims to study the relation of density and flexural strength of geopolymer based ceramic with addition of Ultra High Molecular Weight Polyethylene as binder. Geopolymer were synthesized by fixing the NaOH molarity, Na2SiO3/NaOH and solid to liquid ratio at 12 M, 0.24 and 1.0 respectively. Geopolymer in a powder form with addition of various content of UHMWPE (2 wt.%, 4 wt.%, 6 wt.%, 8 wt.% ) were pressed into pellets followed by sintering at 1200 °C. The highest flexural strength of geopolymer based ceramics was achieved at sintering temperature of 1200 °C which is 92.1 MPa with a lowest density of 1.88 g/cm3.


2020 ◽  
Vol 27 ◽  
pp. 2169-2173
Author(s):  
B. Suresha ◽  
B. Harshavardhan ◽  
Ashwij M. Rao ◽  
U.R. Koushik ◽  
R. Hemanth

2016 ◽  
Vol 857 ◽  
pp. 412-415
Author(s):  
Romisuhani Ahmad ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Kamarudin Hussin ◽  
Andrei Victor Sandu ◽  
Mohammed Binhussain ◽  
...  

This paper present the flexural strength of kaolin geopolymer ceramics with addition of ultra-high molecular weight polyethylene (UHMWPE) as a binder. The effect of varying UHMWPE loading and different sintering temperature on kaolin geopolymer ceramics were evaluated. Kaolin and alkaline activator were mixed with the solid-to-liquid ratio of 1.0. Alkaline activator was formed by mixing the 8 M NaOH solution with sodium silicate at a ratio of 0.24. Addition of UHMWPE to the kaolin geopolymer ceramics are fabricated with UHMWPE loadings of 2, 4, 6 and 8 (wt. %) by using powder metallurgy method. The samples were heated at different temperature started from 900 °C until 1200 °C and the strength were tested. It was found that the flexural strength for the kaolin geopolymer ceramics with addition of UHMWPE were higher and generally increased with the increasing of UHMWPE loading. Similar trend was observed for the effect of sintering temperature. The result revealed that the optimum flexural strength was obtained at UHMWPE loading of 8 wt. % and the samples heated at 1200 °C achieved the highest flexural strength (49.15 MPa).


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